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Composite raw material for preparing polyamide film and preparation method of composite raw material

A polyamide film and polyamide technology, which is applied in the field of polyamide film preparation, can solve the problems of insignificant improvement of finished film properties, defects in film products, easy agglomeration of inorganic powders, etc., achieving good opening and preventing agglomeration or precipitation. , the effect of improving compatibility

Active Publication Date: 2018-04-17
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of the existing polyamide film processing masterbatch mainly relying on the addition of inorganic powder to improve the processing performance and the performance of the finished film, there are defects such as inorganic powder is easy to agglomerate, resulting in defects in the film product, and the performance of the finished film is not significantly improved. The object of the present invention is to provide a polyamide film combination raw material with excellent processing performance, and the prepared polyamide film has excellent mechanical properties, transparency, stretchability, anti-blocking properties, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 2.5 parts of silicon dioxide with an average particle size of 0.5 microns and 3 microns each, surface-treated with a silane coupling agent, and 100 parts of molten caprolactam monomer under the action of a high-shear disperser to prepare an additive mother liquor.

[0033] 100 parts of caprolactam monomer, 2 parts of desalted water, and 3 parts of additive mother liquor are mixed by a static mixer, and then continuously enter into a two-stage polymerization reactor. The pressure of the front polymerization tube is 0.15MPa, and the reaction temperature is 260-270°C; the pressure of the rear polymerization tube is -0.03MPa, and the reaction temperature is 250-260°C. Polyamide 6 obtained through polymerization was granulated, extracted and dried, and mixed with 0.05% ethylene bisstearamide in a conical double-helix mixer for 20 minutes to obtain polyamide product A for membranes.

Embodiment 2

[0035] The polymerization process was the same as in Example 1, except that the inorganic additives were changed to talcum powder with an average particle size of 0.8 microns and calcium carbonate with an average particle size of 2 microns to obtain polyamide product B for membranes.

Embodiment 3

[0037] The polymerization process was the same as in Example 1, changing 100 parts of caprolactam monomers to 80 parts of caprolactam monomers, and 40 parts of 50% nylon 66 saline solution. Obtain polyamide product C for film

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PUM

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Abstract

The invention discloses a composite raw material for preparing a polyamide film and a preparation method of the composite raw material. The composite raw material is prepared in steps as follows: a composite particle additive consisting of two inorganic articles with different particle sizes is added in a polyamide polymerization process, after polymerization, obtained polyamide is subjected to granulation, extraction and drying, the obtained material is mixed with bisamide compounds, and the composite raw material for the polyamide film is obtained. Processing master batch is not required tobe used additionally when the composite raw material is used for preparing the film, and the prepared polyamide film has ideal mechanical performance, transparency, stretchability, blocking resistanceand the like.

Description

technical field [0001] The invention relates to a raw material for producing polyamide film, in particular to a polyamide film raw material modified by inorganic particles and a preparation method thereof, belonging to the technical field of polyamide film preparation. Background technique [0002] Polyamide film has excellent strength and toughness, resistance to freezing and high temperature, good oxygen barrier properties, puncture and tear resistance, good transparency and gloss, and low haze. It is especially suitable for cooking, freezing, and vacuum packaging, and is widely used in food, chemical products, and electronic product packaging. [0003] The polyamide used in the production of film needs to be able to form a fine and uniform crystal structure during processing and molding, so as to ensure that the film is not easy to break during the forming and stretching process, and the finished film has ideal transparency. At the same time, the prepared film is require...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08K9/06C08K3/36C08K3/34C08K3/26C08J5/18
CPCC08J5/18C08J2377/02C08J2477/06C08K3/26C08K3/34C08K3/36C08K9/06C08K2201/003C08L77/02C08L2201/10C08L2203/16C08L77/06
Inventor 唐成华张利建李楚新何宁艳狄金凤
Owner CHINA PETROLEUM & CHEM CORP
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