Method for one-step synthesis of ethyl methyl carbonate from propylene oxide and co-production of 1,2-propanediol
A technology for methyl ethyl carbonate and propylene oxide, applied in the field of synthesizing methyl ethyl carbonate, can solve the problems of high energy consumption, increased operating cost, low reactant conversion rate and product selectivity, etc.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0062] 1. Preparation method of mesoporous molecular sieve carrier:
[0063] In the present invention, orderly acid-base treatment is carried out on different carriers, and finally the molecular sieve carrier with the compound pore structure of mesoporous and micropores is prepared by high-temperature roasting. The purpose of the acid treatment is to remove the Al in the molecular sieve framework, so as to realize pore formation. The main function of the alkali treatment is to remove the Si in the molecular sieve framework to make the molecular sieve form a mesoporous structure. The preparation process includes the following steps:
[0064] 1) Dealumination: Add a certain mass of M-S carrier to a certain volume of acidic solution with a concentration of 0.11 mol / L, then stir and reflux in an oil bath at 100°C for 6 h, then filter, wash, and dry at 120°C for 8 h. The dealuminated M-S-DAl carrier is obtained.
[0065] 2) Desiliconization: Add the M-S-DAl carrier prepared in pro...
Embodiment 1
[0099] In the still of 50L slurry bed reactor, reaction pressure 10MPa, reaction raw material propylene oxide: carbon dioxide: methyl alcohol: ethanol=1:1:3:2, drop into each 1.2kg of basic catalyst that above-mentioned preparation method obtains respectively, reaction solution The total volume is 40 L. The reaction was mechanically stirred at a reaction temperature of 100°C. After 10 hours of reaction, samples were taken for chromatographic analysis and calculation. The conversion rate of raw materials and product selectivity are shown in Table 1.
[0100]
[0101] The propylene oxide and carbon dioxide conversions were essentially the same under all reaction conditions, therefore, the propylene oxide conversion, CO 2 The conversion rate also represents the CO 2 and propylene oxide conversion, product selectivity in terms of CO 2 base calculation. In addition to the generation of propylene carbonate (PC), dimethyl carbonate (DMC), ethyl methyl carbonate (EMC) and diethy...
Embodiment 2
[0103] In a fixed-bed reactor, the effects of different reaction pressures on the conversion of raw materials and product selectivity were explored. 50 g of 15%BaO-5%Al2O3-3%La2O3 / Cs-meso-EMT catalyst was loaded into the fixed bed, the molar ratio of propylene oxide to carbon dioxide was 1:1, and the methanol and ethanol were mixed according to the molar ratio of 3 :2 ratio pumped into the reactor with a space velocity of 5 h -1 , the reaction pressure is shown in the table, the reaction temperature is 100°C, and it is stabilized for 500 h. After stabilization, samples are taken for chromatographic analysis and calculation. The conversion rate of raw materials and product selectivity are shown in Table 2.
[0104]
[0105] As can be seen from Table 2, with 15%BaO-5%Al 2 o 3 -3%La 2 o 3 When / Cs-meso-EMT was used as the catalyst, the conversion of reactants and product selectivity increased with the increase of reaction pressure. When the reaction pressure reaches 5MPa ...
PUM
Property | Measurement | Unit |
---|---|---|
pore size | aaaaa | aaaaa |
melting point | aaaaa | aaaaa |
boiling point | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com