Environmentally friendly cable material and preparation method thereof
A cable material and environmental protection technology, applied in the field of environmental protection cable material and its preparation, can solve the problems of poor weather resistance and physical and mechanical properties, weak anti-electromagnetic interference ability, frost spray and extravasation, etc. Low cost and the effect of improving fire retardant performance
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Embodiment 1
[0030] An environment-friendly cable material is prepared from the following components in parts by weight: 100 parts of polyacrylic acid copolymer modified silicone rubber, 1 part of sulfur, 1 part of maleic anhydride grafted polyethylene, and 10 parts of waste tire rubber powder.
[0031] The preparation method of described polyacrylic acid copolymer modified silicone rubber, comprises the steps:
[0032] 1) After adding 20g of 3-(3-phenylaminosulfonylphenyl)acrylic acid and 10g of amino-modified 107 silicone rubber into 50g of organic solvent, add 2-ethoxy-1-ethoxycarbonyl-1 to it, 50 g of 2-dihydroquinoline was stirred and reacted at room temperature under a nitrogen atmosphere for 18 hours. After the reaction was completed, it was precipitated in ether, filtered, and the product was washed 5 times with ether, and the solvent was removed by rotary evaporation to obtain a modified silicone rubber; Said organic solvent is the mixture that dichloromethane and methanol solvent...
Embodiment 2
[0036] An environment-friendly cable material is prepared from the following components in parts by weight: 100 parts of polyacrylic acid copolymer modified silicone rubber, 2 parts of vulcanizing agent DTDM, 2 parts of maleic anhydride grafted polypropylene, and 12 parts of waste tire rubber powder.
[0037] The preparation method of described polyacrylic acid copolymer modified silicone rubber, comprises the steps:
[0038] 1) After adding 23g of 3-(3-phenylaminosulfonylphenyl)acrylic acid and 10g of amino-modified 107 silicone rubber into 65g of organic solvent, add 2-ethoxy-1-ethoxycarbonyl-1 to it, 3.5 g of 2-dihydroquinoline was stirred and reacted at room temperature under a helium atmosphere for 20 hours. After the reaction, it was precipitated in ether, filtered, and the product was washed with ether for 6 times, and the solvent was removed by rotary evaporation to obtain a modified silicone rubber ; The organic solvent is a mixture of dichloromethane and Virahol solv...
Embodiment 3
[0042] An environment-friendly cable material is prepared from the following components in parts by weight: 100 parts of polyacrylic acid copolymer modified silicone rubber, 2 parts of vulcanizing agent DCP, 3 parts of maleic anhydride grafted polyethylene, and 13 parts of waste tire rubber powder.
[0043] The preparation method of described polyacrylic acid copolymer modified silicone rubber, comprises the steps:
[0044] 1) After adding 25g of 3-(3-phenylaminosulfonylphenyl)acrylic acid and 10g of amino-modified 107 silicone rubber into 80g of organic solvent, add 2-ethoxy-1-ethoxycarbonyl-1 to it, 4g of 2-dihydroquinoline was stirred and reacted at room temperature for 21 hours under a neon gas atmosphere. After the reaction, it was precipitated in ether, filtered, and the product was washed with ether for 7 times, and then the solvent was removed by rotary evaporation to obtain a modified silicone rubber; Described organic solvent is the mixture that dichloromethane and e...
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