Self-cleaning coating for metal substrate and preparation method and use method thereof

A metal-based, self-cleaning technology, applied in anti-corrosion coatings, anti-fouling/underwater coatings, polyurea/polyurethane coatings, etc., can solve problems such as poor scrub resistance, reduced deformation, and poor weather resistance, achieving high market value, Effect of reducing deformation and low cost

Inactive Publication Date: 2018-03-13
广州市泰宇科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its self-cleaning layer can decompose organic pollutants adsorbed on the surface of titanium dioxide into CO by using the photocatalytic reaction of titanium dioxide. 2 and H 2 O, together with the remaining inorganic matter, it can be washed away by normal clean water or rainwater, so as to realize the self-cleaning function, and also decompose the organic matter emitted by the car to a certain extent. The polyvinyl alcohol contained in the self-cleaning layer is a kind of Excellent emulsifiers and adhesives can not only balance the material distribution of the self-cleaning coating, but also improve its tensile strength and wear resistance; the polyurethane contained in the middle layer has corrosion resistance and can prevent the self-cleaning coating It corrodes or decomposes the metal substrate by direct contact with the metal substrate. The nano-silica contained in the middle layer can improve the coating’s poor suspension stability, poor thixotropy, poor weather resistance, and poor scrub resistance, so that the combination of the coating film and the metal substrate The strength is greatly improved, the hardness of the coating film is increased, and the self-cleaning ability of the surface is also enhanced. In addition, the nano-talc powder included can improve the stability of the product shape, increase the tensile strength, shear strength, flexural strength, and pressure strength, reduce deformation, Elongation, thermal expansion coefficient, high whiteness, etc.

Method used

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  • Self-cleaning coating for metal substrate and preparation method and use method thereof

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preparation example Construction

[0057] The present invention also provides a kind of preparation method for the self-cleaning coating of metal base simultaneously, comprises the following steps:

[0058] S1. Select coating raw materials: by mass parts, select polyurethane 62-78.5, nano silicon dioxide 4.2-8.6, butyl acetate 6.5-15, nano talcum powder 5-8, nano titanium dioxide 16-23, ethanol 21-31, propanol 7-15.2, polyvinyl alcohol 4-9.5;

[0059] S2. Prepare the middle layer material: Mix the butyl acetate and polyurethane selected in S1 to form a solution at 10°C-30°C, then add nano-talc powder and nano-silicon dioxide, and stir until it is in an emulsion liquid state, and let it stand After 3h-5h, the intermediate layer coating is obtained;

[0060] S3. Preparation of self-cleaning layer material: mix propanol and ethanol selected in S1 at 10°C-30°C and stir evenly, then add nano titanium dioxide and polyvinyl alcohol into the mixed solution of propanol and ethanol, and stir When it is in emulsion liqu...

Embodiment 1

[0066] Raw material quality: polyurethane 62g, nano silicon dioxide 4.2g, butyl acetate 6.5g, nano talc powder 5g, nano titanium dioxide 16g, ethanol 21g, propanol 7g, polyvinyl alcohol 4g.

[0067] Preparation:

[0068] S1. Select coating raw materials: In terms of parts by mass, 62g of polyurethane, 4.2g of nano-silica, 6.5g of butyl acetate, 5g of nano-talcum powder, 16g of nano-titanium dioxide, 21g of ethanol, 7g of propanol, and polyethylene Alcohol 4g;

[0069] S2. Preparation of the middle layer material: After mixing the butyl acetate and polyurethane selected in S1 to form a solution at 10°C, add nano-talc powder and nano-silica, and stir until it is in an emulsion liquid state. After standing for 3 hours, Get the intermediate coating;

[0070] S3. Preparation of self-cleaning layer material: Mix the propanol and ethanol selected in S1 at 10°C and stir evenly, then add nano-titanium dioxide and polyvinyl alcohol into the mixed solution of propanol and ethanol, and ...

Embodiment 2

[0077] Raw material quality: polyurethane 78.5g, nano silicon dioxide 8.6g, butyl acetate 15g, nano talc powder 8g, nano titanium dioxide 23g, ethanol 31g, propanol 15.2g, polyvinyl alcohol 9.5g.

[0078] Preparation:

[0079] S1. Select coating raw materials: In terms of parts by mass, 78.5g of polyurethane, 8.6g of nano-silicon dioxide, 15g of butyl acetate, 8g of nano-talcum powder, 23g of nano-titanium dioxide, 31g of ethanol, 15.2g of propanol, poly Vinyl alcohol 9.5g;

[0080] S2. Prepare the middle layer material: mix the butyl acetate and polyurethane selected in S1 to form a solution at 30°C, then add nano-talc powder and nano-silicon dioxide, and stir until it is in an emulsion liquid state. After standing for 5 hours, Get the intermediate coating;

[0081] S3. Preparation of self-cleaning layer material: Mix the propanol and ethanol selected in S1 at 30°C and stir evenly, then add nano-titanium dioxide and polyvinyl alcohol into the mixed solution of propanol and ...

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Abstract

The invention belongs to the technical field of coatings and particularly relates to a self-cleaning coating for a metal substrate and a preparation method and use method thereof. The self-cleaning coating for a metal substrate comprises an intermediate layer and a self-cleaning layer. The intermediate layer is sprayed on a metal substrate and the self-cleaning layer is sprayed on the intermediatelayer. The intermediate layer comprises polyurethane, nano-silica, butyl acetate and nano-talcum powder. The self-cleaning layer comprises nanometer titanium dioxide, ethanol, propanol and polyvinylalcohol. The self-cleaning coating for a metal substrate can utilize a photocatalytic reaction of titanium dioxide in the self-cleaning layer to realize a self-cleaning function. The polyurethane in the intermediate layer has corrosion resistance and prevents the self-cleaning layer from directly contacting with the metal substrate to inhibit metal substrate corrosion or decomposition.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a self-cleaning coating for metal substrates, a preparation method and an application method thereof. Background technique [0002] Stain resistance has always been an important indicator for evaluating the quality of coatings. However, the current coatings generally have problems of poor stain resistance or unsustainable stain resistance. At the same time, there are also problems of paint corrosion or decomposition of base materials. This is both It affects the beauty of the coated object and increases the maintenance cost. Moreover, people pay more and more attention to environmental protection issues nowadays. Therefore, it is urgent to develop a coating that can be self-cleaning, environmentally friendly and does not damage its substrate. question. This is especially true for metal substrates. Nowadays, metal materials are widely used because of their excellent ...

Claims

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Application Information

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IPC IPC(8): C09D175/04C09D7/61C09D129/04C09D5/08C09D5/16B05D5/00B05D7/14B05D7/24
CPCC09D175/04B05D5/00B05D7/14B05D7/24B05D7/54B05D2451/00B05D2503/00B05D2601/20B05D2601/22B05D2602/00C08K3/34C08K3/36C08K2003/2241C08K2201/011C09D5/08C09D5/1681C09D129/04B05D2420/01B05D2401/10
Inventor 单泰雷
Owner 广州市泰宇科技发展有限公司
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