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High-efficiency low-warpage solar cell aluminum slurry and preparation method thereof

A technology for solar cells and aluminum paste, which is used in cable/conductor manufacturing, circuits, electrical components, etc., and can solve problems such as cell warpage

Inactive Publication Date: 2017-05-17
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These methods have a certain effect, but the problem of cell warpage is still prominent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Equipped with 76 parts by mass of spherical aluminum powder so that the average particle size is 3-6 μm and the maximum particle size is less than 15 μm.

[0022] 20 parts by mass of an organic vehicle are prepared. The preparation process is: select 66% terpineol, 10% ethyl cellulose, 3% butyl carbitol acetate, 10% butyl carbitol, 5% tributyl citrate, 3% Phenolic resin and 3% lecithin. After mixing, stir at 100°C for 2 hours, cool naturally, and filter for later use.

[0023] Weigh 4 parts by mass of glass powder. The glass powder preparation process is: weigh 28% barium oxide, 11% vanadium pentoxide, 4% zinc oxide, 26% lead oxide, 30% bismuth trioxide, 0.5% potassium oxide, 10.5% di boron. Mix it evenly in a corundum crucible, and after fully preheating at 500°C, heat it to 1350°C and keep it warm for 2 hours. Stir the high-temperature mixture evenly and quench it with water to obtain a glass powder precursor. The precursor was mechanically milled with zirconia ...

Embodiment 2

[0026] Equipped with 74 parts by mass of spherical aluminum powder, so that the average particle size is 3-6 μm, and the maximum particle size is less than 15 μm.

[0027] 23 parts by mass of an organic vehicle were prepared. Its preparation process is: select 70% terpineol, 8% ethyl cellulose, 1% butyl carbitol acetate, 12% butyl carbitol, 5% tributyl citrate, 2% Phenolic resin and 4% lecithin. After mixing, stir at 100°C for 2 hours, cool naturally, and filter for later use.

[0028] Weigh 3 parts by mass of glass powder. The glass powder preparation process is as follows: 10% barium oxide, 2% vanadium pentoxide, 16% zinc oxide, 10% lead oxide, 32% bismuth trioxide, 26% boron trioxide, 1% oxide Titanium, 3% magnesium oxide. Mix it evenly in a corundum crucible, and after fully preheating at 500°C, heat it to 1350°C and keep it warm for 2 hours. Stir the high-temperature mixture evenly and quench it with water to obtain a glass powder precursor. The precursor was mechan...

Embodiment 3

[0031] Equipped with 76 parts by mass of spherical aluminum powder so that the average particle size is 3-6 μm and the maximum particle size is less than 15 μm.

[0032] 21 parts by mass of an organic vehicle are prepared. The preparation process is: select 68% terpineol, 8% ethyl cellulose, 2% butyl carbitol acetate, 12% butyl carbitol, 2% tributyl citrate, 3% Phenolic resin and 5% lecithin. After mixing, stir at 100°C for 2 hours, cool naturally, and filter for later use.

[0033] Weigh 3 parts by mass of glass powder. The glass powder preparation process is as follows: 1% vanadium pentoxide, 24% zinc oxide, 52% bismuth trioxide, 20% boron trioxide and 3% titanium oxide are weighed in parts by mass. Mix it evenly in a corundum crucible, and after fully preheating at 500°C, heat it to 1300°C and keep it warm for about 2.5 hours. Stir the high-temperature mixture evenly and quench it with water to obtain a glass powder precursor. The precursor was mechanically milled with...

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Abstract

The invention discloses aluminum slurry for a back surface field of a crystalline silicon solar cell and a preparation method of the aluminum slurry. The aluminum slurry comprises 70-80 parts of aluminum powder, 1-5 parts of glass powder and 15-25 parts of an organic carrier by weight. The organic carrier comprises 50-70 parts of terpineol, 3-10 parts of ethyl cellulose, 0-5 parts of butyl carbitol acetic ester, 10-12 parts of butyl carbitol, 5-10 parts of tributyl citrate, 0.1-5 parts of phenolic resin, 0-3 parts of polyester resin and 1-5 parts of lecithin by weight. The glass powder comprises 0-30 parts of BaO, 0-25 parts of ZnO, 30-60 parts of Bi2O3, 10-30 parts of B2O3, 0-1 part of K2O, 0-5 parts of TiO2, 0-3 parts of MgO, 1-20 parts of V2O5 and 0-30 parts of PbO by weight. The aluminum powder, the glass powder and the organic carrier are mixed uniformly according to certain proportion, and a mixture is ground by a three-roller grinder till the fitness reaches 5-15 micron and the viscosity 35-45 Pa.S. The aluminum slurry can facilitate formation of the back surface field of the crystalline silicon cell, a high photoelectric conversion efficiency can be obtained under the condition that the printing wet weight of the aluminum slurry is reduced, and the warpage of the cell is reduced.

Description

technical field [0001] The invention belongs to the field of crystalline silicon solar cells, and in particular relates to an aluminum paste for a back electric field of a crystalline silicon solar cell and a preparation method thereof. Background technique [0002] Solar energy is rich in resources and widely distributed, and it is a renewable energy with great development potential. As problems such as energy shortage and environmental pollution become increasingly prominent, solar photovoltaic power generation technology has been widely concerned and continuously developed by countries all over the world because of its clean, safe, and convenient features. The development of solar cells has a history of more than 30 years. There are many types of solar cells in the market, mainly monocrystalline, polycrystalline, and amorphous silicon. At present, the largest market and the most mature technology are crystalline silicon solar cells, and aluminum paste is an important mat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/22H01B13/00H01L31/0224
CPCH01B1/22H01B13/00H01L31/022425
Inventor 周继承陈星
Owner CENT SOUTH UNIV