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A kind of cool feeling nylon 6 staple fiber and preparation method thereof

A technology of short fiber and cool feeling, which is applied in the field of cool feeling nylon 6 short fiber and its preparation, which can solve the problems of short duration of cold feeling, disappearing cool feeling of products, poor air permeability, etc., and achieve fast reaction rate and less side effects , the effect of high production efficiency

Active Publication Date: 2021-05-21
江苏恒创园区管理服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the cool fiber experience that has been developed so far is still insufficient, and there are still some problems in the preparation of cool fiber, which are mainly reflected in the following aspects: 1) the problem that the coolness of the touch is not long; At the beginning of textile use, because the temperature was not high at that time, it did feel cool to the touch, but as the use time increased and the temperature rose sharply, the cool feeling of the product disappeared; 2) The problem of poor air permeability; Having a cool feeling does not mean that the fiber itself has good breathability and moisture absorption and perspiration effects. To make the fiber feel really cool, not only must the material be extremely cool, but it must also meet the actual needs of the human body for heat dissipation in summer; 3) In order to pursue coolness, researchers need to modify fiber products, which will more or less affect other properties of fibers, such as mechanics, electrical conductivity or UV resistance, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A kind of preparation method of cool feeling nylon 6 staple fiber, concrete steps are as follows:

[0046] (1) prepare mixture;

[0047] (1.1) Pretreatment of cooling functional powder;

[0048] First, disperse the cooling functional powder with a particle size of 12-32nm in absolute ethanol to obtain a suspension with a solid content of 13wt%, then put the suspension into a grinder and grind it for 2.5 hours, and then add caprolactam sodium salt Grinding at 55°C for 1 hour, and finally after 4 hours of slurry aging, drying and jet milling to obtain the pretreated cooling function powder, wherein the cooling function powder refers to mica and jade with a mass ratio of 1:1 The compounded powder has a thermal conductivity of 1.55W / m·K, and the surface of the cool-feeling functional powder is coated with caprolactam sodium salt;

[0049] (1.2) mixing;

[0050] First, put the pretreated cool-feeling functional powder in the melt of caprolactam and heptadecane, then mecha...

Embodiment 2

[0056] A kind of preparation method of cool feeling nylon 6 staple fiber, concrete steps are as follows:

[0057] (1) prepare mixture;

[0058] (1.1) Pretreatment of cooling functional powder;

[0059] First, disperse the cooling functional powder with a particle size of 30-55nm in absolute ethanol to obtain a suspension with a solid content of 18wt%, then put the suspension into a grinder and grind it for 2 hours, and then add caprolactam magnesium bromide Grinding at 50°C for 1 hour, and finally after 11 hours of slurry aging, drying and jet milling to obtain the pretreated cooling function powder, wherein the cooling function powder refers to jade and Tai Chi with a mass ratio of 1:2 The thermal conductivity of the powder compounded with stone is 1.6W / m·K, and the surface of the cooling functional powder is coated with caprolactam magnesium bromide;

[0060] (1.2) mixing;

[0061] First, place the pretreated cooling functional powder in the melt of caprolactam and octade...

Embodiment 3

[0067] A kind of preparation method of cool feeling nylon 6 staple fiber, concrete steps are as follows:

[0068] (1) prepare mixture;

[0069] (1.1) Pretreatment of cooling functional powder;

[0070] First, disperse the cooling functional powder with a particle size of 5.8-12.5nm in absolute ethanol to obtain a suspension with a solid content of 10wt%, then add the suspension to a grinder for grinding for 3 hours, and then add Grignard reagent Grinding at 80°C for 2.5 hours, and finally after 5 hours of slurry aging, drying and airflow pulverization to obtain the pretreated cooling function powder, wherein the cooling function powder refers to the mass ratio of 1:1 mica and The thermal conductivity of Taichi stone is 1.2W / m·K. The surface of the cooling powder is coated with Grignard reagent, which is a commercially available alkylmagnesium halide organic compound;

[0071] (1.2) mixing;

[0072] First, place the pretreated cooling functional powder in a mixture of heptad...

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Abstract

The invention relates to a cool-feeling nylon 6 staple fiber and a preparation method thereof. The method is as follows: cool-feeling nylon 6 slices are spun to obtain cool-feeling nylon 6 short fibers, and the cool-feeling nylon 6 is made of a mixture successively passed through a cool-feeling functional powder The surface chain growth reaction, ring-opening pre-condensation reaction and final polycondensation reaction; the mixture is mainly composed of cool functional powder coated with catalyst on the surface, phase change material, caprolactam and water; the surface chain of cool functional powder The growth reaction refers to the reaction in which the caprolactam enriched on the surface of the cool-feeling functional powder is polymerized to form a linear molecular chain under the action of a catalyst; the Qmax of the prepared cool-feeling nylon 6 staple fiber is 0.15-0.35W / cm 2 , it takes 30 to 40 seconds to reach equilibrium after contacting the human body. The preparation method of the present invention has few side reactions, fast reaction rate and high efficiency, and the prepared cool-feeling nylon 6 short fiber can keep cool feel continuously at a relatively high temperature, and has high popularization value.

Description

technical field [0001] The invention belongs to the field of nylon preparation, and relates to cool-feeling nylon 6 staple fiber and a preparation method thereof. Background technique [0002] Nylon fiber refers to a polymer whose main chain contains polar amide groups (-CONH-). Nylon can be obtained by ring-opening polymerization of caprolactam, or by polycondensation of diamine and dibasic acid. Among them, nylon fiber mainly refers to Nylon 6 (PA6) is a kind of polymer with excellent performance and wide application. [0003] Along with the diversified demand for clothing fiber products, people are paying more and more attention to the development of new nylon differentiated fiber materials. New nylon differentiated fiber materials include new nylon prepared from new monomers and co-nylon esters that are copolymerized and modified from existing nylon. Through differential modification, researchers have differentially applied some properties that people need daily, such ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/90D01F1/10C08G69/16C08G69/14
CPCC08G69/14C08G69/16D01F1/10D01F6/90
Inventor 余志赵岭林敏吉鹏王朝生陈烨张圣明
Owner 江苏恒创园区管理服务有限公司