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Preparation method and application of an inorganic-organic composite sludge conditioner

A sludge conditioning and composite technology, which is applied in sludge treatment, water/sludge/sewage treatment, dehydration/drying/thickened sludge treatment, etc., can solve the problems of high cost, increased volume of sludge filter cake, and It can reduce the water content and achieve the effect of excellent effect.

Inactive Publication Date: 2021-03-16
SHENZHEN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] (1) Inorganic low-molecular conditioners are cheap and easy to obtain, but the dosage is large, generally reaching 5% to 20% of the dry solid weight of the sludge, which will lead to an increase in the volume of the sludge filter cake
Moreover, iron ions have a color, and iron salts are also highly corrosive, and chloride ions in water will also reduce the flocculation of alum, increasing the dosage of alum, so the use of inorganic low molecular conditioners has become less and less
[0015] (2) Synthetic organic polymer conditioners are expensive, generally difficult to degrade, and have biological toxicity. The most widely used PAM monomer is easy to remain in the sludge, and the dehydration rate is only 75%. ” effect, which is more harmful to the environment
Although chitosan is non-toxic and easy to degrade, it is difficult to reduce the dehydration rate to less than 60% when used alone, failing to achieve the purpose of deep dehydration
[0016] (3) Although the inorganic-organic composite conditioner has a good treatment effect, there are still problems such as refractory degradation and environmental pollution, and the synthesis of the composite conditioner is difficult. The inorganic-natural organic composite flocculant has poor stability due to the complex natural organic components. , it is difficult to carry out large-scale industrial production
[0017] (4) For microbial conditioners, there is a lack of research on mutagenesis breeding and gene control of excellent conditioner-producing bacteria, and there are disadvantages such as complex preparation process, long cycle, high cost and low yield.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A kind of preparation method of chitosan (CTS)-polyferric chloride (PFC) conditioning agent

[0048] Weigh a certain amount of chitosan at room temperature, dissolve it in 1% to 2% acetic acid solution, and prepare a chitosan solution of 1 to 2 mg / mL; prepare FeCl with a concentration of 0.5 mol / L 3 Put the solution in a beaker, add NaOH solution with a concentration of 0.25mol / L under rapid stirring to obtain a polyferric chloride solution with a degree of alkalinity of 1; Add it into the prepared polyferric chloride solution, wherein the mass ratio of CTS to PFC is 1, and the reaction time is 1h. After the reaction, the beaker was removed to cool down, and aged for 24 hours for later use.

Embodiment 2

[0050] A kind of preparation method of chitosan (CTS)-polyferric chloride (PFC) conditioning agent

[0051] Weigh a certain amount of chitosan at room temperature, dissolve it in 1% to 2% acetic acid solution, and prepare a chitosan solution of 1 to 2 mg / mL; prepare FeCl with a concentration of 0.5 mol / L 3 Put the solution in a beaker, add NaOH solution with a concentration of 0.25mol / L under rapid stirring to obtain a polyferric chloride solution with a degree of alkalinity of 1; Add it into the prepared polyferric chloride solution, wherein the mass ratio of CTS to PFC is 1.5, and the reaction time is 2h. After the reaction, the beaker was removed to cool down, and aged for 24 hours for later use.

Embodiment 3

[0053] A kind of method for sludge conditioning of inorganic-organic composite sludge conditioner

[0054] At first, add 500mL sludge sample in the beaker that measuring range is 1L, join the NaCl solution of 0,0.1,0.2,0.3,0.4,0.5mol / L in the beaker, stir 120 minutes at 80r / min; Then add (Example 1 sludge conditioner) 30mg / L The prepared sludge conditioner sludge mixture was stirred at 300r / min for 30s, then stirred at 80r / min for 3min; finally the sludge pyrolysis residue of 50% of the total mass of the aforementioned sludge was The powder (SR) was added into the beaker, and the sludge mixture was stirred at 80r / min for 5min.

[0055] The preparation method of sludge pyrolysis residue powder is to take a certain amount of sludge and put it into a microwave oven with a power of 1200W and a pyrolysis time of 20 minutes. After the pyrolysis is completed, take it out and grind it to pass through a 200-mesh sieve; the water content of the sludge residue is 0.

[0056] Among them...

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PUM

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Abstract

The invention belongs to the technical field of sludge treatment, relates to a preparation method and an application of a sludge dewatering conditioner, in particular to a preparation method and an application of an inorganic-organic compound sludge conditioner, and provides a novel method and a particular preparation method of a chitosan (CTS)-polymerization ferric chloride (PFC) compound conditioner. The novel method is characterized in that sludge is firstly treated by NaCl and then collectively treated by the chitosan (CTS)-polymerization ferric chloride (PFC) compound conditioner and sludge residue coagulant aid. The method is excellent in sludge dewatering effect, deep dewatering is achieved, and technical support is provided for sludge dewatering and subsequent treatment.

Description

technical field [0001] The invention belongs to the technical field of sludge treatment, and relates to the preparation and application of a sludge dehydration conditioner, in particular to a preparation method and application of an inorganic-organic composite sludge conditioner. Background technique [0002] Municipal sludge is a by-product produced in the process of sewage treatment. With the rapid development of my country's economy and rapid population growth, the amount of domestic sewage treatment in my country has increased year by year, and the amount of residual sludge has also increased rapidly. However, the investment and operating costs of sludge treatment are huge, accounting for 25% to 65% of the investment and operating costs of the entire sewage plant, which has become a heavy burden for urban sewage treatment plants. Sludge dehydration has become a very important link in the process of sludge treatment and disposal. It is of great significance to save subseq...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/148
CPCC02F11/14
Inventor 张培新权宗刚马睿孙世昌方琳
Owner SHENZHEN UNIV
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