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Shell waste based soil improvement agent as well as preparation method and application thereof

A soil conditioner and waste technology, applied in the field of shell waste soil conditioner and its preparation, can solve the problems of pollution, increase of soil calcium content and high calcium carbonate content

Inactive Publication Date: 2018-09-28
GUANGZHOU XINNONGKE FERTILIZER SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The soil conditioner makes full use of shell waste, waste residue from corncob hydrolysis, phosphogypsum by-product in phosphoric acid production process, and desulfurization waste in flue gas desulfurization process; the porous structure of shell powder makes it have a high The specific surface area and porosity of the shell make the mixing and dispersion of the raw materials more uniform. The calcium carbonate content of the shell powder is high, which can increase the calcium content of the soil. At the same time, the amino acids and polysaccharides contained in the shell powder can enrich the soil nutrients. In addition, the shell powder The addition of powder solves the problem of soil pollution caused by aluminum, heavy metal elements and radioactive elements in fly ash, and the specific surface area of ​​activated carbon prepared from corncob hydrolysis residue is as high as 2000m 2 / g, with strong adsorption performance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A preparation method of shell waste soil conditioner, comprising the following steps:

[0029] (1) Wash the shell waste to remove impurities, then dry at 80°C for 1 hour, grind and pass through a 200-mesh sieve to obtain shell powder;

[0030] (2) Add the hydrolysis residue of corn cob into deionized water, keep it warm at 220°C for 1.5h, wash the residue after reaction with deionized water, and dry at 100°C for 1h to obtain hydrothermal coke, and then raise the temperature to 400°C under nitrogencarbonization for 1 hour to obtain activated carbon, which was ground and passed through a 200-mesh sieve to prepare activated carbon powder;

[0031] (3) Grinding the phosphogypsum and flue gas desulfurization waste respectively and passing through a 200-mesh sieve to obtain phosphogypsum powder and flue gas desulfurization waste powder;

[0032](4) Mix 65 parts by weight of shell powder, 12 parts by weight of activated carbon powder, 6 parts by weight of phosphogypsum pow...

Embodiment 2

[0035] A preparation method of shell waste soil conditioner, comprising the following steps:

[0036] (1) Wash the shell waste to remove impurities, then dry at 95°C for 1 hour, grind and pass through a 200-mesh sieve to obtain shell powder;

[0037] (2) Add the hydrolyzed residue of corn cob into deionized water, keep it warm at 200°C for 2h, wash the residue after reaction with deionized water, and dry at 100°C for 1.5h to obtain hydrothermal coke, then raise the temperature to 410°C under nitrogen Carbonize at ℃ for 65min to obtain activated carbon, pass through a 200-mesh sieve after grinding, and prepare activated carbon powder;

[0038] (3) Grinding the phosphogypsum and flue gas desulfurization waste respectively and passing through a 200-mesh sieve to obtain phosphogypsum powder and flue gas desulfurization waste powder;

[0039] (4) Mix 63 parts by weight of shell powder, 14 parts by weight of activated carbon powder, 7 parts by weight of phosphogypsum powder, 11 par...

Embodiment 3

[0042] A preparation method of shell waste soil conditioner, comprising the following steps:

[0043] (1) Wash the shell waste to remove impurities, then dry at 95°C for 2 hours, grind and pass through a 200-mesh sieve to obtain shell powder;

[0044] (2) Add the hydrolysis residue of corn cob into deionized water, keep it warm at 250°C for 1h, wash the residue after reaction with deionized water, and dry at 100°C for 1h to obtain hydrothermal coke, then raise the temperature to 390°C under nitrogen Carbonize for 80 minutes to obtain activated carbon, pass through a 200-mesh sieve after grinding, and prepare activated carbon powder;

[0045] (3) Grinding the phosphogypsum and flue gas desulfurization waste respectively and passing through a 200-mesh sieve to obtain phosphogypsum powder and flue gas desulfurization waste powder;

[0046] (4) Mix 76 parts by weight of shell powder, 10 parts by weight of activated carbon powder, 7 parts by weight of phosphogypsum powder, 9 parts...

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Abstract

The invention belongs to the technical field of soil improvement and particularly relates to a shell waste based soil improvement agent and a preparation method thereof. The preparation method disclosed by the invention comprises the following steps: washing and drying shell wastes, and grinding to obtain a shell powder, carrying out a low-temperature hydrothermal reaction on corncob hydrolysis residues to prepare hydrothermal coke; performing high temperature carbonization in a nitrogen environment to obtain activated carbon, grinding to obtain an activated carbon powder, and respectively grinding phosphogypsum and flue gas desulfurization wastes to obtain a phosphogypsum powder and a flue gas desulfurization waste powder; finally, performing mixing granulation on the shell powder, the activated carbon powder, the phosphogypsum powder and the flue gas desulfurization waste powder, so as to obtain the shell waste based soil improvement agent. According to the preparation method disclosed by the invention, industrial and agricultural wastes are fully utilized as raw materials of the soil improvement agent, and the soil improvement agent is low in cost and environmental-friendly; theprepared soil improvement agent is capable of obviously improving the pH value of soil, improving soil hardening and increasing calcium-magnesium content in the soil.

Description

technical field [0001] The invention belongs to the technical field of soil improvement, and in particular relates to a soil conditioner for shell waste and its preparation method and application. Background technique [0002] At present, the area of ​​soil pollution in my country is increasing. The main reasons for its formation are: soil pollution from sewage irrigation; soil pollution from air pollution; soil pollution from unreasonable use of chemical fertilizers; impact of pesticides on soil and solid Waste pollution of the soil. In particular, the degree of soil acidification in the south is serious, which affects the normal growth of crops. The main reasons for soil acidification are as follows: 1. Large and concentrated precipitation, strong leaching effect, and a large amount of alkaline bases such as calcium, magnesium, and potassium are lost, which is the root cause of soil acidification. For example, acid rain etc. 2. The lack of traditional agricultural measur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/06B09C1/08C09K101/00C09K109/00
CPCB09C1/08C09K17/06C09K2101/00C09K2109/00
Inventor 徐培智国彬陈鸿哲张政勤罗文贱李国富
Owner GUANGZHOU XINNONGKE FERTILIZER SCI & TECH
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