Ink that can excite polychromatic light, its preparation method and application
A multi-color light and ink technology, applied in the field of fluorescent anti-counterfeiting labels, can solve the problems of easy cracking, high price, poor precision, etc., and achieve the effects of simple preparation process, cheap and easy-to-obtain raw materials, and good controllability
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Embodiment 1
[0023] Preparation of the first mixture: Stir and mix 4-vinylpyridine, acrylic solid resin, vinylpyrrolidone and water according to the mass ratio of 2:2.7:6:10; heat from room temperature to 65°C at a speed of 3°C / min and keep it warm for 20min , adding sodium hydroxide solution to adjust the pH to about 5, adding organic pigments and ethanol for thorough stirring, and finally adding a mixed solution of metal ions of copper sulfate and ferric chloride. Preparation of the second mixture: 3-aminophthalohydrazide and hydrogen peroxide were mixed at a ratio of 2.7:1, and then heated to 160° C. for 20 minutes. Preparation of the third mixture: the Tb 4 o 7 and Y 2 o 3 Dissolve in hydrochloric acid solution at a mass ratio of 1:2.5, adjust pH=5, heat to 100°C and keep for 20 minutes; add n-butanol and adjust pH=6 with aqueous sodium hydroxide solution, wherein n-butanol and Y 2 o 3 The mass ratio is 1.2:2.5 and kept at 80°C for 10min. First add the second mixture to the first...
Embodiment 2
[0027] The mass ratio of the first mixture, the second mixture and the third mixture is controlled at 1.2:1:3, and other conditions are the same as in Example 1.
[0028] When the three mixtures were mixed, there was a weak blue light with a duration of less than 5s in the absence of light excitation.
[0029] The excitation test is carried out with different wavelengths of light, and it can be found that the ink can emit strong blue fluorescence under the ultraviolet light of 365nm, and can emit strong green fluorescence under the ultraviolet light of 250nm.
Embodiment 3
[0031] The mass ratio of the first mixture, the second mixture and the third mixture is controlled at 1.4:1.2:4, and other conditions are the same as in Example 1.
[0032] When the three mixtures were mixed, there was no obvious fluorescence phenomenon in the absence of light excitation.
[0033] Using different wavelengths of light for excitation tests, it can be found that the ink can emit strong blue fluorescence under 370nm ultraviolet light, strong green fluorescence under 250nm ultraviolet light, and weak emission under 200nm purple light of red fluorescence.
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