Preparing method for tianeptine molecularly imprinted electrochemical sensor
A molecular and electrochemical technology of tianeptine, which is applied in the field of preparation of molecularly imprinted electrochemical sensors for tianeptine, can solve problems such as poor drop resistance, inability to properly match functional monomers and template molecules, and low sensitivity. question
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[0016] 1. Treatment of glassy carbon electrode
[0017] Polish the glassy carbon electrode on the polishing cloth with 1.0 μm, 0.3 μm and 0.05 μm alumina powder, then put it in a 1:1 volume ratio of nitric acid for 8 min, and then put it in absolute ethanol for 8 min , And finally clean with pure water ultrasonic cleaning.
[0018] 2. Preparation of tianeptine molecularly imprinted electrochemical sensor
[0019] Prepare 20 mL of a mixed aqueous solution of 0.25 mol / L cobalt sulfate, 0.25 mol / L nickel sulfate and 0.5 mol / L vitamin C with water as the solvent, and use benzyl alcohol as the solvent to prepare a concentration of 0.05 mol / L pentaerythritol 5 mL of distearyl diphosphite, and then add the prepared 5 mL of pentaerythritol diphosphite distearyl solution at a rate of 5 drops per second to the 20 mL of cobalt sulfate, nickel sulfate and vitamin C prepared above In the mixed solution, stir vigorously at a speed of 2500 rpm during the dripping process, and then react in a 50 ...
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