Organic zinc ion secondary battery

A secondary battery and zinc ion technology, applied in secondary batteries, battery electrodes, circuits, etc., can solve the problems of battery flatulence, easy hydrogen evolution, battery short circuit, etc., and achieve high power density, high capacity density, and excellent cycle stability Effect

Inactive Publication Date: 2016-07-13
BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, in the prior art, in the process of preparing zinc-ion batteries, an aqueous solution is used as the electrolyte. During the cycle, zinc ions will be deposited on the zinc electrodes to passivate the zinc electrodes. At the same time, the formed zinc dendrites will penetrate the separator and cause battery damage. Short circuit; In addition, the water electrolyte is prone to hydrogen evolution, resulting in battery flatulence

Method used

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  • Organic zinc ion secondary battery
  • Organic zinc ion secondary battery

Examples

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example 1

[0041] Example 1. Stir 7g of black phosphorus, 1.5g of acetylene black and 1.5g of polytetrafluoroethylene and coat it on copper foil, cut it into electrode sheets of a certain size and dry them in vacuum to constant weight. Use this electrode sheet as the positive electrode and the negative electrode. Extremely 25 micron thick zinc foil;

[0042] Then dissolve zinc sulfate and sodium dodecylbenzenesulfonate in N,N-dimethylformamide to form a 0.01mol / L solution, and use this solution as an electrolyte to assemble a zinc ion secondary battery.

example 2

[0043] Example 2. Stir 7g of phosphorene, 1.5g of graphite and 1.5g of polytetrafluoroethylene and coat it on copper foil, cut it into electrode sheets of a certain size and vacuum-dry them to constant weight. Use this electrode sheet as the positive electrode and the negative electrode Extremely 50 micron thick zinc foil;

[0044] Then dissolve zinc chloride and polyethylene glycol-polypropylene glycol-polyethylene glycol triblock copolymer in propylene carbonate to form a 0.01mol / L solution, and use this solution as an electrolyte to assemble zinc ions secondary battery.

example 3

[0045] Example 3, the composite of 7g black phosphorus and graphene, 2g carbon nanotubes and 1g carboxymethyl cellulose are stirred and coated with copper foil, cut into electrode sheets of a certain size and vacuum-dried to constant weight. The electrode sheet is used as the positive electrode, and the negative electrode is a composite of 7g zinc and 3g graphite; then zinc acetate is dissolved in a mixed solution of propylene carbonate and N,N-dimethylformamide with a volume ratio of 2:1 to form a 0.01mol / L solution, and this solution is used as electrolyte, and then assembled into a zinc ion secondary battery.

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Abstract

The invention discloses an organic zinc ion secondary battery. The battery comprises an anode, a cathode, a membrane between the anode and the cathode, electrolyte with ion conductivity and a surfactant, wherein active materials adopted by the anode include one or more of black phosphorus, black phosphorus/graphite, compound of graphene carbon nanotube or coal, phosphorene and phosphorene/graphite; the active materials adopted by the cathode comprise simple substances, compounds or complexes focusing on zinc element; the electrolyte with ion conductivity comprises a liquid-state or gel-state material which takes soluble salt of zinc as a solute and takes an organic solvent as a solution; the surfactant comprises an ionic surfactant, a nonionic surfactant and a mixture of the ionic surfactant and the nonionic surfactant. The battery has the characteristics of being high capacity density and power density and excellent in cycling stability, and can be widely applied to different fields of electronics, communication, traffic and transportation.

Description

technical field [0001] The invention relates to the technical field of new energy, in particular to an organic zinc ion secondary battery. Background technique [0002] At present, the existing zinc-ion battery is a secondary ion battery that can be recharged and discharged repeatedly. It has the characteristics of safety, environmental protection and low cost, and has very high potential application value in many fields such as electronics, communication, and energy. [0003] However, in the prior art, in the process of preparing zinc-ion batteries, an aqueous solution is used as the electrolyte. During the cycle, zinc ions will be deposited on the zinc electrodes to passivate the zinc electrodes. At the same time, the formed zinc dendrites will penetrate the separator and cause battery damage. Short circuit; In addition, the water electrolyte is prone to hydrogen evolution, resulting in battery flatulence. Contents of the invention [0004] The object of the present inv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/054H01M4/36H01M4/583H01M4/62H01M4/42H01M10/0568H01M10/0569H01M10/0567
CPCH01M4/362H01M4/42H01M4/583H01M4/625H01M10/054H01M10/0567H01M10/0568H01M10/0569Y02E60/10
Inventor 崔秀国祖雷连慧琴
Owner BEIJING INSTITUTE OF PETROCHEMICAL TECHNOLOGY
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