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Water-borne organic cold carrying/heat conduction medium and preparation method thereof

A heat transfer medium and organic technology, which is applied in the field of water-based organically loaded cold/heat transfer medium, can solve the problems of poor nitrogen sealing effect of heat transfer oil system, system operation hazards, hindering the flow of heat transfer oil, etc., and achieves good corrosion inhibition effect and corrosion inhibition Excellent effect, good adsorption effect

Inactive Publication Date: 2017-05-24
ENERGY RES INST OF SHANDONG ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

After the coking phenomenon occurs, it not only hinders the flow of heat transfer oil, reduces heat transfer efficiency and increases fuel consumption, but also causes local overheating and deformation of the pipeline to cause explosion.
(2) Easy to corrode
The nitrogen sealing effect in the heat transfer oil system is not good. In the presence of oxygen, it is easy to oxidize into phytic acid and colloids to adhere to the oil pipeline. Risk of running leaks
Moreover, due to its complex composition, it is particularly difficult to add corrosion and scale inhibitors to solve its corrosion problems. At present, there is no successful case of adding corrosion inhibitors to heat transfer oil to solve its corrosion
(3) Frequent replacement
(4) The operating environment has very strict requirements on water content, and a small amount of water can bring great harm to the system operation
[0006] At present, there are imported products that can meet the above indicators, but the use temperature is limited to below 180°C, and the price is very expensive

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A water-based organic-mounted cold / heat-conducting medium, which includes the following components by weight: 55 parts of propylene glycol, 17 parts of diethylene glycol, 17 parts of triethylene glycol, 2 parts of deionized water, 0.8 part of succinic acid, 0.3 part of adipic acid, 0.1 part of tricarboxylic acid, 0.3 part of diethanolamine, 6 parts of triethanolamine, 0.1 part of mercaptobenzothiazole, 1 part of benzotriazole, hexaethylphosphorous acid 0.3 part of triamine, 0.1 part of polymaleic anhydride with a degree of polymerization of 8000.

[0018] The preparation method of the above-mentioned water-based organically loaded cold / heat-conducting medium is: adding propylene glycol, diethylene glycol, triethylene glycol and deionized water into a beaker according to a certain ratio, and using a polytetrafluoroethylene electric stirrer to Stir, stir and mix evenly to form a base liquid, dissolve diethanolamine and triethanolamine in the base liquid according to a cer...

Embodiment 2

[0026] Embodiment 2: The similarities between this embodiment and Embodiment 1 will not be repeated, and the difference is:

[0027] A water-based organic-mounted cold / heat-conducting medium, which includes the following components by weight: 62 parts of propylene glycol, 15 parts of diethylene glycol, 15 parts of triethylene glycol, 3.2 parts of deionized water, 0.2 part of succinic acid, 0.3 part of adipic acid, 0.05 part of tricarboxylic acid, 0.25 part of diethanolamine, 3.18 part of triethanolamine, 0.1 part of mercaptobenzothiazole, 0.6 part of benzotriazole, hexaethylphosphorous 0.1 part of triamine, 0.02 part of polymaleic anhydride with a degree of polymerization of 8000.

[0028] Its preparation method is with embodiment 1, repeats no more.

[0029] The test results show that,

[0030] (1) Freezing point: -37°C, boiling point 225°C;

[0031] (2) Corrosion and scale inhibition performance: refer to (GB29743-2013 glassware test method), in an environment of 180 ℃, a...

Embodiment 3

[0035] Embodiment 3: The similarities between this embodiment and Embodiment 1 will not be repeated, and the difference is:

[0036] A water-based organic-mounted cold / heat-conducting medium, which includes the following components by weight: 64 parts of propylene glycol, 14 parts of diethylene glycol, 14 parts of triethylene glycol, 4 parts of deionized water, 0.25 parts of succinic acid, 0.5 parts of adipic acid, 0.07 parts of tricarboxylic acid, 0.2 parts of diethanolamine, 2 parts of triethanolamine, 0.1 part of mercaptobenzothiazole, 0.7 part of benzotriazole, hexaethylphosphorous acid It consists of 0.14 parts of triamine and 0.03 parts of polymaleic anhydride with a degree of polymerization of 8000.

[0037] Its preparation method is with embodiment 1, repeats no more.

[0038] The test results show that,

[0039] (1) Freezing point: -39°C, boiling point 218°C;

[0040] (2) Corrosion and scale inhibition performance: refer to (GB29743-2013 glassware test method), in ...

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Abstract

The invention relates to a water-borne organic cold carrying / heat conduction medium and a preparation method. The water-borne organic cold carrying / heat conduction medium is prepared by the following steps of using propylene glycol, diethylene glycol, tri-ethylene glycol and deionized water as base liquids, and using succinic acid, adipic acid, tricarboxylic acid, diethanol amine, triethanolamine, tris(dimethylamino)phosphine, mercaptobenzothiazole, benzotriazole, tris(N,N-diethylamino)phosphine and polymaleic anhydride with polymerizing degree of 8000 as compound corrosion and scale inhibitors; respectively adding, heating by phases, stirring, and dissolving. The prepared water-borne organic cold carrying / heat conduction medium has the characteristics that the excellent corrosion and scale inhibition property is realized for a multi-metal system, and the electrochemical corrosion and heat corrosion are effectively prevented; the reserve alkalinity is more than 20ml, so that the medium has stable PH (potential of hydrogen) value, and the long-time effect of the medium property is guaranteed; the heat conduction coefficient is slightly better than the heat conduction coefficient of heat conduction oil, and the medium can normally work at the temperature range of -40 to 210 DEG C, can be used as a cold carrier and an anti-freezing agent at low temperature, and can also be used as a heat conduction liquid at high temperature; the property is stable at high temperature, the viscosity is low at low temperature, the corrosion and scale inhibition property is lasting, the environment-friendly effect is realized, and the heat conduction coefficient is good.

Description

technical field [0001] The invention relates to the field of organic materials, in particular to an aqueous organic-mounted cold / heat conducting medium. Background technique [0002] At present, the important heat transfer medium of heating oil furnaces in industrial production is heat transfer oil, and the carrier refrigerant is mostly air and water. [0003] Heat transfer oil has the characteristics of high boiling point, high flash point, accurate temperature control, high temperature under low vapor pressure, good heat transfer effect, energy saving, convenient transportation and operation, etc., and has been widely used in various indirect heat transfer fields in recent years . Although heat transfer oil has many advantages, it also has many fatal disadvantages. (1) Easy to coke. After the coking phenomenon occurs, it not only hinders the flow of heat transfer oil, reduces heat transfer efficiency and increases fuel consumption, but also causes local overheating defo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/20C09K5/10
CPCC09K5/20C09K5/10
Inventor 姜桂林刘志刚张承武侯延进吕明明
Owner ENERGY RES INST OF SHANDONG ACAD OF SCI
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