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Phase-change microcapsule-based heat conducting potting silica gel comprising flame retardant and preparation method thereof

A phase change microcapsule, thermal conductivity potting technology, applied in chemical instruments and methods, adhesives, adhesive additives, etc., can solve the problems of poor thermal conductivity, poor compatibility, penetration and migration, etc., and achieve thermal conductivity and heat storage. Good temperature control performance, ensure temperature uniformity, and increase the effect of uniform dispersion

Active Publication Date: 2018-03-20
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the heat conduction agent in the phase change composite material in this patent application is expanded graphite, which has limited adsorption capacity for phase change materials, and repeated use will cause serious problems of melt flow and permeation migration of phase change materials; in addition, expanded graphite heat conduction fillers It will seriously affect the insulation performance of potting silica gel, which is not conducive to the potting application in conductive occasions. As a thermal management system for power batteries, it has a great impact on the overall safety and reliability of power batteries, so it is not suitable for popularization and application; secondly, the The heat-conducting agent used in the heat-conducting silica gel in the patent application is alumina and magnesia, which have not undergone surface treatment, and the compatibility between the directly added filler and the silica gel matrix is ​​poor, resulting in the uniform dispersion of the heat-conducting filler in the silica gel matrix Poor performance, increased thermal resistance at the phase interface between filler / matrix, and poor thermal conductivity

Method used

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  • Phase-change microcapsule-based heat conducting potting silica gel comprising flame retardant and preparation method thereof
  • Phase-change microcapsule-based heat conducting potting silica gel comprising flame retardant and preparation method thereof
  • Phase-change microcapsule-based heat conducting potting silica gel comprising flame retardant and preparation method thereof

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preparation example Construction

[0034] The phase-change microcapsules described in the present invention can be commercially available phase-change microcapsules, for example, paraffin alkane can be used as the core material, urea-formaldehyde resin is used as the shell, and a thermally conductive filler is also contained. The thermally conductive filler is coated with paraffin wax in the urea-formaldehyde resin. The low-temperature heat-controlled phase-change microcapsules are added in the alkane process, and the heat-conducting filler is added in an amount of 5% to 30% of the paraffin alkane mass percentage. The specific preparation method of the low-temperature thermally controlled phase change microcapsules, for example, may include: the first step, paraffin alkane preheating; the second step, urea-formaldehyde resin prepolymer synthesis; the third step, styrene maleic anhydride resin solution , water and inorganic salt polymerization; the fourth step, the materials are mixed to obtain the mixture; the f...

Embodiment 1

[0052] ① Weigh 7g of thermally conductive filler nano-alumina powder and 0.07g of silane coupling agent n-octyltriethoxysilane, prepare n-octyltriethoxysilane and water at a mass ratio of 1:3 to make a solution, add Proper amount of ethanol was mixed evenly and allowed to stand for 20 minutes. Slowly add the hydrolyzed silane coupling agent solution into the thermally conductive filler, stir well until it is uniformly dispersed, and heat and stir the mixed solution in a water bath at 65°C, so that the hydrolyzed silane coupling agent can perform surface treatment on the thermally conductive filler , to obtain a surface-treated thermally conductive filler mixture. Centrifuge the surface-treated thermally conductive filler mixture at a centrifugal speed of 1500r / min for 6 minutes for solid-liquid separation and separate the thermally conductive filler solid matter, and place the thermally conductive filler solid material in a 75°C drying oven for vacuum drying treatment After 1...

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Abstract

The invention relates to a phase-changing microcapsule-based heat conducting potting silica gel comprising flame retardant and a preparation method thereof. The heat conducting potting silica gel is prepared from 40 to 89 percent of dual-component potting silica gel, 5 to 20 percent of phase-changing microcapsule, 5 to 20 percent of surface treated heat conducting filler, and 1 to 20 percent of flame retardant. The preparation method comprises the following steps: treating the surface of the heat conducting filler; preparing heat conducting composite filler; preparing a component A and a component B in the dual-component potting silica gel; preparing a component A1 and a component B1 in the heat conducting potting silica gel; and preparing the heat conducting potting silica gel. Accordingto the preparation method, the surface of the heat conducting filler is treated in the preparation process, so that the dispersity of the heat conducting filler in a silica gel matrix is improved, theheat conduction performance of the heat conducting potting silica gel is improved, and by adding the phase changing microcapsule, the heat conducting potting silica gel has heat storage temperature control performance. The heat conducting potting silica gel has good heat conduction performance and heat storage temperature control performance.

Description

technical field [0001] The invention relates to the technical field of battery heat management, in particular to a phase-change microcapsule-based heat-conducting potting silica gel containing a flame retardant and a preparation method thereof. Background technique [0002] Batteries such as secondary batteries have been widely used as energy sources for wireless mobile devices, such as power sources for electric vehicles, hybrid electric vehicles, and plug-in hybrid electric vehicles, etc., thereby solving problems caused by vehicles using petroleum fuels. For issues such as air pollution, small wireless mobile devices may use one or more battery cells, while medium or large wireless devices such as vehicles may use medium or large battery modules that include multiple battery cells connected to each other. Or large battery modules are usually manufactured to have the smallest possible size and weight, so the battery cells stacked in these battery modules are highly integra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J183/07C09J183/05C09J11/04C09J11/06C09J11/08C09J11/00C09K5/14
CPCC09J11/00C09J11/04C09J11/06C09J11/08C09J183/04C09K5/14C08K2003/282C08K2003/2227C08K2201/011C08L2205/025C08L2205/035C08L2201/02C08L83/04C08L45/00C08K9/06C08K3/22C08K3/2279C08K5/06C08K3/28
Inventor 张雅倩金兆国党广洲张靖驰陈建纪旭阳刘斌张天翔
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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