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Heat-storage warm-keeping chinlon 6 short fiber and preparation method thereof

A short fiber heat storage technology, which is applied in the field of nylon preparation, can solve the problems of loss of heat preservation effect, poor durability, and reduced melt fluidity, and achieve good heat storage and heat preservation performance, good heat storage and heat preservation effect, and not easy to settle Effect

Active Publication Date: 2019-03-01
恒天中纤纺化无锡有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, the Chinese patent application number 20111038048.4 discloses a manufacturing method of polyester hollow micro-denier fiber, which increases the amount of static air in the fiber by increasing the hollowness of the fiber, improves the thermal resistance, and achieves the effect of keeping warm, but with extrusion With the increase of washing times, the hollow fiber deforms and gradually loses its heat preservation effect; the Chinese patent application number 20111009869.3 discloses a hygroscopic heating fiber and its preparation method, which improves the water absorption rate of the fiber by introducing water-absorbing groups, thereby absorbing human body evaporation The water vapor converts kinetic energy into heat energy to keep warm; the Chinese patent application number CN20171024165.6 discloses a far-infrared polyester fiber. By adding nano-powder, the fiber can absorb the infrared rays radiated by the human body and emit infrared rays to the human body. Radiation of far-infrared rays achieves the effect of keeping warm and health care
Although the above patents have improved the warmth retention of fibers or fabrics, there are problems such as single function, poor durability, narrow heat source, low calorific value, and poor powder dispersibility, and as the amount of powder added increases, the fluidity of the melt decreases. poor processability

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Heat-storage warm-keeping chinlon 6 short fiber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A kind of preparation method of heat-storing and warm-keeping nylon 6 staple fiber, concrete steps are as follows:

[0044] (1) Modification of heat storage powder;

[0045] First FeMnCuO 4 , TiC and ZrC mixed powder (mass ratio is 2:3:7) and absolute ethanol are made into a suspension with a solid content of 15wt%, and then the suspension is added to a grinder for grinding for 4 hours, and then sodium caprolactam is added The salt is ground at 80°C for 2 hours, and finally after 8 hours of slurry aging, it is dried and jet-milled to obtain a modified thermal storage powder with a particle size of 100nm-500nm;

[0046] (2) mixing;

[0047] Put the modified heat storage powder in the caprolactam melt, then mechanically stir for 20 minutes, then ultrasonically disperse for 20 minutes, and finally centrifugally settle for 10 seconds, take the upper stable dispersion, mix and stir with water and cyclopentane tetraacid to obtain a mixture, in the mixture, The mass ratio o...

Embodiment 2

[0052] A kind of preparation method of heat-storing and warm-keeping nylon 6 staple fiber, concrete steps are as follows:

[0053] (1) Modification of heat storage powder;

[0054] First FeMnCuO 4 , TiC and ZrO 2 The mixed powder (mass ratio is 2:3:4) and dehydrated alcohol are made into the suspension liquid that solid content is 22wt%, then add suspension liquid in grinder and grind 3h, then add caprolactam magnesium bromide at 50 Grinding at ℃ for 3 hours, and finally after 8 hours of slurry aging, drying and airflow pulverization to obtain a modified heat storage powder with a particle size of 800nm ​​to 1100nm;

[0055] (2) mixing;

[0056] Put the modified heat storage powder in the caprolactam melt, then mechanically stir for 15 minutes, then ultrasonically disperse for 10 minutes, and finally centrifugally settle for 5 seconds, take the upper stable dispersion, mix and stir with water and pyromellitic acid to obtain a mixture, in the mixture, water The mass ratio t...

Embodiment 3

[0068] A kind of preparation method of heat-storing and warm-keeping nylon 6 staple fiber, concrete steps are as follows:

[0069] (1) Modification of heat storage powder;

[0070] First FeMnCuO 4 , ZrC and ZrO 2 The mixed powder (mass ratio is 2:3:4) and absolute ethanol are made into a suspension with a solid content of 15wt%, and then the suspension is added to a grinder for grinding for 4 hours, and then caprolactam sodium salt is added at 60°C Grinding for 1 hour, and finally after 6 hours of slurry aging, drying and airflow crushing to obtain a modified heat storage powder with a particle size of 300nm to 700nm;

[0071] (2) mixing;

[0072] Put the modified heat storage powder in the caprolactam melt, then mechanically stir for 20 minutes, then ultrasonically disperse for 15 minutes, and finally centrifugally settle for 1 minute, take the upper stable dispersion, mix and stir with water and benzophenone tetraacid to obtain a mixture, in the mixture, The mass ratio of ...

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Abstract

The invention relates to a heat-storage warm-keeping chinlon 6 short fiber and a preparation method thereof. The method includes: spinning a heat-storage warm-keeping chinlon 6 melt to prepare a heat-storage warm-keeping chinlon 6 short fiber, wherein the chinlon 6 is prepared from a mixture of caprolactam, a heat-storage powder coated with a catalyst, and water, and successively through a heat-storage powder surface chain growth reaction, a ring-opening pre-polycondensation reaction and a final-polycondensation reaction; wherein the heat-storage powder surface chain growth reaction is a reaction that the caprolactam on the surface of the heat-storage powder is polymerized to form a linear molecular chain under effect of the catalyst. A fabric, being 200-250 g / m<2> in gram weight and prepared from the fiber, is not less than 0.944 m<2>*K / W in thermal resistance, not less than 6.09 in Clo value, not less than 91.4% in warm-keeping rate, not less than 0.90 in far-infrared emissivity andnot less than 1.5 DEG C in far-infrared radiation temperature increasing value. The heat-storage warm-keeping chinlon 6 short fiber has good dispersion uniformity of the heat-storage powder and has excellent heat-storage and warm-keeping function.

Description

technical field [0001] The invention belongs to the field of nylon preparation, and relates to a thermal storage and heat preservation nylon 6 short fiber and a preparation method thereof. Background technique [0002] Nylon 6 staple fiber, also known as nylon 6 or nylon 6, is one of the main varieties of synthetic fibers. Its molecular structure is regularly arranged and many hydrogen bonds are formed between macromolecules, which makes nylon 6 staple fiber have high strength, good resilience, and durability. It is widely used in the fields of clothing or home textiles due to its excellent abrasiveness and strong moisture absorption capacity. As one of the main raw materials of clothing textiles, how to improve the warmth retention of nylon 6 staple fiber is a problem that people and researchers pay more attention to. [0003] At present, there are many types of thermal fibers on the market. The thermal fibers on the market mainly achieve the effect of heating and keeping ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D01F6/90D01F1/10C08G69/14C08G69/16
CPCC08G69/14C08G69/16D01F1/10D01F6/90
Inventor 林敏赵岭余志吉鹏王华平王朝生黄家鹏
Owner 恒天中纤纺化无锡有限公司