Comprehensive utilization method of Cr(VI) (hexavalent chromium)-adsorbed magnetic macromolecular material

A polymer material and magnetic technology, which is applied in the field of comprehensive utilization of magnetic polymer materials after adsorption of Cr(VI), can solve the problems such as the comprehensive utilization has not been effectively carried out, the waste composition is unknown, the structure is unknown, etc., and the process and cost are saved. , good dispersion, high recovery efficiency

Inactive Publication Date: 2018-04-17
NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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Problems solved by technology

However, the composition of the waste after processing Cr(VI) is very complex, such as: different amino groups, different polymer ratios, different magnetic core contents, different Cr(VI) adsorption amounts, different adsorption conditions (such as temperature, pH Value, etc.) and other materials are mixed together to form waste; the composition and structure of the waste are unknown, so the comprehensive utilization of its system has not been effectively carried out

Method used

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  • Comprehensive utilization method of Cr(VI) (hexavalent chromium)-adsorbed magnetic macromolecular material
  • Comprehensive utilization method of Cr(VI) (hexavalent chromium)-adsorbed magnetic macromolecular material
  • Comprehensive utilization method of Cr(VI) (hexavalent chromium)-adsorbed magnetic macromolecular material

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Embodiment

[0029] Synthesis and characterization of amino-functionalized nano-Fe3O4 magnetic polymer composites (series 1-5, similar to series 6, change MMA to St) (Acta Chemical Sinica, 2009, 67(13), 1509-1514; J.Mater.Sci .2010,45,5291–5301; J.Hazard.Mater.2010,182,295–302; Ind.Eng.Chem.Res.2013, 52,12723-12732, etc.) There are records of the synthesis and characterization of some materials:

[0030] 1 nm Fe 3 o 4 Synthesis of particles

[0031] Synthesis of Nano Fe by Co-precipitation 3 o 4 Particles according to Fe 2+ :Fe 3+ = 1.5:2 (the ratio of the amount of substance) to prepare Fe 2+ and Fe 3+ After the solution of ions is fully dissolved, use ammonia water to provide alkalinity, adjust its pH value to 8-9, and stir at a speed of 500 r min- 1 , the reaction temperature is 353K, and the reaction time is 1h. The reaction principle is shown in reaction formula (1):

[0032] Fe2++2Fe3++8OH-→Fe3O4+4H2O (1)

[0033] After the reaction was completed, magnetically separated, w...

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Abstract

The invention discloses a comprehensive utilization method of a Cr(VI) (hexavalent chromium)-adsorbed magnetic macromolecular material. The comprehensive utilization method comprises the following steps of firstly, collecting the Cr(VI)-adsorbed magnetic macromolecular material, uniformly mixing, cleaning in an ultrasonic wave-assisted or microwave-assisted way, magnetically separating, and activating; then, sampling, and representing; finally, applying the Cr(VI)-adsorbed magnetic macromolecular material to absorb and degrade the heavy metal, methylene blue pigment and chlorophenol environment pollutants in wastewater. The comprehensive utilization method has the advantages that the Cr(VI)-adsorbed magnetic macromolecular material NMP-Cr is collected, activated and recycled by an ultrasonic wave-assisted, magnetic separating and vacuum drying cooperating method; the dispersivity is good, the technology is simple, the recycling efficiency is high, and the like; the defects of easinessin agglomeration, poor dispersivity and the like of the magnetic composite material in the recycling process can be overcome; the morphology of the magnetic composite material is favorably stored, theprocedure and cost are reduced, and the pollution to environment due to chromium-containing waste material flowing into the environment system can be avoided.

Description

technical field [0001] The invention relates to a method for comprehensive utilization of magnetic polymer materials after adsorbing Cr(VI), in particular to a method for comprehensive utilization of magnetic polymer materials after adsorbing Cr(VI) as new adsorbents and catalysts. The invention collects, characterizes and activates the magnetic polymer material after adsorbing Cr(VI), and can efficiently and selectively adsorb and degrade heavy metals such as copper, nickel and cadmium, environmental pollutants such as methylene blue pigment and chlorophenol in waste water. Background technique [0002] With the further acceleration of the global industrialization process, industries such as iron and steel, electroplating, tanning and pigment chemistry have achieved considerable development. In the development of these industries, the role of heavy metals cannot be ignored, but at the same time, the environmental pollution caused by heavy metals has also aroused widespread ...

Claims

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Application Information

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IPC IPC(8): C02F1/28C02F1/72B01J20/34B01J20/28B01J20/26B01J31/28C02F101/20C02F101/30C02F101/36C02F101/34
CPCB01J20/26B01J20/28009B01J20/3441B01J20/3483B01J31/28C02F1/28C02F1/725C02F2101/20C02F2101/308C02F2101/345C02F2101/36
Inventor 沈昊宇
Owner NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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