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High-elasticity flame-retardant two-component wall surface material and preparation method thereof

A two-component, high-elasticity technology, applied in the field of mine ventilation, can solve the problems of wall cracking of ventilation structures, high cost of spraying materials, and increased air leakage.

Active Publication Date: 2019-01-25
SHANDONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the high ground pressure increases the deformation of the roadway, which leads to the cracking of the wall of the ventilation structure, which increases the amount of air leakage and affects the production safety of the mine.
[0003] Although some existing wall materials have good effects, there are certain problems in the process of use: the construction process of rockshou, aeglauni, and Ruimi sealing materials is complex, requiring special equipment, and the cost of QC spraying materials is high and the economic benefits are poor. , In addition, the walls of these materials are not smooth after spraying

Method used

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  • High-elasticity flame-retardant two-component wall surface material and preparation method thereof
  • High-elasticity flame-retardant two-component wall surface material and preparation method thereof
  • High-elasticity flame-retardant two-component wall surface material and preparation method thereof

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preparation example Construction

[0029] The present invention also provides a method for preparing the above-mentioned highly elastic flame-retardant two-component wall surface material, which includes the following steps:

[0030] A. Add the polyglycerol ether into the reaction vat, under the conditions of 105±5°C and vacuum degree of 0.085-0.09MPa, vacuum dehydration treatment for 1 hour, then lower it to below 60°C, add hydroquinone, stir evenly, and then Add toluene diisocyanate, nitrile rubber and polymethylpropionate, then raise the temperature to 80±5°C for two hours, cool down to below 60°C, and cool naturally to obtain the above-mentioned component A prepolymer;

[0031] B. Add liquid filler, dioctyl phthalate, and 1,4-butanediol into the reaction vat, heat up to 100±5°C while stirring, then add 3,3'-dichloro-4,4'- Diaminodiphenylmethane was reacted for 5 minutes, then calcium carbonate and antistatic agent were added for stirring and dehydration, and organic tin, diphenylamine and triphosphate were ...

Embodiment 1

[0035] According to parts by weight, it is made of the following raw materials by weight. The prepolymer of component A includes 700 parts of polyglycerol ether, 1.06 parts of hydroquinone, 90 parts of toluene diisocyanate, 100 parts of nitrile rubber, and polymethylpropionic acid 50 parts of ester; B component prepolymer including 650 parts of liquid filler, 20 parts of octyl phthalate, 30 parts of 1,4-butanediol, 3,3'-dichloro-4,4'-diamino 10 parts of diphenylmethane, 250 parts of calcium carbonate, 3.08 parts of antistatic agent, 1.03 parts of organic tin catalyst, 4.08 parts of diphenylamine, and 5.12 parts of triphosphate.

[0036] To obtain the above-mentioned highly elastic flame-retardant two-component wall material, the specific steps are:

[0037]Step 1: Add polyglycerol ether into the reaction vat at 105±5°C, vacuum degree 0.085-0.09MPa, vacuum dehydration for 1 hour, then drop below 60°C, add hydroquinone, stir evenly, Then add toluene diisocyanate, nitrile rubber...

Embodiment 2

[0041] According to parts by weight, it is made of the following raw materials by weight. The prepolymer of component A includes 750 parts of polyglycerol ether, 1.24 parts of hydroquinone, 81 parts of toluene diisocyanate, 82 parts of nitrile rubber, and polymethylpropionic acid 65 parts of ester; B-component prepolymer including 700 parts of liquid filler, 16.17 parts of octyl phthalate, 42 parts of 1,4-butanediol, 3,3'-dichloro-4,4'-diamino 12.12 parts of diphenylmethane, 214 parts of calcium carbonate, 5.06 parts of antistatic agent, 1.72 parts of organotin catalyst, 5.02 parts of diphenylamine, and 6.24 parts of triphosphate.

[0042] To obtain the above-mentioned highly elastic flame-retardant two-component wall material, the specific steps are:

[0043] Step 1: Add polyglycerol ether into the reaction vat at 105±5°C, vacuum degree 0.085-0.09MPa, vacuum dehydration for 1 hour, then drop below 60°C, add hydroquinone, stir evenly, Then add toluene diisocyanate, nitrile ru...

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Abstract

The invention discloses a high-elasticity flame-retardant two-component wall surface material and a preparation method thereof, wherein a component A prepolymer comprises polyglycerol ether, hydroquinone, toluene diisocyanate, nitrile butadiene rubber and polymethyl propionate, a component B prepolymer comprises a liquid filler, octyl phthalate, 1,4-butanediol, 3,3'-dichloro-4,4'-diaminodiphenylmethane, calcium carbonate, an antistatic agent, an organotin catalyst, diphenylamine and triphosphate, and the component A prepolymer and the component B prepolymer are completely mixed according to aratio of 2:1 to obtain the high-elasticity flame-retardant two-component wall surface material. According to the present invention, the coating has advantages of good compactness, noninflammability, simple construction and adjustable thickness; the component A prepolymer, the component B prepolymer and the novel wall surface material are the non-flammable materials, and can be directly coated ontothe wall; the thickness of the coating can be adjusted, such that the material can be used at mine shaft air doors, dampers, closed gaps and other easy-to-leakage places; and the material has good elasticity and strong tensile strength.

Description

technical field [0001] The invention relates to the technical field of mine ventilation, in particular to a highly elastic flame-retardant two-component wall surface material and a preparation method thereof. Background technique [0002] In order to realize the stability and reliability of the ventilation system, there must be a stable and reliable ventilation structure. However, with the improvement of the degree of mechanization of mine mining and the increase of coal mining depth, the section (roadway) of the construction point of ventilation facilities is required to increase continuously, and the ventilation facilities need to have higher pressure bearing capacity and air leakage prevention capacity. However, the high ground pressure increases the deformation of the roadway, which leads to the cracking of the wall of the ventilation structure, which increases the amount of air leakage and affects the production safety of the mine. [0003] Although some existing wall ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08L9/02C08L33/10C08L77/12C08K13/02C08K5/12C08K3/26C08K5/521C08G18/76C08G18/48
CPCC08G18/4829C08G18/7614C08K2003/265C08K2201/003C08L75/08C08L2201/02C08L2205/035C08L9/02C08L33/10C08L77/12C08K13/02C08K5/12C08K3/26C08K5/521
Inventor 苗德俊程英模徐毓名郑珂孔令晓
Owner SHANDONG UNIV OF SCI & TECH
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