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Transparent hydrophobic and oleophobic functional coating material and transparent hydrophobic and oleophobic functional coating layer formed thereby

A hydrophobic and oleophobic functional coating technology, applied in the field of coatings, can solve the problems of difficult coating preparation and weak bonding between substrates, and achieve the effect of low cost and convenient operation

Inactive Publication Date: 2017-06-30
北京奥润联创微电子科技开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The common chemical method is to apply polyvinylidene fluoride, polytetrafluoroethylene, etc. to the surface of the substrate to form a hydrophobic coating. The hydrophobic and oleophobic effect of the substrate surface obtained in this way is good, but the maximum contact angle is 120 degrees. At the same time, due to the low surface energy of fluoropolymers, the bonding force between the fluoropolymer and the substrate is relatively weak, so it is difficult to prepare thinner coatings

Method used

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  • Transparent hydrophobic and oleophobic functional coating material and transparent hydrophobic and oleophobic functional coating layer formed thereby

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The fluorine-containing acrylic resin (10% fluorine content) is dissolved in butyl acetate to prepare a mass concentration of 5%. The silicon dioxide with a particle size of 10 nm was treated with an ethanol solution of tridecafluorooctyltrimethoxysilane, the hydrolysis time was 2 hours, and the silicon dioxide was centrifuged out, and dried in vacuum. The modified silicon dioxide is added to the resin solution with a concentration of 5% according to 1% of the weight of the resin, and after ultrasonication for 30 minutes, a uniform and transparent dispersion liquid is obtained. Clean the surface of the stainless steel sheet as the substrate, apply the dispersion to the surface of the stainless steel by the dip coating method, and dry the surface at 60°C after the surface is dry to obtain a hydrophobic and oleophobic coating film.

Embodiment 2

[0032] The fluorine-containing acrylic resin (30% fluorine content) is dissolved in toluene to prepare a mass concentration of 10%. The silicon dioxide with a particle size of 25nm was treated with tridecafluorooctyltriethoxysilane in isopropanol solution, the hydrolysis time was 2 hours, the silicon dioxide was centrifuged, and dried in vacuum. The modified silicon dioxide is added to the resin solution with a concentration of 10% according to 2% of the weight of the resin, and after ultrasonication for 40 minutes, a uniform and transparent dispersion liquid is obtained. Clean the surface of the stainless steel sheet as the substrate, apply the dispersion to the surface of the stainless steel by the dip coating method, and dry the surface at 60°C after the surface is dry to obtain a hydrophobic and oleophobic coating film.

Embodiment 3

[0034] Fluorocarbon resin (50% fluorine content) is dissolved in methyl ethyl ketone to prepare a mass concentration of 5%. The silicon dioxide with a particle diameter of 40nm was treated with n-butanol solution of heptadecafluorooctyltrimethoxysilane, the hydrolysis time was 2 hours, and the silicon dioxide was centrifuged out, and dried in vacuum. The modified silicon dioxide is added to the resin solution with a concentration of 5% according to 1% of the weight of the resin, and after ultrasonication for 30 minutes, a uniform and transparent dispersion liquid is obtained. The substrate polyimide (PI) plastic surface was cleaned, and the dispersion liquid was applied to the surface of PI by dip coating method. After the surface was dried, it was dried at 80°C to obtain a hydrophobic and oleophobic coating film.

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Abstract

The invention provides a transparent hydrophobic and oleophobic functional coating material. The transparent hydrophobic and oleophobic functional coating material is prepared from fluorine-containing resin, silicon dioxide particles and a solvent, wherein the mass concentration of the fluorine-containing resin is 5 to 15%; the mass of the silicon dioxide particles accounts for 1 to 5% of the mass of the fluorine-containing resin; the fluorine-containing resin contains at least one of fluorine-containing acrylic resin, fluorocarbon resin, fluorine-containing acrylic modified polyurethane resin and fluorine-containing acrylic modified organic silicon resin; the fluorine content of the fluorine-containing resin is 10 to 50wt%, the particle size of the silicon dioxide particles is 10 to 40 nanometers, and a modifying solvent uses a fluoroalkyl silane coupling agent to modify; the solvent is prepared from ethyl acetate, butyl acetate, isoamyl acetate, ethyl butyrate, acetone, butanone, cyclohexanone, methylbenzene, xylene or nonafluorobutyl ether. The invention also provides a transparent hydrophobic and oleophobic functional coating layer which is made of the transparent hydrophobic and oleophobic functional material.

Description

technical field [0001] The invention relates to the field of coatings, in particular to a transparent hydrophobic and oleophobic functional coating and the transparent hydrophobic and oleophobic functional coating formed therefrom. Background technique [0002] The lotus effect is also called the self-cleaning effect, which can be applied to many places, such as waterproof, oil-proof, self-cleaning of the glass surface, etc. By observing the surface of the lotus leaf with an electron scanning microscope, it will be found that there are some tiny protrusions on the surface of the lotus leaf. These tiny protrusions are micron-scale, and nano-scale protrusions are formed on the micron-scale protrusions. The lotus effect is mainly due to the superhydrophobic surface endowed by the stacking and interlacing of this micro-nano structure. Therefore, through the bionic simulation of this structure, functional coatings for waterproof and oil-proof can be prepared. [0003] There are ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/16C09D127/12C09D175/14C09D183/08C09D7/12
CPCC09D133/16C08K3/36C08K9/06C09D7/62C09D127/12C09D175/14C09D183/08
Inventor 郑冬琛
Owner 北京奥润联创微电子科技开发有限公司
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