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A kind of nanocapsule phase change material and preparation method thereof

A technology of phase change materials and nanocapsules, applied in heat exchange materials, chemical instruments and methods, etc., can solve the problems of poor cysticity and low loading capacity, and achieve good cysticity, high loading capacity, and coating rate high effect

Active Publication Date: 2020-06-30
ZHEJIANG OCEAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at the disadvantages of poor encapsulation and low loading capacity in preparing nanocapsule phase change materials in the prior art using silicon dioxide as a wall material, the present invention provides a nanocapsule phase change material and a preparation method thereof. The preparation process of the method is Simple, mild conditions, non-toxic, the prepared nanocapsule phase change material has excellent encapsulation performance and high loading capacity

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  • A kind of nanocapsule phase change material and preparation method thereof
  • A kind of nanocapsule phase change material and preparation method thereof

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preparation example Construction

[0025] The preparation method of the nanocapsule phase-change material provided by the invention comprises the following steps:

[0026] S1, mixing phospholipids and organic phase change materials in a solvent, making the phospholipids coat the organic phase change materials to form liposome nanocapsules, and obtaining a suspension of liposome nanocapsules;

[0027] S2, adding a solution of a biomimetic silicification inducer to the suspension of the liposome nanocapsule, so that the biomimetic silicification inducer is attached to the liposome nanocapsule to form a suspension of a preform;

[0028] S3, adding a silicon source to the suspension of the preform to form silicon oxide on the surface of the preform to obtain a nanocapsule phase change material.

[0029] In step S1, the phospholipid is preferably soybean lecithin and lecithin, and the solvent is preferably distilled water. After the phospholipid is dispersed in distilled water, a coating layer is formed to cover th...

Embodiment 1

[0049] Place 0.1 g of lecithin in 5 mL of distilled water and stir for 20 min at 26.4°C to obtain a mixture of lecithin and distilled water.

[0050] Add 7mL of 40mg / mL polyethylene glycol 4000 ethanol solution dropwise to the mixture of lecithin and distilled water while stirring, and continue stirring for 7min to make lecithin coat polyethylene glycol 4000 to form liposome nanocapsules. A suspension of liposomal nanocapsules was obtained.

[0051] Add 25mL of 2mg / mL polydiene dimethyl ammonium chloride aqueous solution dropwise into the suspension of liposome nanocapsules while stirring. The addition time is 20min. The polydiene dimethyl ammonium chloride is attached to the liposome nanocapsule to form a suspension of the pre-product, and the suspension is a yellow flocculent mixed liquid.

[0052] Add 7mL of 8mg / mL methyl orthosilicate aqueous solution dropwise to the pre-product suspension while stirring to form an emulsion, and continue stirring for 10min.

[0053] Afte...

Embodiment 2

[0057] Place 0.2 g of soybean lecithin in 5 mL of distilled water and stir for 40 min at room temperature to obtain a mixture of soybean lecithin and distilled water.

[0058] Add 10mL of 100mg / mL n-stearyl alcohol ethanol solution dropwise to the mixture of soybean lecithin and distilled water while stirring, and continue to stir for 5min, so that soybean lecithin is coated with n-stearyl alcohol to form liposome nanocapsules to obtain liposomes. Suspensions of plastid nanocapsules.

[0059] Add 30mL of 4mg / mL polylysine aqueous solution drop by drop into the suspension of liposome nanocapsules with soybean lecithin as the capsule wall and n-stearyl alcohol as the capsule core, and seal with plastic wrap after adding , after continuing to stir for 20 minutes, the polylysine is attached to the liposome nanocapsule to form a suspension of the pre-product, and the suspension is a yellow flocculent mixed liquid.

[0060] Add 20mL of 8mg / mL tetraethyl orthosilicate aqueous soluti...

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Abstract

The invention relates to a nanocapsule phase-change material and a preparation method thereof. The preparation method comprises the following steps of: mixing phospholipid and an organic phase-changematerial in a solvent to coat the organic phase-change material with the phospholipid to form liposome nanocapsules, so as to obtain a suspension of the liposome nanocapsules; adding a biomimetic silication inducer solution to the suspension of the liposome nanocapsules to attach a biomimetic silication inducer to the liposome nanocapsules, so as to form a suspension of a preform; and adding a silicon source to the suspension of the preform to form silicon oxide on the surface of the perform, so as to obtain a nanocapsule phase-change material. The nanocapsule phase-change material is a spherical particle comprising a capsule wall, a coating layer and a capsule core, wherein the coating layer is disposed between the capsule wall and the capsule core, the material of the capsule wall is silicon oxide, the material of the capsule core is an organic phase-change material, the coating layer is made from phospholipid, and a biomimetic silication inducer is attached to the surface, facing the capsule wall, of the coating layer. The nanocapsule phase-change material obtained by the method of the invention has excellent capsule formation performance and high loading capacity.

Description

technical field [0001] The invention relates to the technical field of phase change energy storage materials, in particular to a nanocapsule phase change material and a preparation method thereof. Background technique [0002] At present, physical adsorption, vacuum infiltration, melt blending and other methods are usually used for the preparation of shaped phase change materials. However, the shape-fixed phase change materials prepared by the above traditional methods still have defects such as low phase change enthalpy, poor thermal conductivity and thermal stability, which cannot meet the needs of actual production. Using nanocapsule technology to encapsulate phase change materials, preparing stable nanocapsulated heat storage particles, and developing novel and efficient shape-fixed phase change materials are one of the important ways to solve the above problems. [0003] Among them, silicon oxide has the advantages of good thermal conductivity, low density, excellent f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/06
CPCC09K5/063
Inventor 陈妍高军凯
Owner ZHEJIANG OCEAN UNIV
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