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High-ammonia nitrogen high-salt wastewater resourceful treatment method

A treatment method, high-salt wastewater technology, applied in multi-stage water treatment, water/sewage treatment, chemical instruments and methods, etc., can solve the problems of inability to realize energy reuse, blockage of stripping distillation tower, high equipment investment, etc. Achieve good economic benefits, reduce equipment costs, and simplify equipment

Active Publication Date: 2017-12-19
徐州赛科康仑智能装备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, since both stripping distillation and evaporation require continuous consumption of heat sources and high energy consumption, the traditional process usually heats the stripping distillation system and the evaporation system separately, which cannot realize the reuse of energy and consumes a large amount of steam; secondly, High-ammonia-nitrogen and high-salt wastewater usually contains strong corrosive ions. In the existing technical solutions, both stripping, rectification and evaporation work in a corrosive environment, which requires high equipment materials, which will inevitably lead to high investment in equipment; again, stripping The rectification tower works under strong alkaline conditions. Once the wastewater in the traditional process contains fouling components, it is easy to scale under alkaline conditions, resulting in blockage of the stripping rectification tower

Method used

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  • High-ammonia nitrogen high-salt wastewater resourceful treatment method
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  • High-ammonia nitrogen high-salt wastewater resourceful treatment method

Examples

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Effect test

Embodiment 1

[0034] An example of the application of single-effect evaporation and stripping distillation column coupling treatment of high-ammonia nitrogen and high-salt wastewater.

[0035] Wastewater 1 enters the single-effect forced circulation evaporation system for evaporation and crystallization, crystallized salt 6 is discharged from the system through centrifugal separation, raw steam 2 (about 0.4-0.5MPa) heats the wastewater in the evaporator, and the evaporated secondary steam 3 (about 0.3MPa ) as the heat source of the stripping and rectifying system enters the reboiler, the condensed water 4 is dilute ammonia water, enters the condensed water tank, and then pumps into the stripping and rectifying system for deamination, after multi-stage vapor-liquid balance, the concentration at the top of the tower is High-purity concentrated ammonia water 8 higher than 18%, the concentration of ammonia nitrogen in the effluent of the tower kettle meets the requirements (for example, less tha...

Embodiment 2

[0037] An example of the application of a three-effect evaporator coupled with a stripping distillation column to treat high-ammonia nitrogen and high-salt wastewater.

[0038] Wastewater 1 first enters the first-effect falling film evaporator for evaporation and concentration, then the first-effect effluent 2 enters the second-effect forced circulation evaporator, and the second-effect effluent 3 enters the third-effect forced circulation evaporator. Evaporated and dissolved by steam condensed water, the waste water is concentrated step by step until supersaturated and crystallized, and the crystallized salt 4 is separated by a centrifuge and discharged out of the system.

[0039] The raw steam 5 (about 0.7MPa) enters the shell side of the first-effect evaporator, and the evaporated mixed steam 6 (about 0.5MPa) of water vapor and ammonia vapor is used as the heat source of the second-effect evaporator, and the condensed water 7 of the second-effect evaporator enters Three-eff...

Embodiment 3

[0042] An example of the application of MVR coupled with stripping and rectifying towers to treat high-ammonia nitrogen and high-salt wastewater.

[0043] Wastewater 1 enters the forced circulation evaporation system to be evaporated and concentrated, and crystallized salt 6 is obtained after supersaturation, and is discharged from the system after centrifugation.

[0044] Raw steam 2 (about 0.3MPa) heats the evaporation system, and the condensed water is discharged out of the system. The secondary steam 3 (about 0.1MPa) generated by the evaporation system enters the steam compressor, and the enthalpy of the compressed secondary steam 4 increases (about 0.3MPa), and then enters the reboiler as a heat source for the stripping and rectifying system, and is condensed to obtain The dilute ammonia water 5 enters the condensed water tank, and the condensed water enters the stripping rectification system for deammonization treatment. After multi-stage vapor-liquid balance, the top of...

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Abstract

The invention discloses a high-ammonia nitrogen high-salt wastewater resourceful treatment method which comprises the following steps: with the combination of steam stripping distillation and evaporation, firstly, evaporating wastewater so as to obtain ammonia-containing steam and crystal salt; performing heat exchange on the ammonia-containing steam with a reboiler so as to provide a heat source to a steam stripping distillation tower; centrifuging the crystal salt, abd recycling the crystal salt; feeding weak aqua ammonia obtained after heat exchange of the ammonia-containing steam into the steam stripping distillation tower for deamination concentration so as to obtain ammonium hydroxide recycling, performing up-to-stand discharge on the effluent, or recycling the effluent for production. By adopting the method disclosed by the invention, secondary steam generated from evaporation is adopted as the heat source of the steam stripping distillation tower, steam condensate is adopted as fed water of the steam stripping distillation tower, no intense corrosion medium or caking component is introduced, requirements on equipment materials are reduced, meanwhile the problem that the steam stripping distillation tower is blocked is solved, the cost is reduced, and good market prospects are achieved.

Description

technical field [0001] The invention relates to the field of waste water treatment, in particular to a method for resourceful treatment of waste water with high ammonia nitrogen and high salt. Background technique [0002] At present, in the field of industrial high-ammonia nitrogen and high-salt wastewater treatment, the wastewater is usually first passed into the stripping rectification system for deamination treatment, and then enters the multi-effect evaporation system for desalination treatment, and finally achieves deamination and desalination and achieves the goal of qualified effluent water quality . [0003] However, since both stripping distillation and evaporation require continuous consumption of heat sources and high energy consumption, the traditional process usually heats the stripping distillation system and the evaporation system separately, which cannot realize the reuse of energy and consumes a large amount of steam; secondly, High-ammonia nitrogen and hi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/04C02F1/10C02F101/16
CPCC02F1/04C02F1/048C02F1/10C02F2101/16C02F2301/08
Inventor 刘晨明林晓康晨旭李金涛
Owner 徐州赛科康仑智能装备有限公司
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