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Nano-composite foam rope and preparation method thereof

A nano-composite and nano-modification technology, applied in the field of ropes, can solve the problems of reduced toughness of materials, increased weight of product parts, narrow molecular weight distribution, etc., and achieves high dimensional stability, improved work efficiency, and simple preparation methods.

Inactive Publication Date: 2018-01-19
界首市宏利塑料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the molecular chain of ordinary polypropylene is a linear structure, and the molecular weight distribution is relatively narrow, which leads to the disadvantages of low rigidity, poor heat resistance, large shrinkage, and low melt strength of polypropylene. In thermoforming processing, when the temperature is higher than the melting point After that, the melt strength and viscosity drop sharply, resulting in uneven wall thickness of the product during thermoforming, edge bending, shrinkage, and cell collapse during extrusion, foaming, etc. during extrusion, coating, and calendering. Applications of propylene in thermoforming, foaming, extrusion coating, blow molding, etc.
[0003] In order to overcome these problems, inorganic fillers are usually added, but conventional filler modification usually requires a large amount of addition, which often affects the molding and processing performance of the product, and also reduces the toughness of the material, and significantly increases the density of polypropylene. Thereby increasing the weight of product parts, and material recycling is difficult, which is not conducive to energy saving and environmental protection requirements

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] (1) Preparation of nano-modified polypropylene

[0026] Add 1kg of alkali-free glass powder to a ball mill and grind it through the first sieve with a mesh of 60 mesh to obtain alkali-free glass ultrafine powder. Mix the alkali-free glass ultrafine powder with 15kg purified water, and add 0.8kg dodecane while stirring. Sodium sulfonate, stirring at constant temperature for 2 hours, centrifugal separation, drying, and grinding through a 100-mesh second sieve to obtain modified alkali-free glass ultrafine powder with a particle size of 25nm;

[0027] Add 70kg polypropylene, 16kg modified alkali-free glass superfine powder and 14kg dibenzoic acid grafted polyisobutylene into the screw extruder for extrusion molding and granulation, and the extrusion temperature is 240°C to obtain nano-modified polypropylene;

[0028] (2) Preparation of nano composite foam rope

[0029] Add 65kg of nano-modified polypropylene, 11kg of wool fiber, 6kg of methylpropyl naphthyl phosphate, 10kg of trim...

Embodiment 2

[0031] (1) Preparation of nano-modified polypropylene

[0032] Add 1kg of alkali-free glass powder to a ball mill and grind it through the first sieve with a mesh of 60 mesh to obtain alkali-free glass ultrafine powder. Mix the alkali-free glass ultrafine powder with 10kg purified water, and add 0.5kg dodecane while stirring. Sodium sulfonate, stir at constant temperature for 2 hours, centrifuge, dry, and grind through a second sieve of 100 mesh to obtain modified alkali-free glass ultrafine powder with a particle size of 55nm;

[0033] Add 85kg of polypropylene, 10kg of modified alkali-free glass ultrafine powder and 5kg of oxalic acid grafted polyepoxypentene to the screw extruder for extrusion molding and granulation, and the extrusion temperature is 260°C to obtain nano-modified polypropylene;

[0034] (2) Preparation of nano composite foam rope

[0035] 80kg of nano-modified polypropylene, 4kg of fruit fiber, 1kg of cotton, 2.5kg of methyl propyl naphthyl phosphate, 5.2 kg of tri...

Embodiment 3

[0037] (1) Preparation of nano-modified polypropylene

[0038] Add 1kg of alkali-free glass powder to the ball mill and grind it through the first sieve of 60 mesh to obtain alkali-free glass ultrafine powder. Mix the alkali-free glass ultrafine powder with 12kg purified water, and add 0.6kg dodecane while stirring. Sodium sulfonate, stirring at constant temperature for 2.5 hours, centrifugal separation, drying, and grinding through a 100-mesh second sieve to obtain modified alkali-free glass ultrafine powder with a particle size of 69nm;

[0039] Add 82kg of polypropylene, 8kg of modified alkali-free glass superfine powder and 10kg of 3-cis-isobutenyl benzoyl isocyanate to the screw extruder for extrusion molding and granulation, and the extrusion temperature is 255°C to obtain nano-modified polypropylene;

[0040] (2) Preparation of nano composite foam rope

[0041] The nano-modified polypropylene 78kg, cotton 2.5kg, gypsum microfiber 7kg, methylpropyl naphthyl phosphate 3.8kg, trim...

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PUM

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Abstract

The invention discloses a nano-composite foam rope and a preparation method thereof. The nano-composite foam rope comprises the following raw materials by weight: 65% to 80% of nano-modified polypropylene, 5% to 11% of natural fiber, 2.5% to 6% of methyl propyl naphthyl phosphate, 4% to 10% of trimethyl oxalate acetate, 2% to 6% of a compound stabilizer, 0.2% to 0.7% of magnesium oxalate, 1% to 3%of a defoaming agent and 0.8% to 1.6% of an antioxidant. A surfactant is used for surface treatment of alkali-free glass powder to obtain modified alkali-free glass superfine powder, the modified alkali-free glass superfine powder is used for nano-modified filling of polypropylene to obtain nano-modified polypropylene, the rigidity is improved, toughness and dimensional stability are high, thermal expansion rate is low, melt strength of the nano-modified polypropylene is increased by 5-7 times, the nano-modified polypropylene has good low temperature toughness, and can withstand impact of lowtemperature of-30 DEG C; the preparation method is simple, the work efficiency is improved, the filled nano-filler is comparable with 5-time-filled ordinary packing in rigidity, cost is greatly reduced, and the prepared nano-composite foam rope has high strength, good toughness and long service life.

Description

Technical field [0001] The invention relates to the field of ropes, in particular to a nano composite foamed rope and a preparation method. Background technique [0002] Foam rope is a kind of plastic rope, the main component is polypropylene, which is a kind of thermoplastic resin made by polymerization of propylene. Compared with other thermoplastic resins, polypropylene has low density, high melting point, wide source and price. Low, excellent mechanical properties, good chemical stability and other characteristics, has become an indispensable basic raw material for packaging, light industry, construction, electronics, electrical appliances and automobiles. However, the molecular chain of ordinary polypropylene has a linear structure and the molecular weight distribution is relatively narrow, which leads to the disadvantages of low rigidity, poor heat resistance, large shrinkage, and low melt strength. In thermoforming processing, when the temperature is higher than the meltin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F8/06D01F8/02D01F8/18D01F1/10D07B1/02D01D5/098
Inventor 刘立平刘立华闫学峰刘立中王丽
Owner 界首市宏利塑料股份有限公司
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