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Method for preparing polypropylene composite

A technology for composite materials and polypropylene, which is applied in the field of preparation of polypropylene composite materials, can solve problems such as the inability of nucleating agents to function effectively, and achieve the effects of easy realization of reaction conditions, high thermal stability, and increased heat distortion temperature

Inactive Publication Date: 2017-06-16
XINJIANG TECHN INST OF PHYSICS & CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0051] The object of the present invention is to provide a low-cost, simple process, a method for preparing a polypropylene composite material that effectively combines nucleating agent regulation and fiber reinforcement, and synergistically improves the comprehensive performance of the polypropylene composite material. The method is made of polypropylene , compatibilizer, glass fiber, nucleating agent, and antioxidant are prepared by a two-step method. First, the nucleating agent is used to induce the crystal transformation of polypropylene, and then the glass fiber is compounded with it for further reinforcement. It solves the problem that the traditional method directly mixes polypropylene with nucleating agent and fiber. Due to the introduction of glass fiber as a foreign impurity, the nucleating agent cannot effectively play its role in regulating the crystallization behavior of polypropylene.

Method used

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  • Method for preparing polypropylene composite
  • Method for preparing polypropylene composite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0080] a. Weigh polypropylene 79.3%, antioxidant 0.2%, β-nucleating agent N,N′-dicyclohexyl-2,6-naphthalamide 0.3%, and dry in an oven at 80℃ for 12h , And then put it into a high-speed mixer to mix, and then add it to a twin-screw extruder to extrude and granulate. The twin-screw parameters are: the temperature in the first zone is 160℃, the temperature in the second zone is 180℃, and the temperature in the third zone is 210 ℃, four zone temperature is 220℃, five zone temperature is 220℃, head temperature is 210℃, twin screw speed is 70r / min, feeder speed is 4r / min, pelletizer speed is 200r / min, among which Antioxidant is compounded by pentaerythritol tetrapropionate and tris(2,4-di-tert-butylphenyl) phosphite in a mass ratio of 1:1;

[0081] b. Dry the granulation in step a in an oven at a temperature of 60°C overnight, mix it with 20% of the dried glass fiber and 0.2% of the compatibilizer, and then extrude it in a twin-screw extruder for granulation. The screw parameters are...

Embodiment 2

[0087] a. Weigh polypropylene 69.3%, antioxidant 0.2%, β-nucleating agent (N,N'-dicyclohexylterephthalamide) 0.3% according to the mass fraction, and place them in an oven at 80°C for 12 hours. Put it into a high-speed mixer for mixing, place it in an oven at a temperature of 80℃ for 12h, then mix it, add it to a twin-screw extruder for extrusion and granulation. The twin-screw parameters are: the temperature in the first zone is 165℃, and the temperature in the second zone is 185℃, temperature in three zones is 215℃, temperature in four zones is 225℃, temperature in five zones is 225℃, head temperature is 215℃, twin screw speed is 60r / min, feeder speed is 8r / min, pelletizing The machine speed is 300r / min, and the antioxidant is compounded by pentaerythritol tetrapropionate and tris(2,4-di-tert-butylphenyl) phosphite at a mass ratio of 1:1;

[0088] b. Dry the granulation in step a in an oven at a temperature of 60°C overnight, mix it with 30% of the dried glass fiber and 0.2% of...

Embodiment 3

[0091] a. Weigh 75% polypropylene, 0.2% antioxidant, and 0.2% α-nucleating agent 2,2'-methylene-bis(4,6-di-tert-butylphenyl) sodium phosphate according to mass fraction, Placed in an oven at a temperature of 80℃ for 12h, put it in a high-speed mixer, mix it, and then add it to a twin-screw extruder for extrusion and granulation. The twin-screw parameters are: the temperature in the first zone is 150℃, and the temperature in the second zone is 170℃, three zone temperature is 200℃, four zone temperature is 210℃, five zone temperature is 210℃, head temperature is 200℃, twin screw speed is 80r / min, feeder speed is 5r / min, pelletizing The machine speed is 350r / min. The antioxidant is compounded by pentaerythritol tetrapropionate and tris(2,4-di-tert-butylphenyl) phosphite at a mass ratio of 1:1;

[0092] b. Dry the granulation in step a in an oven at a temperature of 60°C overnight, mix it with 24.5% of the dried glass fiber and 0.1% of the compatibilizer, and then extrude it in a twi...

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Abstract

The invention relates to a method for preparing a polypropylene composite. The method is characterized in that the polypropylene composite is prepared from polypropylene, a compatibilizer, glass fibers, a nucleating agent and an anti-oxidant according to a two-step process. The method comprises the following steps: the nucleating agent is utilized to induce crystal transfer of polypropylene; the glass fibers are compounded with polypropylene subjected to crystal transfer for further enhancement. Therefore, the problem that according to a traditional method in which polypropylene is directly mixed with a nucleating agent and fibers, the polypropylene crystallization behavior regulation and control functions of the nucleating agent cannot be effectively played due to introduction of the glass fibers serving as external impurities is solved. According to the method provided by the invention, regulation and control of the nucleating agent and enhancement of the glass fibers are effectively combined together to improve the combination property of the polypropylene composite, so that the polypropylene composite prepared by the method is not only excellent in comprehensive mechanical property but also high in thermal stability. Meanwhile, the raw materials (the glass fibers) are low in price and easily accessible, and a twin-screw extrusion process is simple and low in cost, so that large-scale production and application can be conveniently realized.

Description

Technical field [0001] The invention relates to a method for preparing a polypropylene composite material, in particular to a method for preparing a polypropylene composite material through the modification of glass fiber and a nucleating agent. Background technique [0002] As one of the five general plastics, polypropylene (PP) has the advantages of low price, low density, easy processing and good mechanical properties. With the continuous expansion of the application range, it has been applied to aerospace, food packaging, automotive and other fields . However, PP also has some shortcomings, such as: high shrinkage, low toughness and easy aging, sensitivity to light and heat, and low impact strength at low temperatures, which limit its further application. [0003] In order to expand the application range of PP, researchers have developed many methods to modify polypropylene, such as adding fillers or nucleating agents. Polypropylene is a polycrystalline polymer, and the commo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08K13/04C08K7/14C08K5/20C08K5/527C08K5/1575B29C47/92B29B9/06B29C48/92
CPCB29B9/06B29C48/92B29C2948/9258B29C2948/92704C08L23/12C08L2201/08C08L2205/24C08L2205/242C08L51/06C08K13/04C08K7/14C08K5/20C08K5/527C08K5/1575
Inventor 张亚刚崔林芳刘泽宇张乐涛徐鲁张岚王璐璐郅柯柯王朋磊周鑫
Owner XINJIANG TECHN INST OF PHYSICS & CHEM CHINESE ACAD OF SCI
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