Cone mill roll biomass rapid catalytic pyrolysis reactor and pyrolysis method thereof

A technology of catalytic pyrolysis and conical grinding, which is applied in the direction of biofuel, special dry distillation, liquid hydrocarbon mixture preparation, etc. It can solve the problem that the catalytic pyrolysis product is not as good as the direct catalytic reaction, it is difficult to ensure the catalytic effect of the catalyst, and the condensation of pyrolysis gas Difficulties and other problems, to achieve the effect of compact structure, good catalytic effect, and reduced scale

Active Publication Date: 2019-07-12
NORTH CHINA ELECTRIC POWER UNIV (BAODING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for the current mainstream pyrolysis reactors: moving mechanical structures, such as rotating cones, ablation types, etc., it is difficult to make the catalyst penetrate into the particle to directly catalyze the pyrolysis reaction only by relying on centrifugal force, and the effect of catalyzing the pyrolysis product is not It is not as good as a direct catalytic reaction; for the pressure roller structure, the raw material particles also become compact during the rolling process, and it is also difficult to ensure the catalytic effect of the catalyst on

Method used

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  • Cone mill roll biomass rapid catalytic pyrolysis reactor and pyrolysis method thereof
  • Cone mill roll biomass rapid catalytic pyrolysis reactor and pyrolysis method thereof
  • Cone mill roll biomass rapid catalytic pyrolysis reactor and pyrolysis method thereof

Examples

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Effect test

Embodiment 1

[0036] Willow with a moisture content of 6wt% is crushed to an average particle size of 10mm, and is fed into the pyrolysis reactor through a screw feed system at a feed rate of 100kg / h; the catalytic tank 102 is only set as a friction layer and filled with friction paint; The speed of the conical grinding roller 1 is 300r / min; the temperature of the hot flue gas in the flue 6 is 670°C, and the measured temperature in the pyrolysis reactor is 500°C; the pyrolysis product is separated and condensed to obtain three Phase pyrolysis products, wherein the yield of coke is 20.1wt%, the yield of bio-oil is 60.3wt%, and the yield of combustible gas is 19.6wt%.

Embodiment 2

[0038] Hazelnut shells with a moisture content of 7wt% are crushed to an average particle size of 10mm; the screw feed system is fed into the feed port 4 with a feed rate of 80kg / h; by adjusting the power of the motor, the conical grinding roller 1 The rotation speed is 150r / min; the catalytic tank only uses the friction coating as the friction layer, and the ZnCl 2 The catalyst is introduced by directly impregnating the raw material during pretreatment, with a load of 16.7wt%; the temperature of the flue gas entering the flue 6 is 480°C, and the temperature in the pyrolysis reactor is guaranteed to be 340°C; the pyrolysis product is gas-solidified After separation and condensation of the pyrolysis gas, three-phase pyrolysis products of coke, bio-oil and combustible gas are obtained, and the respective yields are 49.3wt%, 42.1wt% and 8.6wt%, and the yield of the target product furfural is 7.3wt% .

Embodiment 3

[0040] The rice husks with a water content of 8wt% are crushed to an average particle size of 12mm, and the feed rate is 120kg / h and sent to the feed inlet 4 through a screw feed system; the rotating speed of the conical grinding roller 1 is controlled to maintain 150r / min; No catalyst is introduced, and the entire catalytic tank is set as a friction layer; the temperature of the flue gas entering the flue 6 is 700°C, and the temperature in the pyrolysis reactor is 520°C; The yields of solid, liquid and gas three-phase pyrolysis products are 28.1wt%, 49.7wt% and 22.2w%, respectively.

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Abstract

The invention relates to a cone mill roll biomass rapid catalytic pyrolysis reactor and a pyrolysis method thereof. The pyrolysis reactor comprises a gas outlet, a feed inlet, a discharge hole, a conemill roll, a friction wall, a smoke flue, a closed shell, a carbon collection box and a sealing filler, wherein the cone mill roll consists of a cone roll body, a catalysis groove, a friction belt and a rotating shaft. Pretreated biomass particles suffer from the heating of the friction wall, and the surfaces of the pretreated biomass particles are rapidly warmed for a pyrolytic reaction; simultaneously, under the pushing extrusion of the friction belt, the materials suffer from the friction shearing action of the cone mill roll and the friction wall, the catalyst and heat can be sufficientlyfed into the interiors of the particles through surface residual carbon generated after the materials are constantly peeled and pyrolyzed, and efficient catalytic reaction is guaranteed; pyrolysis gas is rapidly condensed after gas-solid separation so as to obtain high-grade bio-oil fuel or bio-oil rich in specific high value-added products; and moreover, combustible gas and coke are colleted, high temperature flue gas is generated after combustion and is used for heating the shell, and a self-heating type pyrolysis process is realized.

Description

technical field [0001] The invention belongs to the technical field of biomass energy utilization, and in particular relates to a conical grinding roller type biomass rapid catalytic pyrolysis reactor and a pyrolysis method thereof. Background technique [0002] As the only renewable energy that can be directly converted into liquid fuels, biomass has attracted worldwide attention due to its advantages such as huge output, storability and carbon cycle. Converting a large amount of garbage and agricultural and forestry waste generated every year into bio-oil through rapid pyrolysis technology is equivalent to adding tens of millions of tons of oil equivalent energy each year, which can significantly improve my country's energy security and effectively reduce pollutants and greenhouse gas emissions. At the same time, through directional regulation of the biomass pyrolysis process (such as using catalysts for catalytic pyrolysis of biomass), the grade of bio-oil can be improved...

Claims

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Application Information

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IPC IPC(8): C10B53/02C10G1/00
CPCC10B53/02C10G1/00C10G2300/1014Y02E50/10
Inventor 陆强谢文銮张镇西马善为杨勇平
Owner NORTH CHINA ELECTRIC POWER UNIV (BAODING)
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