Preparation method of high polymer damping plate with excellent noise reduction performance
A polymer and damping plate technology, which is applied in the field of damping plates, can solve the problems of environmental hazards, excessive material consumption, labor costs, etc., and achieve the effects of good physical and mechanical properties, good noise reduction performance, and short cycle time
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Embodiment 1
[0030] A method for preparing a polymer damping plate with excellent noise reduction performance, comprising the following steps:
[0031] (1) At -20°C, add deionized water, main initiator tricumyl chloride, LiCl, trifluoromethanesulfonic acid, the first monomer isobutylene, the second monomer alkylstyrene and isobutene into the reactor Pentadiene and tert-butyl acetate are uniformly mixed to obtain a mixed solution; the co-initiator is diluted with hexane or deionized water to obtain a co-initiator system;
[0032] Wherein, in the mixed solution, the concentration of tert-butyl acetate is 2×10 -4 mol / L; the molar ratio of tert-butyl acetate to initiator is 2:1; the co-initiator is a mixture of tris(pentafluorophenyl)gallium and tris(pentafluorophenyl)aluminum, the mass of both The ratio is 1:1; the content of LiCl in deionized water is 50wt%; the molar ratio of the first monomer to the second monomer is 10:1; the amount of trifluoromethanesulfonic acid added is 10wt% of the ...
Embodiment 2
[0038] A method for preparing a polymer damping plate with excellent noise reduction performance, comprising the following steps:
[0039] (1) At -100°C, add deionized water, main initiator water, H2SO4, sodium lauryl sulfate, the first monomer isobutylene, the second monomer alkylstyrene and isoprene to the reactor Alkene and triethylamine are mixed uniformly to obtain a mixed solution; the co-initiator is diluted with hexane or deionized water to obtain a co-initiator system;
[0040] Wherein, in the mixed solution, the concentration of triethylamine is 1×10 -2 mol / L; the molar ratio of triethylamine to initiator is 10:1; the co-initiator is a mixture of tris(pentafluorophenyl)gallium and tris(pentafluorophenyl)aluminum, the mass of both The ratio is 1:1; the content of H2SO4 in deionized water is 5wt%; the molar ratio of the first monomer to the second monomer is 70:1; the addition amount of sodium lauryl sulfate is 0.5wt of the monomer mass %;
[0041] (2) At -100°C, ad...
Embodiment 3
[0046]A method for preparing a polymer damping plate with excellent noise reduction performance, comprising the following steps:
[0047] (1) At -40°C, add deionized water, main initiator dicumyl chloride, HBF4, sodium lauryl sulfate, the first monomer isobutylene, the second monomer alkylstyrene, Propiophenone; co-initiator adopts hexane or deionized water dilution to make co-initiator system;
[0048] Wherein, in the mixed solution, the concentration of propiophenone is 2×10 -3 mol / L; the mol ratio of propiophenone and initiator is 4:1; Described co-initiator is the mixture of three (pentafluorophenyl) gallium, three (pentafluorophenyl) aluminum, and the mass ratio of the two is 1:1; the content of HBF4 in deionized water is 15wt%; the molar ratio of the first monomer to the second monomer is 20:1; the addition of sodium lauryl sulfate is 2wt% of the monomer mass;
[0049] (2) At -40°C, add the co-initiator system to the mixed solution in the reactor, carry out the polymer...
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