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Metal-plastic double-layer combined part and preparation method thereof

A joint and plastic technology, applied in the direction of coating, etc., can solve the problems such as the thermal conductivity of joints, the thermal conductivity of metal and plastic joints, and poor thermal conductivity, etc., to achieve good thermal conductivity and good thermal conductivity. Interface strength, the effect of improving the binding force

Active Publication Date: 2018-01-05
ZHEJIANG NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] In the prior art, there are few studies on the thermal conductivity of metal-plastic composite structures, and metal-plastic composite structures generally have the problem of poor thermal conductivity
For example, CN101578018A discloses that the metal body is used as an insert and molded by injecting molten plastic after cooling. The material of the plastic part is selected from liquid crystal polymers, polyphenylene sulfide, and polybutylene terephthalate. To the thermal conductivity of the bonding parts; CN201726613U discloses that the plastic part is used as the shell, and the inner surface of the plastic part has an adhesive layer, and the metal film layer is sprayed with powdery metal material on the adhesive layer on the inner surface of the plastic part, and cooled by high-temperature hot melt post-molding, but does not mention the thermal conductivity of metal and plastic joints; CN103673739A discloses that the material of the thermally conductive plastic layer is a polymer and a modified polymer-based composite material, and the heat dissipation efficiency is improved through the micro-nano structure of plastic processing, but No mention of thermal conductivity of metal to plastic joints

Method used

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  • Metal-plastic double-layer combined part and preparation method thereof
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  • Metal-plastic double-layer combined part and preparation method thereof

Examples

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preparation example Construction

[0030] The present invention also provides a method for preparing the metal-plastic double-layer combination described in the above technical solution, comprising the following steps:

[0031] Mix carbon fiber with boron nitride and PA66 to obtain PA66 composite material;

[0032] Surface-treating the aluminum alloy metal plate to obtain a metal plate with micropores on the surface;

[0033] performing plasma activation on the metal plate with micropores on the surface to obtain an activated metal plate;

[0034] Injection molding the PA66 composite material on the surface of the activated metal plate to obtain a molded sample;

[0035] The molded sample is subjected to heat preservation treatment to obtain a metal-plastic double-layer combination.

[0036] The invention mixes carbon fiber, boron nitride and PA66 to obtain PA66 composite material. In the present invention, the humidity of the PA66 composite material is preferably less than 0.2%. In the present invention, t...

Embodiment 1

[0048] 45 parts of PA666, 20 parts of carbon fiber (diameter 5 μm, length 0.5 mm), 35 parts of hexagonal boron nitride BN (diameter 5 μm, thickness 100 nm), after mixing evenly, add to the feeding port of the twin-screw extruder, twin-screw extruder The temperature of the 5 extrusion temperature zones of the extruder is 270° C., and the rotation speed of the extrusion screw is 80 rpm for extrusion granulation.

[0049] Select an aluminum alloy 6063 plate of 2mm×Ф12.7mm, wash away the iron filings stains on the surface of the machined aluminum sheet with deionized water, place the aluminum sheet in a 5% NaOH solution, make the solution immerse the aluminum sheet sample, and ultrasonically Take out after shaking for 5 minutes. Then put the shaken aluminum sheet into acetone, soak for 30s, remove the remaining NaOH solution on the surface, and then perform anodic oxidation microporous treatment on the aluminum alloy plate to obtain a metal plate with a micropore diameter of 40nm....

Embodiment 2

[0057] 45 parts of PA666, 25 parts of carbon fiber (diameter 20μm, length 6mm), 30 parts of hexagonal boron nitride BN (diameter 35μm, thickness 300nm), after mixing evenly, add to the feeding port of the twin-screw extruder, twin-screw extrusion The temperature of the 8 extrusion temperature zones of the machine is 260° C., the rotation speed of the extrusion screw is 150 rpm, and extrusion granulation is performed.

[0058] Select an aluminum alloy 6063 plate of 2mm×Ф12.7mm, wash away the iron filings stains on the surface of the machined aluminum sheet with deionized water, place the aluminum sheet in a 5% NaOH solution, make the solution immerse the aluminum sheet sample, and ultrasonically Take out after shaking for 5 minutes. Then put the shaken aluminum sheet into acetone, soak for 30s, remove the remaining NaOH solution on the surface, and then perform micro-porous treatment on the aluminum alloy plate to obtain a metal plate with a micro-pore diameter of 20 μm.

[00...

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Abstract

The invention provides a metal-plastic double-layer combined part, and belongs to the field of metal-plastic composite structures. The metal-plastic double-layer combined part comprises an aluminum alloy metal sheet layer and a PA66 composite layer, and in composition, the PA66 composite layer comprises, by weight, 10-30% of carbon fiber, 20-40% of boron nitride and the balance PA66. In the metal-plastic double-layer combined part, carbon fiber has high strength and thermal conductivity, boron nitride also has high thermal conductivity, and the addition of carbon fiber and boron nitride is beneficial to forming a thermal conduction network in PA66 and improving thermal conductivity; besides, due to the physical and chemical effects of the aluminum alloy metal sheet layer and the PA66 composite layer, the interface strength of the metal-plastic double-layer combined part is improved. Embodiment data shows that the thermal diffusion coefficient of the metal-plastic double-layer combinedpart is 2.88 m<2> / s, the interface strength of the metal-plastic double-layer combined part is 5.52 MPa, and the metal-plastic double-layer combined part has high thermal conductivity and interface strength.

Description

technical field [0001] The invention relates to the technical field of metal-plastic composite structures, in particular to a metal-plastic double-layer combination and a preparation method thereof. Background technique [0002] With the continuous development of science and technology, various product components have higher and higher requirements for the comprehensive performance of materials. How to combine the advantages of various materials together to make the designed components have good thermal conductivity, and have light weight, The feature of high strength has always been one of the hot topics of discussion among product designers today. [0003] In the prior art, there are few studies on the thermal conductivity of metal-plastic composite structures, and metal-plastic composite structures generally have the problem of poor thermal conductivity. For example, CN101578018A discloses that the metal body is used as an insert and molded by injecting molten plastic af...

Claims

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Application Information

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IPC IPC(8): C08L77/06C08K7/06C08K3/38B29C45/14B29C45/76B29C45/77
Inventor 李熹平徐东厚宫宁宁曾水萍刘兴茶汪彬
Owner ZHEJIANG NORMAL UNIVERSITY
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