High-rigidity low-water-absorption nylon 6 composite material

A composite material, low water absorption technology, applied in the field of nylon modification, can solve the problems of affecting the dimensional stability of the product, the existence of defects in mechanical strength, and the decrease of material rigidity. Effect

Active Publication Date: 2019-04-23
厦门德丰行塑胶工业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyamide fiber, commonly known as nylon, or PA for short, is a thermoplastic resin containing repeated amide groups on the main molecular chain. Moreover, the process temperature range is very wide, and its impact resistance and solubility resistance are better than nylon 66 plastics. It is widely used in petrochemical, national defense, machinery and textile industries. It is an important engineering plastic, but due to the large water absorption of nylon , leading to a large decrease in material rigidity, defects in mechanical strength, and high moisture absorption rate, resulting in a large molding shrinkage rate and affecting the dimensional stability of the product. Some nylon products that are used in contact with water, such as bathroom interior parts and irrigation shells Products, after long-term contact with water, the rigidity of the water-absorbing material decreases and it is easy to break

Method used

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  • High-rigidity low-water-absorption nylon 6 composite material
  • High-rigidity low-water-absorption nylon 6 composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A kind of nylon 6 composite material with high rigidity and low water absorption, comprising the following raw materials in parts by weight: 6100 parts of nylon, 10 parts of polym-xylylenediamine adipamide, 3 parts of nano-montmorillonite, 30 parts of alkali-free glass fiber, silane diacetate 1 part of joint agent solution, 3 parts of nano-layered silicate, 5 parts of acrylonitrile-butadiene-styrene-terpolymer, 1 part of polytetrafluoroethylene (PTFE), maleic anhydride grafted ethylene-octyl 3 parts of vinyl copolymer, 1 part of compatibilizer, 0.1 part of tris(2,4-di-tert-butylphenyl) phosphite, 0.1 part of silicone masterbatch, 0.1 part of H10.

[0019] The silane coupling agent solution is a solution prepared by γ-aminopropyltriethoxysilane and methanol or ethanol with a mass ratio of 1:3;

[0020] The compatibilizer is a vinyl elastomer bifunctionalized with maleic anhydride and acrylate.

[0021] The glass fibers are chopped glass fibers with a single filament dia...

Embodiment 2

[0029] A kind of nylon 6 composite material with high rigidity and low water absorption, comprising the following raw materials in parts by weight: nylon 6110 parts, polym-xylylenediamine adipamide 20 parts, nano-montmorillonite 4 parts, alkali-free glass fiber 40 parts, silane di 1.5 parts of joint agent solution, 4 parts of nano-layered silicate, 8 parts of acrylonitrile-butadiene-styrene-terpolymer, 5 parts of polytetrafluoroethylene (PTFE), maleic anhydride grafted ethylene-octyl 4 parts of vinyl copolymer, 3 parts of compatibilizer, 0.5 parts of tris(2,4-di-tert-butylphenyl) phosphite, 0.5 parts of silicone masterbatch, and 0.5 parts of H20.

[0030] The silane coupling agent solution is a solution prepared by γ-aminopropyltriethoxysilane and methanol or ethanol with a mass ratio of 1:3.

[0031] The compatibilizer is a vinyl elastomer bifunctionalized with maleic anhydride and acrylate.

[0032] The alkali-free glass fibers are chopped glass fibers with a single filamen...

Embodiment 3

[0036] A kind of nylon 6 composite material with high rigidity and low water absorption, comprising the following raw materials in parts by weight: 120 parts of nylon, 30 parts of polym-xylylenediamine adipamide, 5 parts of nanometer montmorillonite, 50 parts of alkali-free glass fiber, silane diacetate 2 parts of joint agent solution, 5 parts of nano-layered silicate, 10 parts of acrylonitrile-butadiene-styrene-terpolymer, 10 parts of polytetrafluoroethylene (PTFE), maleic anhydride grafted ethylene-octyl 5 parts of vinyl copolymer, 5 parts of compatibilizer, 1 part of tris(2,4-di-tert-butylphenyl) phosphite, 1 part of silicone masterbatch, 1 part of HS-03.

[0037] The silane coupling agent solution is a solution prepared by γ-aminopropyltriethoxysilane and methanol or ethanol with a mass ratio of 1:3;

[0038] The compatibilizer is a vinyl elastomer bifunctionalized with maleic anhydride and acrylate.

[0039] The glass fibers are chopped glass fibers with a single filamen...

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Abstract

The invention discloses a high-rigidity low-water-absorption nylon 6 composite material. The high-rigidity low-water-absorption nylon 6 composite material is characterized by being prepared from the following raw materials in parts by weight: 100 to 120 parts of nylon 6, 10 to 30 parts of barrier, 3 to 5 parts of nano montmorillonite, 30 to 50 parts of alkali-free glass fibers, 1 to 2 parts of silane coupling agent solution, 3 to 5 parts of nano layered silicate, 5 to 10 parts of acrylonitrile-butadiene-styrene-terpolymer, 1 to 10 parts of polytetrafluoroethylene, 3 to 5 parts of toughening agent, 1 to 5 parts of compatilizer, 0.1 to 1 part of heat resisting agent, 0.1 to 1 part of antioxidant, and 0.1 to 1 part of lubricating agent. The high-rigidity low-water-absorption nylon 6 compositematerial can still keep good rigidity in a water environment.

Description

technical field [0001] The invention relates to the technical field of nylon modification, in particular to a nylon 6 composite material with high rigidity and low water absorption. Background technique [0002] Polyamide fiber, commonly known as nylon, or PA for short, is a thermoplastic resin containing repeated amide groups on the main molecular chain. Moreover, the process temperature range is very wide, and its impact resistance and solubility resistance are better than nylon 66 plastics. It is widely used in petrochemical, national defense, machinery and textile industries. It is an important engineering plastic, but due to the large water absorption of nylon , leading to a large decrease in material rigidity, defects in mechanical strength, and high moisture absorption rate, resulting in a large molding shrinkage rate and affecting the dimensional stability of the product. Some nylon products that are used in contact with water, such as bathroom interior parts and irr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08L55/02C08L27/18C08K13/04C08K3/34C08K7/14
CPCC08K2201/003C08K2201/006C08K2201/011C08L77/02C08L2205/02C08L2205/035C08L2205/24C08L77/06C08L55/02C08L27/18C08K13/04C08K3/346C08K7/14C08K3/34
Inventor 黄志勤熊吉辉曾晓强
Owner 厦门德丰行塑胶工业有限公司
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