A kind of near-net-shape diamond/copper composite material with high thermal conductivity and preparation method thereof
A composite material and diamond technology, applied in the field of metal materials, can solve the problems of poor compatibility between diamond and metal, single shape of composite material, and low surface quality, so as to reduce interface thermal resistance, high surface quality, and improve two-phase compatibility sexual effect
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Embodiment 1
[0034] After surface purification, degreasing, and roughening treatments, 200g of diamond particles with an average particle size of 105μm are mixed with 2380gW powder in a ball mill and then taken out, under the protection of a mixed salt bath (the mass ratio of KCl and NaCl is 1:1) Heat to 1150℃, keep the temperature for 120 minutes, and cool down with the furnace to obtain diamond particles on the surface of W. The thickness of the tungsten plating layer and tungsten carbide layer is 3μm; the diamond particles on the surface of W and the binder (the binder includes the following Raw materials in weight ratio: 50% paraffin wax, 20% high-density polyethylene, 10% stearic acid and 20% polypropylene) at a mass ratio of 13:1, fully mixed to form a feed, injection molded on an injection molding machine, and degreasing The porous diamond preform is then obtained. Put an appropriate amount of copper on top of the diamond preform, in which the mass ratio of copper and diamond preform...
Embodiment 2
[0036] After surface purification, degreasing, and roughening treatments, 200g of diamond particles with an average particle size of 105μm are mixed with 3570gW powder in a ball mill and taken out, under the protection of a mixed salt bath (the mass ratio of KCl and NaCl is 1:1) Heat to 1150℃, keep the temperature for 120 minutes, and cool down with the furnace to obtain diamond particles on the surface of W. The thickness of the tungsten plating layer and tungsten carbide layer is 3μm; the diamond particles on the surface of W and the binder (the binder includes the following Raw materials in weight ratio: 40% paraffin wax, 25% high-density polyethylene, 10% stearic acid and 25% polypropylene) at a mass ratio of 13:1, fully mixed to form feedstock, injection molded on an injection molding machine, and degreasing The porous diamond preform is then obtained. Put an appropriate amount of copper on top of the diamond preform, in which the mass ratio of copper to diamond preform is...
Embodiment 3
[0038] After surface purification, degreasing, and roughening treatments, 20g of diamond particles with an average particle size of 105μm are mixed with 357gW powder in a ball mill and taken out, and protected in a mixed salt bath (the mass ratio of KCl and NaCl is 1:1) Heat to 1150℃, keep the temperature for 20 minutes, and cool down with the furnace to obtain diamond particles with W-plated surface. The thickness of the tungsten coating and tungsten carbide layer is 1μm; the diamond particles with W-plated surface and the binder (the binder includes the following Raw materials by weight ratio: 60% paraffin wax, 16% high-density polyethylene, 8% stearic acid and 16% polypropylene) are fully mixed at a mass ratio of 13:1, pressed in a mold, and degreasing to obtain porous diamond Preform: Put an appropriate amount of copper on top of the diamond preform, where the mass ratio of copper and diamond preform is 2:1, heated to 1300°C in an argon atmosphere, kept for 60 minutes, and c...
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