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Preparation method of silicon-magnesium ceramic based complex fiber

A ceramic matrix composite and fiber technology is applied in the field of ceramic composite materials, which can solve the problems of poor compactness and poor mechanical properties, and achieve the effects of improving mechanical properties, increasing the degree of densification, and improving the stability of fiber formation.

Inactive Publication Date: 2017-11-24
常州市顺旭商贸有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The technical problem to be solved by the present invention: Aiming at the disadvantages of poor compactness and poor mechanical properties of traditional ceramic matrix composite materials, a preparation method of silicon-magnesium ceramic matrix composite fibers is provided

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0025] First take 40g tetraethyl orthosilicate, 5g carboxymethyl cellulose, add it to 1L ethanol solution with a mass fraction of 70%, and stir at 300r / min for 20min to obtain reaction solution A; then take 4g magnesium acetate, 3g citric acid, and 18g glucose , add 1L of deionized water, stir at 300r / min for 20min, then adjust the pH to 5.0 with 10% ammonia water to obtain reaction solution B; then mix reaction solution A and reaction solution B evenly and place in a vacuum drying oven , at 1kPa, stand still for 1h to obtain impregnating solution; take 10g of carbon fiber fabric and impregnating solution into a hydrothermal reaction kettle, conduct homogeneous hydrothermal treatment at 180°C for 6h, cool to room temperature and filter to obtain filter residue, put the filter residue in In a drying oven, dry to constant weight at 60°C to obtain a ceramic matrix composite fiber precursor; finally, put the ceramic matrix composite fiber precursor into a high-temperature vacuum fu...

example 2

[0027] First take 60g tetraethyl orthosilicate and 8g carboxymethyl cellulose, add it to 2L ethanol solution with a mass fraction of 70%, and stir at 350r / min for 25min to obtain reaction solution A; then take 6g magnesium acetate, 5g citric acid, and 27g glucose , add 2L deionized water, stir at 350r / min for 25min, then adjust the pH to 5.3 with 10% ammonia water to obtain reaction solution B; then mix reaction solution A and reaction solution B evenly and place in a vacuum drying oven , under 6kPa, stand still for 2h to obtain impregnating solution; take 15g of carbon fiber fabric and impregnating solution into a hydrothermal reaction kettle, conduct homogeneous hydrothermal treatment at 200°C for 7h, cool to room temperature and filter to obtain filter residue, put the filter residue in In a drying oven, dry at 70°C to constant weight to obtain a ceramic matrix composite fiber precursor; finally, put the ceramic matrix composite fiber precursor into a high-temperature vacuum...

example 3

[0029] First take 80g tetraethyl orthosilicate, 10g carboxymethyl cellulose, add it to 2L ethanol solution with a mass fraction of 70%, and stir at 400r / min for 30min to obtain reaction solution A; then take 8g magnesium acetate, 6g citric acid, and 36g glucose , add 2L of deionized water, stir at 400r / min for 30min, then adjust the pH to 5.5 with 10% ammonia water to obtain reaction solution B; then mix reaction solution A and reaction solution B evenly and place in a vacuum drying oven , under 10kPa, let it stand for 2 hours to obtain the impregnating liquid; take 20g of carbon fiber fabric and impregnating liquid and put them into a hydrothermal reaction kettle, conduct a homogeneous hydrothermal treatment at 220°C for 8 hours, and filter to obtain a filter residue after cooling to room temperature. In a drying oven, dry at 80°C to constant weight to obtain a ceramic matrix composite fiber precursor; finally, put the ceramic matrix composite fiber precursor into a high-tempe...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention discloses a preparation method of silicon-magnesium ceramic based complex fiber, and belongs to the field of ceramic complex materials. The preparation method comprises the following steps: mixing tetraethoxysilane, carboxymethyl cellulose and an ethanol solution to obtain a reaction solution A; then mixing magnesium acetate, citric acid, glucose and deionized water, and regulating the pH value with ammonia water to obtain a reaction solution B; uniformly mixing the reaction solution B with the reaction solution A to obtain a mixed solution, standing the mixed solution in a vacuum drying box to stand to obtain steeping liquor, and then mixing the steeping liquor with a carbon fiber fabric to perform hydro-thermal treatment, cooling to the room temperature and filtering to obtain filter residues, and drying the filter residues to obtain a ceramic based complex fiber precursor; then performing thermal-insulation heat treatment on the ceramic based complex fiber precursor, and cooling to the room temperature to prepare the silicon-magnesium ceramic based complex fiber. The preparation method has the beneficial effects that: the silicon-magnesium ceramic based complex fiber has relatively good compactness and mechanical property, and is worthy of the being popularized and used.

Description

technical field [0001] The invention relates to a preparation method of a silicon-magnesium ceramic-based composite fiber, which belongs to the field of ceramic composite materials. Background technique [0002] Ceramic matrix composites are a type of composite materials that are composited with ceramics as a matrix and various fibers. The ceramic matrix can be high-temperature structural ceramics such as silicon nitride and silicon carbide. It also refers to the introduction of reinforcing materials into the ceramic matrix to form a composite material with the introduced reinforcing material as the dispersed phase and the ceramic matrix as the continuous phase. The dispersed phase can be continuous fibers, particles or whiskers. [0003] At present, the preparation methods of ceramic matrix composites include chemical vapor infiltration method, polymer impregnation cracking method and slurry impregnation hot pressing method. [0004] The chemical vapor infiltration meth...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): C04B35/80C04B35/84C04B35/20C04B35/622C04B35/636C04B35/632
CPCC04B35/20C04B35/622C04B35/632C04B35/6365C04B35/80C04B2235/3826C04B2235/449C04B2235/96
Inventor 江建荣方晓俊王之霖
Owner 常州市顺旭商贸有限公司