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Cationic self-extinction resin and its preparation method and application

A cationic, self-extinguishing technology, applied in coatings, polyurea/polyurethane coatings, etc., to achieve the effect of improving poor film formation, increasing mobility and good resistance

Active Publication Date: 2020-08-28
WANHUA CHEM GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In view of the fact that there is no research report on cationic self-extinction resin, it is necessary to develop and prepare a cationic self-extinction resin, which can overcome the defects in the prior art and has excellent self-extinction effect. of

Method used

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  • Cationic self-extinction resin and its preparation method and application
  • Cationic self-extinction resin and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0087] A kind of cationic self-dulling resin, the weight parts of raw materials are composed of:

[0088] 7.8 parts of isocyanate (the molar ratio of IPDI to HDI is 2:1),

[0089] Macromolecule polyol (PTMG1000) 14.0 parts,

[0090] 0.11 parts of monohydric alcohol and / or dihydric alcohol (MPEG1200) containing polyoxyethylene segment in main chain and / or side chain,

[0091] 0.37 parts of diamine cationic hydrophilic chain extender (HBAAP),

[0092] Small molecule diamine chain extender (EDA and EDA-OH) 1.73 parts,

[0093] Catalyst (organic bismuth 8108) 0.0022 parts,

[0094] 32.9 parts of solvent (acetone),

[0095] 56.0 parts of deionized water,

[0096] Neutralizing agent (acetic acid) 0.1 part.

[0097] Above-mentioned cationic self-extinction resin, the preparation method is:

[0098] (1) Add 140 grams of PTMG1000 into a four-necked flask with a condenser and a stirrer, then add 31 grams of IPDI and 47 grams of HDI, 0.022g of organic bismuth 8108, 22 grams of ace...

Embodiment 2

[0104] 5.3 parts of isocyanate (IPDI, TDI, HDI),

[0105]Macromolecule polyol (PTMG1000) 11.7 parts,

[0106] 0.11 parts of monohydric alcohol and / or dihydric alcohol (MPEG1200) containing polyoxyethylene segment in main chain and / or side chain,

[0107] 0.37 parts of diamine cationic hydrophilic chain extender (HBAAP),

[0108] Small molecule diamine chain extender (EDA) 0.98 parts,

[0109] Catalyst (organic bismuth 8108) 0.00164 parts,

[0110] Solvent (acetone) 29.1 parts,

[0111] 43.1 parts of deionized water,

[0112] Neutralizing agent (acetic acid) 0.1 part.

[0113] Above-mentioned cationic self-extinction resin, the preparation method is:

[0114] (1) Add 117 grams of PTMG1000 to a four-necked flask with a condenser and a stirrer, then add 23 grams of IPDI, 6 grams of TDI and 24 grams of HDI, 0.0164 grams of organic bismuth 8108, 17 grams of acetone, and heat at 85 ° C After reacting for 1.5 hours, the NCO value was 7.3% (theoretical value was 7.36%), and a d...

Embodiment 3

[0120] 10.2 parts of isocyanate (HMDI and HDI),

[0121] Macromolecule polyol (PTMG1000) 20.0 parts,

[0122] 0.33 parts of monohydric alcohols and / or dihydric alcohols (MPEG1200) containing polyoxyethylene segments in the main chain and / or side chains,

[0123] 0.93 part of dibasic amine cationic hydrophilic chain extender (HBAAP),

[0124] Small molecule diamine chain extender (IPDA and EDA-OH) 3.2 parts,

[0125] Catalyst (organic bismuth 8108) 0.003 part,

[0126] Solvent (acetone) 51.9 parts,

[0127] 80.9 parts of deionized water,

[0128] Neutralizing agent (acetic acid) 0.254 parts.

[0129] Above-mentioned cationic self-extinction resin, the preparation method is:

[0130] (1) Add 200 grams of PTMG1000 into a four-necked flask with a condenser and a stirrer, then add 31 grams of HMDI and 71 grams of HDI, 0.03 grams of organic bismuth 8108, 31 grams of acetone, and react at 85 ° C for 1.5 hours, The NCO value is 8.7% (theoretical value is 8.61%), resulting in di...

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Abstract

The invention discloses a cationic self-dulling resin and its preparation method and application. The raw material components include isocyanate, diamine cationic hydrophilic chain extender, macromolecular polyol, and the main chain and / or side chains contain polyethylene oxide chains. Monohydric alcohol and / or dihydric alcohol, small molecule diamine chain extender, catalyst, solvent and neutralizing agent, and the preparation method of the present invention is simple in process, easy to operate, safe and non-toxic, and the prepared cationic self-extinction resin, Small fluctuations in particle size, good emulsion stability and tolerance, good adhesion to anionic leather and glass substrates, giving leather a soft and smooth feel and a natural and plump appearance, and can be widely used in leather Finishing, wood plastics, paper printing, printing and dyeing inks, printing coatings, packaging coatings, matting nail polish and other fields.

Description

technical field [0001] The invention belongs to the technical field of cationic self-extinction resin preparation, and relates to a cationic self-extinction resin and its preparation method and application. Background technique [0002] Water-based polyurethane has the characteristics of non-toxicity, flexibility, environmental protection, and easy modification due to its use of water as the medium. Under the premise of today's increasingly high environmental protection requirements, water-based polyurethane is widely used in textile coatings, wood, architectural coatings, metals, adhesives and leather. With the development of society and the continuous improvement of aesthetics, the pursuit of self-extinction or matte is becoming more and more vigorous. At present, there are mainly two methods to achieve the effect of extinction: external addition method and self-extinction. Among them, the external addition method mainly achieves the matting effect by adding matting powd...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/66C08G18/32C08G18/48C09D175/08
CPCC08G18/3228C08G18/3271C08G18/3275C08G18/4833C08G18/4854C08G18/6674C08G18/6685C08G18/6688C09D175/08
Inventor 周操赵炳炎张洁韩克
Owner WANHUA CHEM GRP CO LTD
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