Method for preparing aluminum and white copper alloy by utilizing recovery of waste lithium battery
A waste lithium battery and alloy technology, applied in the direction of improvement of process efficiency, furnace type, furnace, etc., can solve the problems of natural environment and human health threats, high cost of copper and aluminum separation, different particle sizes, etc., and achieve fast production efficiency , low pollution, high safety effect
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Embodiment 1
[0013] A method for preparing aluminum-nickel-nickel alloy by recycling waste lithium batteries, carried out according to the following steps,
[0014] (a) Crushing the waste lithium battery and sorting the active material powder and the mixed powder containing copper and aluminum; the crushing includes two steps of coarse crushing and fine crushing, and the active material powder generally contains nickel, cobalt, manganese, lithium, and graphite powder And a small amount of copper and aluminum elements, the mixed powder containing copper and aluminum contains copper, aluminum and a small amount of active material powder; the sorted mixed particles containing copper and aluminum are placed in a sieving machine to screen out copper-rich materials; after testing, In the copper-rich material, the mass content of copper is 88%, the mass content of aluminum is 9%, and the total mass content of nickel, cobalt, manganese, lithium, graphite, etc. is 3%;
[0015] (b) Melt the copper-r...
Embodiment 2
[0021] A method for preparing aluminum-nickel-nickel alloy by recycling waste lithium batteries, the steps of which are basically the same as those of the method for preparing aluminum-nickel-nickel alloy by recycling waste lithium batteries in Example 1, except that:
[0022] 1. In step (a), after testing, in the copper-rich material, the mass content of copper is 97%, the mass content of aluminum is 2%, and the total mass content of nickel, cobalt, manganese, lithium, graphite, etc. is 1%;
[0023] 2. In step (b), the temperature of the refining reverberatory furnace is controlled to be 1350° C., and the melting time is controlled to be 4 hours; the auxiliary reductant is natural gas with a pressure of 0.2 Mpa, and the quality of natural gas added is based on the content of sulfur in the semi-finished alloy product. 0.009% is controlled; the flux uses quartz stone with a silicon dioxide content of more than 90%, and the added quality of quartz stone is 3% of the added mass of...
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