A catalytic cracking method for producing light olefins and light aromatics

A technology for catalytic cracking and low-carbon olefins, applied in the treatment of hydrocarbon oil, hydrocarbon oil treatment products, petroleum industry, etc., can solve the problems of increased and limited yield of light aromatics, and achieve reduced selectivity, high BTX yield, improved The effect of stability

Active Publication Date: 2020-11-13
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0006] In summary, the existing technologies all take low-carbon olefins as the main target yield and co-produce light aromatics, so the increase in the yield of light aromatics is limited. It is necessary to develop a catalytic cracking method with higher yields of low-carbon olefins and light aromatics on the basis of current technology and catalytic materials

Method used

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  • A catalytic cracking method for producing light olefins and light aromatics

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preparation example Construction

[0072] The present invention also provides a method of preparing the catalytic cleavage catalyst, comprising preparing the phosphorus-containing and negative metal IMF structural molecular sieve, which will be sieved and a molecular sieve, natural mineral, natural mineral, natural mineral , The oxide pre-body sol is mixed, spray drying; wherein the preparation method of the phosphorus-containing and load metal IMF structural molecular sieve includes:

[0073] A. The sodium IMF structure molecular sieve is subjected to a silicon sketch; B is obtained, and the dexuxiliary molecular sieve obtained in step A is used to obtain a ammonium exchange molecular sieve; wherein the sodium oxide is measured. The total dry base weight of the ammonium exchange molecular sieve is based. The sodium content of the ammonium exchange molecular sieve is less than 0.2% by weight; C, the ammonium exchange molecular sieve obtained in step B is subjected to complexate composed of fluorosilic acid, organic...

Embodiment

[0122] according to figure 1 The test process, the feedstock is a vacuum gas oil, catalytic cracking catalyst prepared in the preceding, on a pilot plant test, three reactors are operating pressure hydrocracking tail oil into the riser 1, in a reaction temperature 580 ℃, the reaction time of 2.0 seconds, a mixture of regenerated catalyst and spent catalyst (spent catalyst wherein the catalyst mixture accounted for 20 wt%) by weight of the feedstock oil ratio 10, the weight ratio of steam to oil feed is carried out under conditions of 0.25 cleavage reaction, the reaction of oil and gas and water vapor into the cyclone and the spent catalyst from the reactor outlet.

[0123] Aromatic raffinate oil (saturated hydrocarbon content of 87 wt%) into the riser bottom 2, at a reaction temperature of 625 deg.] C, the reaction time is 1.8 seconds, regenerated catalyst to feed oil weight ratio of 15, the weight ratio of steam to oil feed is 0.25 carried out under the conditions of the cleavage...

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Abstract

The invention relates to a catalytic cracking method for producing low-carbon olefins and light aromatic hydrocarbons. According to the catalytic cracking method, a heavy raw material and a first catalytic cracking catalyst are subjected to a contact reaction in a first reactor; a lightweight raw material rich in saturated hydrocarbons, a lightweight raw material rich in olefins and a second catalytic cracking catalyst are subjected to a contact reaction in a second reactor and a third reactor; all the reaction oil-gas and the spent catalysts are subjected to gas-solid separation; the reactionoil-gas is further separated to obtain a product containing light-carbon olefins and light aromatic hydrocarbons; and the spent catalysts are subjected to steam stripping, the steam stripped catalysts enter a catalyst regenerator, charring regeneration is performed, and the regenerated catalyst returns to the reactor so as to be recycled, wherein the catalytic cracking catalyst comprises, by weight, 15-65% of natural minerals, 10-60% of an oxide, and 25-75% of a Y-type molecular sieve and a loaded metal-containing IMF structure molecular sieve. With the method of the present invention, the yield of low-carbon olefins is high, and the yield of light aromatic hydrocarbons is high.

Description

Technical field [0001] The present invention relates to a method of catalytic conversion of hydrocarbon oil in the event that there is no hydrogen, and more particularly to a catalytic cracking method for producing low carbon olefins and light aromatics. Background technique [0002] Low carbon olefins represented by ethylene, propylene are the most basic raw materials of the chemical industry, and more natural gas or light petroleum fractions are raw materials at home and abroad, and the vapor cracking process is produced using a vapor hydrocarbon in the vinyl hydrocarbon. In addition to producing ethylene, about 70% propylene, 90% butadiene, 30% of the aromatic hydrocarbons are from steam cracking byproducts. Although the steam cracking technology has been continuously improved by decades, there is still high energy consumption, high production cost, CO 2 Large emissions and product structures are not easy to adjust and other technologies, traditional steam cleavage production ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G65/02
CPCC10G65/02C10G2300/70C10G2300/703C10G2400/20C10G2400/24
Inventor 谢朝钢魏晓丽陈学峰张久顺罗一斌田辉平张执刚刘银亮李福超
Owner CHINA PETROLEUM & CHEM CORP
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