Heat-storage warm-keeping chinlon 6 short fiber and preparation method thereof
A short fiber heat storage technology, which is applied in the field of nylon preparation, can solve the problems of loss of heat preservation effect, poor durability, and reduced melt fluidity, and achieve good heat storage and heat preservation performance, good heat storage and heat preservation effect, and not easy to settle Effect
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Embodiment 1
[0043] A kind of preparation method of heat-storing and warm-keeping nylon 6 staple fiber, concrete steps are as follows:
[0044] (1) Modification of heat storage powder;
[0045] First FeMnCuO 4 , TiC and ZrC mixed powder (mass ratio is 2:3:7) and absolute ethanol are made into a suspension with a solid content of 15wt%, and then the suspension is added to a grinder for grinding for 4 hours, and then sodium caprolactam is added The salt is ground at 80°C for 2 hours, and finally after 8 hours of slurry aging, it is dried and jet-milled to obtain a modified thermal storage powder with a particle size of 100nm-500nm;
[0046] (2) mixing;
[0047] Put the modified heat storage powder in the caprolactam melt, then mechanically stir for 20 minutes, then ultrasonically disperse for 20 minutes, and finally centrifugally settle for 10 seconds, take the upper stable dispersion, mix and stir with water and cyclopentane tetraacid to obtain a mixture, in the mixture, The mass ratio o...
Embodiment 2
[0052] A kind of preparation method of heat-storing and warm-keeping nylon 6 staple fiber, concrete steps are as follows:
[0053] (1) Modification of heat storage powder;
[0054] First FeMnCuO 4 , TiC and ZrO 2 The mixed powder (mass ratio is 2:3:4) and dehydrated alcohol are made into the suspension liquid that solid content is 22wt%, then add suspension liquid in grinder and grind 3h, then add caprolactam magnesium bromide at 50 Grinding at ℃ for 3 hours, and finally after 8 hours of slurry aging, drying and airflow pulverization to obtain a modified heat storage powder with a particle size of 800nm to 1100nm;
[0055] (2) mixing;
[0056] Put the modified heat storage powder in the caprolactam melt, then mechanically stir for 15 minutes, then ultrasonically disperse for 10 minutes, and finally centrifugally settle for 5 seconds, take the upper stable dispersion, mix and stir with water and pyromellitic acid to obtain a mixture, in the mixture, water The mass ratio t...
Embodiment 3
[0068] A kind of preparation method of heat-storing and warm-keeping nylon 6 staple fiber, concrete steps are as follows:
[0069] (1) Modification of heat storage powder;
[0070] First FeMnCuO 4 , ZrC and ZrO 2 The mixed powder (mass ratio is 2:3:4) and absolute ethanol are made into a suspension with a solid content of 15wt%, and then the suspension is added to a grinder for grinding for 4 hours, and then caprolactam sodium salt is added at 60°C Grinding for 1 hour, and finally after 6 hours of slurry aging, drying and airflow crushing to obtain a modified heat storage powder with a particle size of 300nm to 700nm;
[0071] (2) mixing;
[0072] Put the modified heat storage powder in the caprolactam melt, then mechanically stir for 20 minutes, then ultrasonically disperse for 15 minutes, and finally centrifugally settle for 1 minute, take the upper stable dispersion, mix and stir with water and benzophenone tetraacid to obtain a mixture, in the mixture, The mass ratio of ...
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