The invention discloses a production process for extracting elements such as aluminum, vanadium, molybdenum and nickel from black shale. The production process comprises the following steps: carrying out crushing and fine grinding on ores, adding an additive, water and concentrated sulfuric acid, uniformly stirring and then, sealing for storage and curing; stirring and leaching cured materials in water to obtain a solution of aluminum sulfate, nickel sulfate, molybdenum acyl sulfate and vanadium acyl sulfate, and carrying out liquid-solid separation; adding an ammonium salt or a potassium salt into filtrate to produce alum crystals, and carrying out filtering separation; regulating the PH value of the filtrate, then carrying out oxidization, then, adsorbing by using anion resin and desorbing by using an lkali liquor; regulating the PH value of the desorbing liquor, adding the ammonium salt to produce vanadate, and carrying out filtering separation; re-regulating the PH value of the filtrate to produce molybdate crystals, and carrying out filtering separation; adsorbing nickel from ion-exchanged liquor by using amino phosphate rein, and generating nickel sulfate by virtue of elution, evaporation and concentration of the sulfuric acid, and carrying out crystallizing separation on the nickel sulfate; and returning the filtrate for use.