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POK/PET/PBT (polyketone/polyethylene terephthalate/polybutylene terephthalate) ternary alloy material and preparation process thereof

A ternary alloy and compatibilizer technology, applied in the field of POK/PET/PBT ternary alloy material and its preparation process, can solve the problem of poor antistatic performance and flame retardancy, and adjust POK/PET/PBT ternary alloy material Toughness and hardness, limit the scope of use and other issues, to achieve good dimensional stability, good processing performance, increase the effect of practicality

Inactive Publication Date: 2019-05-31
广东壹豪新材料科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to provide a POK / PET / PBT ternary alloy material and its preparation process, which can make the POK / PET / PBT ternary alloy material have excellent antistatic performance and flame retardancy, and can be reasonably adjusted according to requirements The advantages of toughness and hardness of POK / PET / PBT ternary alloy materials solve the problem that the existing POK / PET / PBT ternary alloy materials have poor antistatic performance and flame retardancy, and cannot reasonably adjust POK / PET / The toughness and hardness of PBT ternary alloy materials, which in turn limit the scope of use of POK / PET / PBT ternary alloy materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The invention provides a technical solution: a POK / PET / PBT ternary alloy material, the components of which are proportioned by mass percentage: polyethylene terephthalate 25%, polybutylene terephthalate 30% ester, 20% polyketone, 5% antistatic agent, 10% halogen-free flame retardant, 0.5% compatibilizer, 0.5% lubricant, 5% antioxidant, 1% toughening agent and 3% reinforcing agent.

[0024] In the present invention: the antistatic agent is an antistatic agent formed by compounding alkylbenzene sulfonate and siloxane, and the mass ratio of alkylbenzene sulfonate and siloxane in the antistatic agent is 7:2.

[0025] In the present invention: the toughening agent is a mixture of methyl methacrylate-butadiene-styrene terpolymer and acrylonitrile-butadiene-styrene copolymer.

[0026] In the present invention: the compatibilizer is a mixture of a cyclic anhydride type compatibilizer and an isocyanate type compatibilizer.

[0027] In the present invention: the halogen-free fla...

Embodiment 2

[0034] Embodiment 2: This implementation differs from Embodiment 1 in that:

[0035] The invention provides a technical solution: a POK / PET / PBT ternary alloy material, the components of which are proportioned by mass percentage: polyethylene terephthalate 30%, polybutylene terephthalate 30% ester, 20% polyketone, 4% antistatic agent, 9% halogen-free flame retardant, 0.2% compatibilizer, 0.8% lubricant, 3% antioxidant, 1% toughening agent and 2% reinforcing agent.

[0036] In the present invention: the antistatic agent is an antistatic agent formed by compounding alkylbenzene sulfonate and siloxane, and the mass ratio of alkylbenzene sulfonate and siloxane in the antistatic agent is 8:3.

[0037] In the present invention: the toughening agent is a mixture of styrene-butadiene thermoplastic elastomer and polyimide.

[0038] In the present invention: the compatibilizer is a mixture of epoxy resin type compatibilizer, oxazoline type compatibilizer and isocyanate type compatibiliz...

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PUM

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Abstract

The invention discloses a POK / PET / PBT (polyketone / polyethylene terephthalate / polybutylene terephthalate) ternary alloy material, comprising, by mass, 20-30% of polyethylene terephthalate, 20-30% of polybutylene terephthalate, 10-20% of a polyketone, 1-5% of an antistatic agent, 5-10% of a halogen-free flame retardant, 0.1-0.5% of a compatibilizer, 0.2-0.8% of a lubricant, 1-5% of an antioxidant, 0.5-1% of a toughener, and 1-3% of an enhancer. A preparation process of the invention is simple, convenient to operate and control, good in quality, high in production efficiency, low in cost and suitable for large-scale industrial production; the POK / PET / PBT ternary alloy material has good toughness, corrosion resistance, wear resistance, oil resistance, impact resistance and the like, is environmentally friendly and flame retardant, and has good forming property; the POK / PET / PBT ternary alloy material made by means of blending with the antistatic agent has efficient and lasting static resistance; the toughness and hardness of the POK / PET / PBT ternary alloy material can be adjusted according to different needs.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a POK / PET / PBT ternary alloy material and a preparation process thereof. Background technique [0002] Polybutylene terephthalate (PBT) is a thermoplastic polyester developed in the 1970s. It has excellent mechanical, electrical, high temperature resistance, moisture resistance, chemical corrosion resistance, good electrical insulation performance, good elasticity, crystallization It has the characteristics of fast speed, good fluidity and easy forming and processing, and can maintain good mechanical properties in a wide temperature range. Due to the unique properties of PBT products, PBT engineering plastics and various alloys are widely used in electronic appliances and household appliances. It is an indispensable new material in various fields such as automobile, machinery, instrument, light textile and civil use. With the progress of science and technology and the de...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L61/02C08L51/04C08L55/02C08L67/00C08L81/02C08K13/04C08K7/10C08K5/20C08K5/42C08K3/22
Inventor 郑豪
Owner 广东壹豪新材料科技股份有限公司
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