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Patterning method of nitride ceramic copper-clad plate and nitride ceramic copper-clad plate

A technology of nitride ceramics and copper clad laminates, which is applied in the manufacture of electrical components, electrical solid devices, semiconductor/solid devices, etc., can solve the problems of poor state of the metal plate surface, reduced etching ability, slow etching rate, etc., and achieve the state of the plate surface Good, uniform etching, shortened etching time

Inactive Publication Date: 2017-01-11
ZHEJIANG TC CERAMIC ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the actual process, it is found that the fluoride ion etching solution such as the mixture of hydrofluoric acid and nitric acid has problems such as slow etching rate and incomplete etching, and the etching solution bites the surface of the metal plate, making the state of the metal plate surface poor
The hydrogen peroxide system etching solution also has the problem of incomplete etching and difficult removal of residues after etching
Hydrogen peroxide is easy to decompose and has poor stability. In order to improve the stability of etching solution, it is necessary to add stabilizers and etching selectors, which can improve the stability of hydrogen peroxide etching solution, but at the same time, the etching ability of etching solution for other metals is reduced, and it is more likely to occur The problem of incomplete etching and difficult removal of residues

Method used

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  • Patterning method of nitride ceramic copper-clad plate and nitride ceramic copper-clad plate
  • Patterning method of nitride ceramic copper-clad plate and nitride ceramic copper-clad plate
  • Patterning method of nitride ceramic copper-clad plate and nitride ceramic copper-clad plate

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preparation example Construction

[0034]The preparation of the nitride ceramic copper-clad laminate 100 further includes: a printing process, a copper-clad foil process, and a sintering process. Specifically: the printing process is to apply the active brazing material to both surfaces of the ceramic substrate 110 by full-plate printing. In this embodiment, the active brazing material of the present invention is copper-silver brazing material, and further includes one or more active metals such as titanium, zirconium, and hafnium. The copper foil cladding process is to coat a whole plate of copper foil 120 on both sides of the ceramic substrate 110 coated with active solder, wherein the copper foil 120 requires surface pretreatment, that is, degreasing and deoxidation treatment to ensure that the surface of the copper foil 120 is free from grease and oxides. According to a preferred embodiment, the degreasing of the copper foil 120 can be carried out by lye or degreasing agent. According to a preferred embod...

Embodiment 1

[0050] The active brazing material is coated on both sides of the 50mm×50mm aluminum nitride ceramic substrate 110 by full plate printing. A piece of copper foil 120 matching the size of the ceramic substrate 110 is provided on both sides of the ceramic substrate 110 coated with active solder. Before the copper foil 120 is installed, the surface of the copper foil 120 needs to be pre-treated to remove oil stains and oxide layers on the surface. The aluminum nitride ceramic substrate 110 and the copper foil 120 are sintered at a temperature of 800° C., and the sintering process is carried out under vacuum conditions with a vacuum degree of 5×10 -4 Pa. The whole sintering time is 10min. After sintering, the surface of the semi-finished aluminum nitride ceramic copper-clad laminate 100 is provided with a dry film as a resist layer. Then a desired etching pattern (that is, a circuit pattern to be formed) is formed on the resist layer. The semi-finished aluminum nitride ceramic...

Embodiment 2

[0053] The active brazing material is coated on both sides of the 50mm×50mm boron nitride ceramic substrate 110 by full plate printing. A piece of copper foil 120 matching the size of the ceramic substrate 110 is provided on both sides of the ceramic substrate 110 coated with active solder. Before the copper foil 120 is installed, the surface of the copper foil 120 needs to be pre-treated to remove oil stains and oxide layers on the surface. The aluminum nitride ceramic substrate 110 and the copper foil 120 are sintered at a temperature of 900° C., and the sintering process is carried out under vacuum conditions with a vacuum degree of 2×10 -4 Pa. The whole sintering time is 40min. After sintering, the surface of the semi-finished aluminum nitride ceramic copper-clad laminate 100 is provided with a dry film as a resist layer. Then a desired etching pattern (that is, a circuit pattern to be formed) is formed on the resist layer. The semi-finished aluminum nitride ceramic co...

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Abstract

The invention discloses a patterning method of a nitride ceramic copper-clad plate and a nitride ceramic copper-clad plate. The patterning method comprises the following steps: arranging a patterned anti-corrosion layer on the surface of the nitride ceramic copper-clad plate, wherein the nitride ceramic copper-clad plate is formed by an active brazing method; performing first etching treatment on the nitride ceramic copper-clad plate by using a first etching solution, wherein the first etching solution comprises a CuCl<2> solution or a FeCl<3> solution; performing second etching treatment on the nitride ceramic copper-clad plate being subjected to the first etching treatment by using a second etching solution; and performing third etching treatment on the nitride ceramic copper-clad plate being subjected to the second etching treatment by using a third etching solution. The patterning method has the advantages of high etching efficiency, uniform etching and freeness from residues; the etching quality is improved; and a metal layer has a good plate surface state.

Description

technical field [0001] The invention relates to the technical field of semiconductor substrate preparation, in particular to a patterning method of a nitride ceramic copper clad laminate and a nitride ceramic copper clad laminate. Background technique [0002] High-power modules are widely used in electric locomotives, electric vehicles, photovoltaic solar energy and other fields. As power modules become more integrated and more powerful, the heat generated by semiconductor devices is on the rise. At present, the practice of forming a ceramic circuit board by joining a metal plate with good electrical and thermal conductivity to a ceramic sintered body substrate with good insulation and heat dissipation such as aluminum nitride has been widely popularized. Due to its good thermal conductivity, ceramic circuit boards are widely used as lining boards of power modules to solve the heat dissipation problem of semiconductor devices. [0003] So far, there are two main methods o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L21/48H01L23/14
Inventor 袁超钱建波黄世东于岩
Owner ZHEJIANG TC CERAMIC ELECTRONICS
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