Anti-seepage coating layer with heavy metal chelating function as well as composition and application thereof
An anti-seepage coating and heavy metal technology, applied in the field of environmental governance, can solve the problems of heavy metal pollution in groundwater, uplift and rupture of anti-seepage membrane, etc., and achieve the effect of increasing mechanical strength, high efficiency and lasting effect, and low cost
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[0040] Such as figure 1 As shown, the method for preparing an impermeable coating with heavy metal chelating function provided by the embodiment of the present invention includes the following steps:
[0041] S101: Through active group siloxane, long-chain alkyl derivatives and polyamine structure compounds, all have a ring-opening reaction with the polyepoxy backbone molecule or the epoxy ring of the polyepoxy polymer;
[0042] S102: The polyether modified siloxane chain Rn and the long-chain alkyl group R f And polyamine structure R m Introduced into the polymer chain, polyepoxy main chain: polyether modified siloxane chain R n :Long chain alkyl R f :Polyamine chain R m The ratio is 5-50:1-10:1-10:1-10.
[0043] The present invention also provides an anti-seepage coating composition with heavy metal chelating function. The anti-seepage layer is combined with micro-nano particles, vinyl silicone oil, hydrogen-containing silicone oil and a catalyst to form an anti-seepage coating com...
Example Embodiment
[0058] Example 1
[0059] The anti-seepage coating with heavy metal chelating function provided by the embodiment of the present invention has the following structural characteristics:
[0060]
[0061] Wherein, x, y, z, g are all integers from 10-500;
[0062] R n Is aminosiloxane;
[0063] R f Is a hexyl hydroxy alcohol;
[0064] R m Is ethylenediamine;
[0065] The preparation method of the impermeable coating in the embodiment of the present invention is as follows: double parts of A epoxy resin 828, aminosiloxane, hexyl hydroxy alcohol, and ethylene diamine, with a molar ratio of 50:10:10:10, stirring and mixing uniformly, It is an impermeable layer with heavy metal chelating function.
[0066] The preparation method of the impermeable coating composition of the embodiment of the present invention is as follows: the impermeable coating, vinyl silicone oil, methyl silicone resin, diatomaceous earth, hydrogen-containing silicone oil, reaction inhibitor: chloroplatinic acid, molar rati...
Example Embodiment
[0069] Example 2
[0070] The anti-seepage coating with heavy metal chelating function provided by the embodiment of the present invention has the following structural characteristics:
[0071]
[0072] Wherein, x, y, z, g are all integers from 10-500;
[0073] R n Is a hydroxysiloxane;
[0074] R f Is dodecyl hydroxy alcohol;
[0075] R m Is diethylene triamine;
[0076] The preparation method of the impermeable coating in the embodiment of the present invention is: trimethylolpropane triglycidyl ether, hydroxysiloxane, lauryl hydroxy alcohol, diethylene triamine, and a molar ratio of 5:2:3:1 Mix and stir evenly to obtain the impermeable coating composition. .
[0077] The preparation method of the impermeable coating composition of the embodiment of the present invention is as follows: the impermeable coating, vinyl silicone oil, phenyl silicone resin, sepiolite, hydrogen-containing silicone oil, reaction inhibitor, caster catalyst, and molar ratio Mix the mixture at 50:30:10:10:5:1:...
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