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Fast absorption type water-absorbent resin and preparation method thereof

A water-absorbent resin, absorbent technology, applied in absorbent pads, medical science, etc., can solve the problems of slow absorption, non-absorptive fracture surface, reverse osmosis, etc., to increase specific surface area, control acrylic acid residue, and water absorption speed. boosted effect

Inactive Publication Date: 2018-03-23
广州得莱适商业咨询有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The wood pulp core (also known as fluff pulp, traditional core) is composed of fluff pulp and water-absorbing resin mixed in disorder, not layered, and the structure is relatively loose. The wood pulp core combs the fluff pulp to guide urine into the absorption Inside the core, the urine is absorbed by the water-absorbing capacity of the water-absorbent resin. Because the fluff pulp has good hydrophilicity and excellent drainage properties, the water absorption speed of the wood pulp core diaper is fast; but the fluff pulp will expand rapidly after absorbing water. , compared to composite core diapers, which are thicker, so wood pulp core diapers have the problem of easy fracture and upturning after absorbing water; resulting in poor air permeability of diapers, and the fault surface is not absorbent, resulting in uneven absorption of diapers
[0005] The composite core is a layered structure, mainly composed of water-absorbing resin and fluffy non-woven fabric. The water-absorbing resin is placed on the upper and lower sides of the fluffy non-woven fabric, and the urine is guided through the fluffy non-woven fabric layer to absorb the water-absorbing resin. The composite core The body uses a large amount of water-absorbing resin to ensure the water absorption of diapers, but because of the layered structure, the overall expansion after absorbing water has the advantages of continuous layers and no lumps; but the hydrophilicity of fluffy non-woven fabrics is not as good as that of fluffy pulp. , so the absorption rate of the composite core of diapers is much slower than that of the wood pulp core, that is, the composite core cannot diffuse quickly when it absorbs urine locally, and the urine capacity of this part will increase rapidly, which is prone to side leakage and reverse osmosis affect the dryness of the composite core after absorption
[0006] The semi-core is a new type of core that combines wood pulp core and composite core. It is still in the development stage, so it is not commonly used in the market.

Method used

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  • Fast absorption type water-absorbent resin and preparation method thereof
  • Fast absorption type water-absorbent resin and preparation method thereof
  • Fast absorption type water-absorbent resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A fast-absorbing water-absorbing resin, comprising the following components in parts by weight:

[0036] 30 parts of acrylic acid; 40 parts of deionized water; 35 parts of 32% sodium hydroxide aqueous solution; microsphere foaming agent refers to 0.5 part of macromolecular hollow microspheres coated with nano-calcium carbonate on the surface of acrylic resin; 1 part of a mixture of methylbisacrylamide and polyethylene glycol dimethacrylate with a mass ratio of 1:1; photoinitiator 1-hydroxycyclohexyl phenyl ketone and 2,4,6-trimethylbenzene 0.5 parts of acyl-diphenylphosphine oxide mass ratio of 2:1 mixture; 0.5 parts of cumene hydroperoxide as initiator; 6 parts of surface treatment solution.

[0037] (1) Mix 30 parts of acrylic acid and 40 parts of deionized water, then add 35 parts of 32% sodium hydroxide aqueous solution for neutralization reaction, control the reaction temperature <40 °C; then add 0.5 parts of microsphere foaming agent, 1 part of Cross-linking agen...

Embodiment 2

[0043] A fast-absorbing water-absorbing resin, comprising the following components in parts by weight:

[0044] 35 parts of acrylic acid; 45 parts of deionized water; 40 parts of 32% sodium hydroxide aqueous solution; microsphere foaming agent refers to 0.8 part of macromolecule hollow microspheres coated with nano-calcium carbonate on the surface of acrylic resin; 1.5 parts of a mixture of methylbisacrylamide and polyethylene glycol dimethacrylate with a mass ratio of 1:1; photoinitiators 1-hydroxycyclohexyl phenyl ketone and 2,4,6-trimethylbenzyl 0.8 parts of acyl-diphenylphosphine oxide mass ratio of 2:1 mixture; 0.8 parts of cumene hydroperoxide as initiator; 8 parts of surface treatment solution.

[0045] (1) Mix 35 parts of acrylic acid and 45 parts of deionized water, then add 40 parts of 32% sodium hydroxide aqueous solution for neutralization reaction, control the reaction temperature <40°C; then add 0.8 parts of microsphere foaming agent, 1.5 parts of Cross-linking ...

Embodiment 3

[0051] A fast-absorbing water-absorbing resin, comprising the following components in parts by weight:

[0052] 40 parts of acrylic acid; 50 parts of deionized water; 45 parts of 32% sodium hydroxide aqueous solution; microsphere foaming agent refers to 1 part of polymer hollow microspheres coated with nano-calcium carbonate on the surface of acrylic resin; 2 parts of a mixture of methylbisacrylamide and polyethylene glycol dimethacrylate with a mass ratio of 1:1; photoinitiators 1-hydroxycyclohexyl phenyl ketone and 2,4,6-trimethylbenzene 1 part of acyl-diphenylphosphine oxide mass ratio of 2:1 mixture; initiator refers to 1 part of cumene hydroperoxide; 10 parts of surface treatment solution.

[0053] (1) Mix 40 parts of acrylic acid and 50 parts of deionized water, then add 45 parts of 32% sodium hydroxide aqueous solution for neutralization reaction, control the reaction temperature <40°C; then add 1 part of microsphere foaming agent, 2 parts of Cross-linking agent, 1 par...

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PUM

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Abstract

The invention discloses fast absorption type water-absorbent resin and a preparation method thereof, and belongs to the technical field of water-absorbent resin. After a neutralization reaction is carried out, a microsphere foaming agent is added into a neutralization solution, the microsphere foaming agent releases heat and generates gas through a polymerization reaction, and a glue block swellsby several times under the action of the gas; then pelleting, drying and smashing are carried out, and the fast absorption type water-absorbent resin is obtained after surface crosslinking is carriedout. According to the fast absorption type water-absorbent resin and the preparation method thereof, operation is easy, the manufacturing process is easy to control, and the production period is short; the obtained water-absorbent resin is high in absorption speed and small in reverse osmosis, particles obtained after water absorption are high in strength and loose, and the fast absorption type water-absorbent resin is especially suitable for composite core paper diapers and sanitary towels.

Description

technical field [0001] The invention relates to the field of water-absorbing resins, in particular to a fast-absorbing water-absorbing resin and a preparation method thereof. Background technique [0002] Super Absorbent Polymer (SAP) is a new type of functional polymer material with a large number of hydrophilic groups. It has a high water absorption function of absorbing water hundreds to thousands of times heavier than itself, and has excellent water retention performance. Once it absorbs water and swells into a hydrogel, it is difficult to separate the water even if it is pressurized. Water-absorbing resins are widely used and have a very broad application prospect. The main purpose is mainly sanitary materials, accounting for about 70% of the total market. [0003] Water-absorbent resins are mainly used in sanitary products such as diapers, sanitary napkins, breast pads, mattresses, etc. The amount of water-absorbent resin in paper diapers accounts for more than 80% ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A61F13/53C08F283/06C08F220/06C08F222/38C08F2/48C08J9/32
CPCA61F13/53C08F2/48C08F283/065C08J9/32C08J2351/08A61F2013/530481C08F220/06C08F222/385
Inventor 周彧峰
Owner 广州得莱适商业咨询有限公司
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