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Production system and method for coumarone resin

A coumarone resin and production system technology, applied in the field of resin hydrogenation synthesis of new materials, can solve the problem of not removing colored groups, etc., to reduce the production of gelatin in subsequent processes, strong mutual solubility, and low chroma Effect

Active Publication Date: 2016-10-26
朗盈科技(北京)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In the prior art, there is no removal of colored groups from petroleum resin raw materials, and the processes of resin polymerization and dehydrogenation are completely separated

Method used

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  • Production system and method for coumarone resin
  • Production system and method for coumarone resin
  • Production system and method for coumarone resin

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] In this embodiment, according to the flow process shown in the accompanying drawings, the experimental raw material is coumarone resin raw material, and the first-stage hydrogenation catalyst uses a highly active nickel metal hydrogenation catalyst (Ni content 15-30%) produced by the Shanxi Coal Chemical Industry Institute of the Chinese Academy of Sciences, which is resistant to melting and oxidation. aluminum and silica carrier), the two-stage hydrogenation catalyst uses the palladium metal hydrorefining catalyst (5% Pt content, refractory alumina and silica carrier) produced by the Shanxi Coal Chemical Industry Institute of the Chinese Academy of Sciences, and the above-mentioned catalysts are all clover-shaped and inert The catalyst uses alumina active ceramic balls with large pores; the process conditions are shown in Table 1, and the experimental results are shown in Table 4.

[0053] Table 1 process conditions

[0054]

[0055]

Embodiment 2

[0061] In this embodiment, according to the flow process shown in the accompanying drawings, the experimental raw material is coumarone resin raw material, and the first-stage hydrogenation catalyst uses a highly active nickel metal hydrogenation catalyst (Ni content 15-30%) produced by the Shanxi Coal Chemical Industry Institute of the Chinese Academy of Sciences, which is resistant to melting and oxidation. aluminum and silica carrier), the two-stage hydrogenation catalyst uses the palladium metal hydrorefining catalyst (5% Pt content, refractory alumina and silica carrier) produced by the Shanxi Coal Chemical Industry Institute of the Chinese Academy of Sciences, and the above-mentioned catalysts are all clover-shaped and inert The catalyst uses alumina active ceramic balls with large pores; the process conditions are shown in Table 2, and the experimental results are shown in Table 4.

[0062] Table 2 process conditions

[0063]

[0064]

Embodiment 3

[0070] In this embodiment, according to the flow process shown in the accompanying drawings, the experimental raw material is coumarone resin raw material, and the first-stage hydrogenation catalyst uses a highly active nickel metal hydrogenation catalyst (Ni content 15-30%) produced by the Shanxi Coal Chemical Industry Institute of the Chinese Academy of Sciences, which is resistant to melting and oxidation. aluminum and silica carrier), the two-stage hydrogenation catalyst uses the palladium metal hydrorefining catalyst (5% Pt content, refractory alumina and silica carrier) produced by the Shanxi Coal Chemical Industry Institute of the Chinese Academy of Sciences, and the above-mentioned catalysts are all clover-shaped and inert The catalyst uses alumina active ceramic balls with large pores; the process conditions are shown in Table 3, and the experimental results are shown in Table 4.

[0071] Table 3 process conditions

[0072]

[0073]

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PUM

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Abstract

The invention discloses a production system and method for coumarone resin, and belongs to the field of resin hydrogenation synthesis of novel materials. The production system comprises a raw material pretreatment device, a polymerization device, a polymerization ending device, a sampling pre-treating device, a hydrogenation reaction device and a post-treatment device which are sequentially connected, wherein the raw material pretreatment device is a C9 petroleum resin raw material pretreatment reactor; the raw material pretreatment device is a fixed bed reactor which is filled with a high-capacity sulfur nickel based catalyst. By using self-developed process flow and reaction equipment, colored groups of raw materials are removed, and petroleum resin raw material polymerization and a hydrogenation process are integrated, so that procedure operation of the system is simple, and consumption of the catalyst is low; and the obtained resin product is good in light-heat stability, is strong in intersolubility, is low in chromaticity and is high in softening point.

Description

technical field [0001] The invention relates to the field of resin hydrogenation synthesis new materials, in particular to a production system and method of coumarone resin. Background technique [0002] With the rapid development of my country's petrochemical industry, the production capacity of ethylene is increasing year by year, which promotes the continuous increase of the by-product ethylene cracking carbon nine fraction of ethylene plant, which accounts for about 10% to 20% of the total ethylene output. In 2010, my country's total ethylene production capacity was 14.765 million t / a, and the total amount of cracked carbon nine was about 1.4 million tons. As of today, the total cracked carbon nine is estimated to exceed 2 million tons. The domestic level of comprehensive utilization of cracked C9 fractions is low, and the C9 fractions are mainly sold as cheap primary raw materials, or a small part is used to produce petroleum resin or used as gasoline, diesel components...

Claims

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Application Information

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IPC IPC(8): C08F244/00C08F2/01C08F8/04
CPCC08F2/01C08F8/04C08F244/00
Inventor 李涛胡平龚腾勇
Owner 朗盈科技(北京)有限公司