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Ink that can excite polychromatic light, its preparation method and application

A multi-color light and ink technology, applied in the field of fluorescent anti-counterfeiting labels, can solve the problems of easy cracking, high price, poor precision, etc., and achieve the effects of simple preparation process, cheap and easy-to-obtain raw materials, and good controllability

Active Publication Date: 2020-09-18
上海云谟信息技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Existing security identification technologies generally have various technical defects such as complex production process, high price, poor precision, easy cracking, instability, and susceptibility to interference from external factors, which can no longer meet the needs of the development of information security in today's society

Method used

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  • Ink that can excite polychromatic light, its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Preparation of the first mixture: Stir and mix 4-vinylpyridine, acrylic solid resin, vinylpyrrolidone and water according to the mass ratio of 2:2.7:6:10; heat from room temperature to 65°C at a speed of 3°C / min and keep it warm for 20min , adding sodium hydroxide solution to adjust the pH to about 5, adding organic pigments and ethanol for thorough stirring, and finally adding a mixed solution of metal ions of copper sulfate and ferric chloride. Preparation of the second mixture: 3-aminophthalohydrazide and hydrogen peroxide were mixed at a ratio of 2.7:1, and then heated to 160° C. for 20 minutes. Preparation of the third mixture: the Tb 4 o 7 and Y 2 o 3 Dissolve in hydrochloric acid solution at a mass ratio of 1:2.5, adjust pH=5, heat to 100°C and keep for 20 minutes; add n-butanol and adjust pH=6 with aqueous sodium hydroxide solution, wherein n-butanol and Y 2 o 3 The mass ratio is 1.2:2.5 and kept at 80°C for 10min. First add the second mixture to the first...

Embodiment 2

[0027] The mass ratio of the first mixture, the second mixture and the third mixture is controlled at 1.2:1:3, and other conditions are the same as in Example 1.

[0028] When the three mixtures were mixed, there was a weak blue light with a duration of less than 5s in the absence of light excitation.

[0029] The excitation test is carried out with different wavelengths of light, and it can be found that the ink can emit strong blue fluorescence under the ultraviolet light of 365nm, and can emit strong green fluorescence under the ultraviolet light of 250nm.

Embodiment 3

[0031] The mass ratio of the first mixture, the second mixture and the third mixture is controlled at 1.4:1.2:4, and other conditions are the same as in Example 1.

[0032] When the three mixtures were mixed, there was no obvious fluorescence phenomenon in the absence of light excitation.

[0033] Using different wavelengths of light for excitation tests, it can be found that the ink can emit strong blue fluorescence under 370nm ultraviolet light, strong green fluorescence under 250nm ultraviolet light, and weak emission under 200nm purple light of red fluorescence.

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PUM

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Abstract

The invention discloses an ink capable of exciting polychromatic lights, a preparation method thereof and the application thereof. The ink capable of exciting the polychromatic lights comprises a first mixture, a second mixture and a third mixture, which are non-fluorescent in a normal state; the first mixture is water-based ink containing iron ions or copper ions; the second mixture contains 3-aminophthalhydrazide and hydrogen peroxide; in the second mixture, the mole ratio of the 3-aminophthalhydrazide to the hydrogen peroxide is (2.1-2.9):1; the third mixture contains normal butanol, Tb4O7 and Y203; the mass ratio of the first mixture to the second mixture and to the third mixture is (1-3):(1-8):(0.2-0.4). According to the ink capable of exciting the polychromatic lights, after being combined according to a specific mixing ratio, the three non-fluorescent mixtures in the normal state can generate blue lights with wavelengths of about 400 nm without being excited by the light of any waveband; the blue fluorescent lights are weakened after lasting for 30 seconds after being mixed; moreover, the ink can generate strong blue fluorescent lights under 360 nm ultraviolet lights and can generate strong green fluorescent lights under 256 nm ultraviolet lights.

Description

technical field [0001] The application belongs to the technical field of fluorescent anti-counterfeiting labels, and in particular relates to an ink capable of exciting polychromatic light, its preparation method and application. Background technique [0002] Today, with the surge in information volume, the security and accurate identification of information has become a topic of widespread concern in society. Existing security identification technologies generally have various technical defects such as complex production process, high price, poor precision, easy cracking, instability, and susceptibility to interference from external factors, which can no longer meet the needs of the development of information security in today's society. Taking two-dimensional barcodes as an example, the printed content can be seen intuitively, and can be easily copied using a readily available desktop copier or printing machine. [0003] Using anti-counterfeiting inks to form security mar...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/50C09D11/106C09D11/03C09D11/30
CPCC09D11/03C09D11/106C09D11/30C09D11/50
Inventor 朱文皓王强斌张叶俊汪胜郑云山
Owner 上海云谟信息技术有限公司
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