Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Heat-resisting and flame-retardant epoxy resin adhesive

An epoxy resin glue, epoxy resin technology, applied in the direction of epoxy resin glue, novolac epoxy resin adhesive, adhesive, etc., can solve the problem of poor heat resistance and flame retardant performance, fracture energy and fracture Low toughness, limiting epoxy resin adhesives, etc., to achieve the effect of improving corrosion resistance and impact performance, reducing water absorption, and increasing curing speed

Inactive Publication Date: 2017-11-28
安徽大松树脂有限公司
View PDF4 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the fracture energy and fracture toughness of epoxy resin are far lower than those of other plastics, and they are not heat-resistant, and the defect of bond strength will decrease during use. At the same time, as an organic material, its flame retardancy is not good. The prepared adhesive has the defects of poor heat resistance and flame retardancy, which limits the application of epoxy resin adhesives

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] A heat-resistant and flame-retardant epoxy resin adhesive proposed by the present invention, its raw materials include by weight: 65 parts of epoxy resin containing fluorene structure, 15 parts of novolac epoxy resin, 10 parts of 2-ethyl-hexyl glycidyl ether 35 parts of 9,9-bis(4-aminophenyl)fluorene, 5 parts of pentamethyldipropylene triamine, 4.5 parts of curing accelerator, 20 parts of toughening agent, 8 parts of pentaerythritol, 1 part of ammonium polyphosphate, 15 parts of phosphorus nitrogen flame retardant, 0.2 parts of defoamer, 1.5 parts of stabilizer, 1 part of polyether ether ketone, 5 parts of calcium silicate, 1 part of chlorite, 4 parts of aluminum silicate, 1 part of magnesium oxide, 5 parts of expanded graphite.

Embodiment 2

[0016] A heat-resistant and flame-retardant epoxy resin adhesive proposed by the present invention, its raw materials include by weight: 85 parts of epoxy resin containing fluorene structure, 3 parts of novolac epoxy resin, 25 parts of 2-ethyl-hexyl glycidyl ether 20 parts of 9,9-bis(4-aminophenyl) fluorene, 12 parts of pentamethyldipropylene triamine, 2 parts of curing accelerator, 35 parts of toughening agent, 2 parts of pentaerythritol, 5 parts of ammonium polyphosphate, 2 parts of phosphorus nitrogen flame retardant, 1.3 parts of defoamer, 0.2 parts of stabilizer, 5 parts of polyether ether ketone, 2 parts of calcium silicate, 5 parts of chlorite, 1 part of aluminum silicate, 2 parts of magnesium oxide, 2 parts of expanded graphite.

Embodiment 3

[0018] A heat-resistant and flame-retardant epoxy resin adhesive proposed by the present invention, its raw materials include by weight: 83 parts of epoxy resin containing fluorene structure, 6 parts of novolac epoxy resin, 21 parts of 2-ethyl-hexyl glycidyl ether 26 parts of 9,9-bis(4-aminophenyl)fluorene, 11 parts of pentamethyldipropylenetriamine, 2.6 parts of 1-benzyl 2-methylimidazole, 20 parts of liquid silicone rubber, 12 parts of polyurethane, 4 parts of pentaerythritol, 3.9 parts of ammonium polyphosphate, 4 parts of phosphorus nitrogen flame retardant, 1.2 parts of defoamer, 0.5 parts of stabilizer, 4.3 parts of polyether ether ketone, 3.2 parts of calcium silicate, 4.1 parts of chlorite, silicic acid 2 parts of aluminum, 1.3 parts of magnesium oxide, 4 parts of expandable graphite;

[0019] Wherein, the phosphorus nitrogen flame retardant is prepared according to the following process: uniformly mix formaldehyde solution, diethanolamine and dibutyltin dilaurate, rea...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
peel strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses a heat-resisting and flame-retardant epoxy resin adhesive. The heat-resisting and flame-retardant epoxy resin adhesive is prepared from the following raw materials in parts by weight: 65 to 85 parts of epoxy resin with a fluorene-containing structure, 3 to 15 parts of phenolic epoxy resin, 10 to 25 parts of 2-ethyl-hexyl glycidyl ether, 20 to 35 parts of 9,9-bis(4-aminophenyl) fluorene, 5 to 12 parts of 2,6,10-trimethyl-2,6,10-triazaundecane, 2 to 4.5 parts of curing accelerator, 20 to 35 parts of flexibilizer, 2 to 8 parts of pentaerythritol, 1 to 5 parts of ammonium polyphosphate, 2 to 15 parts of phosphorus and nitrogen flame retardant, 0.2 to 1.3 parts of defoaming agent, 0.2 to 1.5 parts of stabilizer, 1 to 5 parts of polyetheretherketone, 2 to 5 parts of calcium silicate, 1 to 5 parts of chlorite, 1 to 4 parts of aluminum silicate, 1 to 2 parts of magnesium oxide and 2 to 5 parts of expandable graphite. The heat-resisting and flame-retardant epoxy resin adhesive disclosed by the invention has the advantages of high heat resistance, excellent flame retardant property and high bonding strength with a matrix.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a heat-resistant and flame-retardant epoxy resin adhesive. Background technique [0002] Epoxy resin refers to an organic compound containing two or more epoxy groups in its molecule. Its molecular chain contains active epoxy groups, which can cross-link with various types of curing agents to form insoluble resins. A polymer with a three-way network structure. The cured epoxy resin has good physical and chemical properties, and it has excellent bonding strength to the surface of metal and non-metal materials, and has become an important matrix material for adhesives. However, the fracture energy and fracture toughness of epoxy resin are far lower than those of other plastics, and they are not heat-resistant, and the defect of bond strength will decrease during use. At the same time, as an organic material, its flame retardancy is not good. The prepared adhesive has the defect...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/00C09J163/04C09J11/08C09J11/04C09J11/06
CPCC09J163/00C08K2003/222C08K2003/323C08K2201/014C08L2201/08C08L2205/02C08L2205/03C08L2205/035C08L2205/06C09J11/04C09J11/06C09J11/08C08L63/04C08L61/16C08K13/04C08K3/34C08K3/22C08K7/24C08K5/053C08K3/32C08K5/0066C08L75/04C08L83/04
Inventor 朱立芳
Owner 安徽大松树脂有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products