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Microelement tracer agent used for offshore oilfield and use method thereof

A trace element and offshore oilfield technology, applied in construction and other fields, can solve the problems of long tracer diffusion time, insufficient analysis accuracy, and low oil recovery efficiency, and achieve the prevention and control of large pores, good safety and stability, and advanced detection technology Effect

Active Publication Date: 2017-02-01
潍坊华诺生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. Due to the long-term water injection in the oil layer, the stability of fractures in the enhanced rock formation decreases, the dissolution of soluble salts increases, and the expansion of cracks directly leads to the formation of large pores;
[0007] 2. The tracers in the prior art are non-radioactive, polluting, and not good enough in safety and stability;
[0008] 3. The tracers in the prior art have insufficient analytical precision;
[0009] 4. In the prior art, the tracer in China has a long diffusion time in water
[0010] Due to the above defects, the oil recovery efficiency is low, the oil yield is low, the amount of water-free treatment is large, and the cost of oil production is increased. The present invention is proposed for the above-mentioned defects of the prior art.

Method used

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  • Microelement tracer agent used for offshore oilfield and use method thereof
  • Microelement tracer agent used for offshore oilfield and use method thereof
  • Microelement tracer agent used for offshore oilfield and use method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Example 1 A trace element tracer, in parts by weight, including the following components:

[0035] Precursors: 4 parts of trace element chloride, 1 part of precursor, 0.1 part of sodium bicarbonate, 0.2 part of citric acid, 0.08 part of sulfonated phenolic resin, 0.12 part of PAM;

[0036] The trace element chloride in the precursor is a mixture of praseodymium-molybdenum chloride; the precursor is sodium ethylenediamine tetramethylene phosphate;

[0037] After-drive: 2-parts of trace element chloride, 0.6-parts of after-drive agent, 0.3 parts of calcium chloride, 0.25 parts of sodium dodecylbenzene sulfonate, 0.05 parts of polyacrylamide;

[0038] In the after-drive, the trace element chloride is a mixture of praseodymium-molybdenum chloride;

[0039] The molar mass ratio of praseodymium chloride to molybdenum chloride in the trace element chloride is 0.6;

[0040] The after-drive agent calcium lignosulfonate;

Embodiment 2

[0041] Example 2 A trace element tracer, using the raw materials described in Example 1, only the ratio of the raw materials was changed to:

[0042] Precursors: 4.5 parts of trace element chloride, 1.1 parts of precursors, 0.12 parts of sodium bicarbonate, 0.25 parts of citric acid, 0.09 parts of sulfonated phenolic resin, 0.13 parts of PAM;

[0043] The trace element chloride in the precursor is a mixture of praseodymium-molybdenum chloride; the precursor is sodium ethylenediamine tetramethylene phosphate;

[0044] After-drive: 2.3 parts of trace element chloride, 0.7 parts of after-drive agent, 0.35 parts of calcium chloride, 0.27 parts of sodium dodecylbenzene sulfonate, 0.07 parts of polyacrylamide;

[0045] In the after-drive, the trace element chloride is a mixture of praseodymium-molybdenum chloride;

[0046] Among the trace element chlorides of the precursor and the follower, the molar mass ratio of praseodymium chloride to molybdenum chloride is 0.8;

[0047] The after-drive ag...

Embodiment 3

[0048] Example 3 A trace element tracer, using the raw materials described in Example 1, only the ratio of the raw materials was changed to:

[0049] Precursors: 5 parts of trace element chloride, 1.2 parts of precursors, 0.15 parts of sodium bicarbonate, 0.3 parts of citric acid, 0.1 parts of sulfonated phenolic resin, 0.14 parts of PAM;

[0050] The trace element chloride in the precursor is a mixture of praseodymium-molybdenum chloride; the precursor is sodium ethylenediamine tetramethylene phosphate;

[0051] After-drive: 2.5 parts of trace element chloride, 0.8 parts of after-drive agent, 0.4 parts of calcium chloride, 0.3 parts of sodium dodecylbenzene sulfonate, 0.08 parts of polyacrylamide;

[0052] In the after-drive, the trace element chloride is a mixture of praseodymium-molybdenum chloride;

[0053] Among the trace element chlorides of the precursor and the follower, the molar mass ratio of praseodymium chloride to molybdenum chloride is 1.1;

[0054] The after-drive agent ca...

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PUM

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Abstract

The invention provides a microelement tracer agent special for an offshore oilfield. The tracer agent is made from raw materials of a precursor and a post-cursor. The precursor and the post-cursor each contain microelement chloride. A microelement mixture is a praseodymium-molybdenum chloride mixture. The invention further provides a use method of the microelement tracer agent. The use method comprises the step that a prepared precursor solution and a prepared post-cursor solution are sequentially injected into a monitoring well, wherein the volume ratio of the precursor solution to the post-cursor solution is 1:(0.8-1), and the time interval for injection of the precursor solution and injection of the post-cursor solution is 80-120 min. The prepared microelement tracer agent is free of radiation and pollution and good in safety and stability; an HR-ICP-MS instrument is used for detecting, the minimum detection limit can be up to 10-15 (ppq grade) grade; and the microelement tracer agent can be fast disintegrated in water, and evenly diffused and dissolved with the diffusion time no longer than 48 seconds.

Description

Technical field [0001] The invention relates to a tracer and a use method thereof, and more specifically, to a trace element tracer for offshore oil fields and a use method thereof. Background technique [0002] Water injection tracing technology is one of on-site production testing technologies. The principle is to inject the tracer from the injection well, and then take samples from the surrounding production wells according to certain sampling regulations, monitor the production situation, analyze the samples, obtain the tracer production curve, and then perform fitting to reflect the water injection The connection of oil and water wells during development. Master the direction of the injected water, the displacement speed, the affected area, the heterogeneity of the reservoir and the distribution of remaining oil saturation, etc. to guide the design of oil well production and the adjustment of the later stage of oil field development. [0003] At present, water injection deve...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E21B47/11
CPCE21B47/11
Inventor 江涛刘维华李铮张国臣
Owner 潍坊华诺生物科技有限公司
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