Internal coating of metal packaging product and preparation method of internal coating
A metal packaging and inner coating technology, applied in coatings, polyester coatings, etc., can solve problems such as endangering human health and polluting the atmosphere, and achieve the effects of low cost, full coating film, and high solid content
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Embodiment 1
[0032] 56 parts by weight of n-pentanol are added to the reactor and the temperature is raised to 116°C, and 50 parts by weight of crotonic acid containing 7wt%, ethyl crotonic acid of 7wt%, polyester resin of 5wt%, and butene of 42wt% are added dropwise. Butyl methacrylate, 16wt% butyl ethacrylate, 3wt% methyl ethacrylate, 7wt% ethyl crotonate, 2wt% hydroxypropyl crotonate, 3wt% ethyl crotonate Glycidyl crotonate, 7wt% n-octyl crotonate crotonic acid mixed monomer, 0.3wt% cumene peroxide and 0.1wt% n-butyl The mixed solution that mercaptan is formed, and control finishes dropping in 5 hours, keep warm for 2 hours, add 0.1 weight part of cumene peroxide again, vacuumize and remove n-amyl alcohol after continuing to keep warm for 5 hours, subsequently the temperature of reaction system When the temperature is below 60°C, neutralize the pH value to 6.5 with ammonia water or an organic amine neutralizer, and finally add an appropriate amount of water to adjust the solid content t...
Embodiment 2
[0034] 60 parts by weight of n-pentanol are added to the reactor and the temperature is raised to 120° C., and 41 parts by weight of crotonic acid containing 10 wt %, ethyl crotonic acid of 3 wt %, ethyl crotonic acid of 7 wt %, 37 wt % of crotonic acid are added dropwise. butylphenol crotonate, 2wt% butyl crotonate, 20wt% cresol crotonate, 10wt% ethyl crotonate, 2wt% propyl crotonate, 5wt % ethyl crotonate glycidyl ester, 3wt% n-octyl crotonate crotonic acid mixed monomer, 0.4wt% cumene peroxide and 0.3wt% crotonic acid mixed monomer The mixed solution that n-butyl mercaptan is formed, and control finishes dropwise in 6 hours, keep warm for 2 hours, add 0.1 weight part of cumene peroxide again, vacuumize and remove n-amyl alcohol after continuing to keep warm for 3 hours, then react When the temperature of the system is below 60°C, the pH value is neutralized to 6.5 with ammonia water or an organic amine neutralizer, and finally an appropriate amount of water is added to adju...
Embodiment 3
[0036] Take by weighing as follows: the water-soluble resin prepared in embodiment 1: 30%, the polyester resin of 10wt%, hexamethoxyethyl melamine resin: 4%, triethylamine: 0.1%, glycerol ether : 0.6%, water: 41%, polyacrylate block copolymer dispersion: 1.5%, non-organic silicon defoamer 0.6%, crotonate nano-silica 0.4%, pigment red: 1%, Chin White powder: 9.0%, barium sulfate: 3%. The self-made water-soluble resin, polyester resin, water, polyacrylate block copolymer dispersant and crotonate
[0037] Disperse and stir nano-silica evenly, add pigment red, chromium white powder and barium sulfate to disperse and stir for 20 minutes, grind 3 to 4 times with a sand mill until the fineness is below 10 μm, add hexamethoxyethylmelamine resin, triethylamine, The glycerol ether and the antifoaming agent are dispersed and stirred for 30 minutes, and the dispersed product is adjusted with water to obtain the inner coating of the metal packaging product of the present invention.
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