Water soluble binary anionic polymeric molecular brush dye capturing settling agent and preparation method and application thereof
An anionic polymer technology, applied in water pollutants, chemical instruments and methods, textile industry wastewater treatment, etc., can solve the problems of single chemical structure of polyacrylamide, inability to deal with heavy metal ions, and poor capture ability of dye molecules. To achieve efficient capture and solve the problem of heavy metal ions, the effect of good electrostatic adsorption capacity
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Embodiment 1
[0018] It is a water-soluble dibasic anionic polymer molecular brush dye capturing and settling agent, prepared by the following steps:
[0019] Step 1: Synthesize PHEMAA polymer backbone
[0020] Take 5 parts of azobisisobutyronitrile initiator, 100 parts of hydroxyethyl acrylamide (HEMAA), 100 parts of methanol, and carry out the polymerization reaction at 60°C for 2 hours under the protection of nitrogen to obtain a degree of polymerization (DP) of 25 Polyhydroxyethyl acrylamide (PHEMAA);
[0021] Step 2 Anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0022] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: Take 4 parts of azodicyanovaleric acid initiator, 100 parts of tert-butyl methacrylate (tBMA), 200 parts of toluene, in nitrogen Free radical polymerization was carried out at 80°C under protection for 1 hour to obtain PtBMA-COOH with a degree of polymerization (DP) of 40;
[0023] The sy...
Embodiment 2
[0030] A water-soluble binary anionic polymer molecular brush dye capturing settling agent is prepared by the following steps:
[0031] Step 1: Synthesize PHEMAA polymer backbone
[0032] Take 2 parts of ethyl 2-bromoisobutyrate initiator, 2 parts of CuBr and 2 parts of 4,4-bipyridine (BPy), 100 parts of hydroxyethyl acrylamide (HEMAA), 40 parts of methanol, in nitrogen Perform polymerization at 65°C under protection for 12 hours to obtain polyhydroxyethyl acrylamide (PHEMAA) with a degree of polymerization (DP) of 110;
[0033] Step 2: Anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0034] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: Take 2 parts of azodicyanovaleric acid initiator, 100 parts of tert-butyl methacrylate (tBMA), 20 parts of toluene, in nitrogen Carry out free radical polymerization at 75°C for 12 hours under protection to obtain PtBMA-COOH with a degree of polymerization (...
Embodiment 3
[0042] It is a water-soluble dibasic anionic polymer molecular brush dye capturing and settling agent, which is prepared by the following steps:
[0043] Step 1: Synthesize PHEMAA polymer backbone
[0044] Take 1 part of ethyl 2-bromoisobutyrate initiator, 1 part of CuBr, 1 part of 4,4-bipyridine (BPy), 400 parts of hydroxyethyl acrylamide (HEMAA), 20 parts of methanol, Perform polymerization at 70°C for 15 hours under the protection of nitrogen to obtain polyhydroxyethyl acrylamide (PHEMAA) with a degree of polymerization (DP) of 450;
[0045] Step 2: Anionic polymer side chain precursor polymer PtBMA-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0046] Synthesis of anionic polymer side chain precursor polymer PtBMA-COOH: Take 1 part of azodicyanovaleric acid initiator, 400 parts of tert-butyl methacrylate (tBMA), 100 parts of toluene, in nitrogen Carry out radical polymerization at 79°C under protection for 13 hours to obtain PtBMA-COOH with a degree of polym...
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