Application and preparation method of dual-functional diethylstilbestrol non-enzymatic sensor constructed on basis of two-dimensional composite material
A technology of diethylstilbestrol and composite material, which is applied in the fields of new nano-functional materials and electrochemical biosensing analysis, can solve the problems of limiting wide application and affecting the convenience of operation, etc., and achieves highly selective detection and convenient operation. , The effect of improving detection sensitivity and detection limit
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Embodiment 1
[0038] Example 1 A bifunctional diethylstilbestrol enzyme-free sensor based on a two-dimensional composite material. The specific preparation steps are:
[0039] (1) Zn-MoS 2 Preparation of:
[0040] 0.005g zinc chloride ZnCl 2 , 2mL of 0.1mol / L ascorbic acid solution, 0.5mL of sodium molybdate Na 2 MoO 4 solution and 0.01 g sodium sulfide Na 2 S, after mixing and stirring for 15 minutes, put it into the reaction kettle, and react for 16 hours at 150°C; after cooling to room temperature, use deionized water to wash centrifugally, and vacuum dry at 40°C to obtain Zn-MoS 2 , which was dissolved in deionized water to obtain Zn-MoS 2 solution.
[0041] (2) Preparation of ECL working electrode W1:
[0042] 1) Using ITO conductive glass as the working electrode, drop-coat the Zn-MoS prepared in (1) on the surface of the electrode 2 Solution, covering an area of 1cm × 1cm, dry at room temperature;
[0043] 2) Put the working electrode obtained in 1) on the Zn-MoS 2 The ...
Embodiment 2
[0060] Example 2 A bifunctional diethylstilbestrol enzyme-free sensor based on a two-dimensional composite material. The specific preparation steps are:
[0061] (1) Zn-MoS 2 Preparation of:
[0062] The preparation steps are the same as that of Zn-MoS in Example 1 2 The preparation method of the solution, the difference is: ZnCl 2 The addition amount of ascorbic acid solution is 0.008g, the addition amount of ascorbic acid solution is 4mL, Na 2 MoO 4 The amount of solution added was 1.0 mL and Na 2 The amount of S added was 0.02 g, and the reaction was carried out at 220° C. for 12 hours.
[0063] (2) Preparation of ECL working electrode W1:
[0064] The preparation steps are the same as those of W1 in Example 1, except that the Zn-MoS prepared in (1) in this example is used 2 Modified electrodes; the length of the gold nanorods is 30nm; the concentration of luminol in the electrolyte is 5mmol / L, the concentration of sulfuric acid is 0.5mol / L, and the electrochemical...
Embodiment 3
[0072] Example 3 A bifunctional diethylstilbestrol enzyme-free sensor based on a two-dimensional composite material. The specific preparation steps are:
[0073] (1) Zn-MoS 2 Preparation of:
[0074] The preparation steps are the same as that of Zn-MoS in Example 1 2 The preparation method of the solution, the difference is: ZnCl 2 The addition amount of ascorbic acid solution is 0.01g, the addition amount of ascorbic acid solution is 6mL, Na 2 MoO 4 The amount of solution added was 1.5mL and Na 2 The amount of S added was 0.03 g, and the reaction was carried out at 220° C. for 12 hours.
[0075] (2) Preparation of ECL working electrode W1:
[0076] The preparation steps are the same as those of W1 in Example 1, except that the Zn-MoS prepared in (1) in this example is used 2 Modified electrodes; the length of the gold nanorods is 40nm; the concentration of luminol in the electrolyte is 10mmol / L, the concentration of sulfuric acid is 1.0mol / L, and the electrochemical ...
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