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A kind of high temperature resistant, low migration organic smooth opening agent and master batch prepared from the opening agent

A technology of opening masterbatch and low migration, which is applied in the field of organic slippery anti-blocking agent and the masterbatch prepared by this anti-blocking agent. It can solve the problems of poor high temperature resistance, poor hand feeling, and high temperature resistance, and achieve surface smoothness. Improvement, good smooth effect, high temperature resistance effect

Active Publication Date: 2018-10-12
禾工(广州)材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the masterbatches on the market use oleic acid amide or erucic acid amide, as well as talcum powder, silicon dioxide, ultrafine calcium carbonate and barium sulfate in the preparation process, so that the prepared masterbatches have a certain Color, large amount added, poor hand feeling
In addition, the masterbatch made of oleic acid amide or erucic acid amide should generally be used at a temperature not higher than 260°C, and its high temperature resistance is poor; and its migration range is too large
[0006] At present, oleic acid amide and erucic acid amide are generally used as slip agents, and the addition amount is extremely low 1 to 3‰ (the dispersion effect is poor in this way), and it is easy to migrate and precipitate on the surface of the product and is not resistant to high temperature. ℃ will decompose more than half, so there will be limitations in use, many high-temperature materials cannot be used, and the general products that need to be printed will not be printed due to precipitation, and the precipitation will also lead to composite film products that cannot be laminated, and it will take a long time Stored long glued together etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A high-temperature-resistant, low-migration organic slippery anti-blocking agent is obtained by mixing 25% by weight of pentaerythritol stearate, 25% by weight of ethylene bisoleic acid amide and 50% by weight of behenic acid amide.

[0025] The anti-blocking agent can be used alone as a masterbatch, and the method for making the anti-blocking agent into a carrier-free, high-temperature-resistant, low-migration organic slippery anti-blocking agent masterbatch is as follows:

[0026] 1. Extrusion method: Mix the components and feed them into the screw extruder, extrude and cut into pellets to obtain carrier-free, high-temperature-resistant, low-migration organic smooth open masterbatch. The obtained masterbatch can withstand high temperature 350°C , and dispersed well, no migration.

[0027] 2. Dropping bead granulation method: Mix and heat the components to 120 degrees to melt, then cool down to 90 degrees and stir for 20 minutes, then filter the materials and send them...

Embodiment 2

[0030] A kind of high temperature resistant, low-migration organic slippery opening agent, the opening agent consists of 35wt% pentaerythritol stearate, 30wt% ethylene bisoleic acid amide and stearyl erucamide mixture (its mixing mass ratio is 2:1) and 35wt% mixture of behenic acid amide and polymethyl methacrylate (the mixing mass ratio is 1:2).

[0031] The anti-blocking agent can be used alone as a masterbatch, and the method for making the anti-blocking agent into a carrier-free, high-temperature-resistant, low-migration organic slippery anti-blocking agent masterbatch is as follows:

[0032] 1. Extrusion method: Mix the components and feed them into the screw extruder, extrude and cut into pellets to obtain carrier-free, high-temperature-resistant, low-migration organic smooth open masterbatch. The obtained masterbatch can withstand high temperature 350°C , and dispersed well, no migration.

[0033] 2. Dropping bead granulation method: Mix and heat the components to 120 ...

Embodiment 3

[0036] A high-temperature-resistant, low-migration organic slippery opening agent is obtained by mixing 40 wt % of pentaerythritol stearate, 30 wt % of stearyl erucamide and 30 wt % of polymethyl methacrylate.

[0037] The anti-blocking agent can be used alone as a masterbatch, and the method for making the anti-blocking agent into a carrier-free, high-temperature-resistant, low-migration organic slippery anti-blocking agent masterbatch is as follows:

[0038]1. Extrusion method: Mix the components and feed them into the screw extruder, extrude and cut into pellets to obtain carrier-free, high-temperature-resistant, low-migration organic smooth open masterbatch. The obtained masterbatch can withstand high temperature 350°C , and dispersed well, no migration.

[0039] 2. Dropping bead granulation method: Mix and heat the components to 120 degrees to melt, then cool down to 90 degrees and stir for 20 minutes, then filter the materials and send them to the constant pressure pump,...

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PUM

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Abstract

The invention discloses a heat-resistant and low-migrating organic smooth opening agent which is obtained by mixing of, by weight, 25-50wt% of component A, 25-50wt% of component B and 25-50wt% of component C. The component B refers to pentaerythritol fatty acid ester, the component B refers to one or two selected from ethylene bis oleamide and stearyl erucic acid amide, and the component C refers to one or two selected from behenamide and polymethyl methacrylate; ethylene bis oleamide and stearyl erucic acid amide are in the mass ratio of 2:1-1:2 when used simultaneously; behenamide and polymethyl methacrylate are in the mass ratio of 2:1-1:2 when used simultaneously. A carrier-free opening-agent master batch obtained with the above formula has the advantages of smoothness, opening, lubricating, demolding and no folding out of the surface in plastics, and the opening agent is resistant to high temperature to 350DEG C, low in migration and uniform in dispersion and is used for preparing the heat-resistant and smooth plastic master batch.

Description

technical field [0001] The invention relates to the technical field of preparation of plastic masterbatches, more specifically, to a high-temperature-resistant, low-migration organic slippery anti-blocking agent and a masterbatch prepared from the anti-blocking agent. Background technique [0002] Plastic raw materials can only be made into plastic materials through processing. The most commonly used methods for forming (thermoplastic) under high temperature conditions are extrusion, injection molding, calendering, casting, blow molding, blister and thermoforming. Plastic materials have the advantages of light weight, high strength, excellent electrical properties, easy processing and molding, and bright colors, so they have become the most active field of material systems, and their applications in other fields are also expanding. From people's daily necessities, medical , agriculture and fishery, automobile, electrical and chemical construction, defense industry, aerospace...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J3/22C08K5/00C08K5/103C08K5/20C08L33/12
CPCC08J3/223C08K5/00C08K5/103C08K5/20C08K2201/014C08L33/12
Inventor 吴贵岚高军高嘉芃
Owner 禾工(广州)材料科技股份有限公司
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