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Aqueous formaldehyde-free painting pigment and preparation method thereof

A formaldehyde and painting technology, applied in the field of water-based formaldehyde-free painting pigments and their preparation, can solve the problems of high pigment manufacturing cost, dermatitis, aquatic toxicity, etc. Effect

Active Publication Date: 2019-08-06
河北青竹画材科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, formaldehyde is extremely harmful to the human body, mainly due to sensitization and stimulation, and it is also a genotoxic substance. During the use of the product, free formaldehyde is released, which can cause respiratory tract infection or carcinogenesis when inhaled by the human body; BCM and chlorothalonil fungicides are harmful to humans. It has a stimulating effect on the skin and eyes and can cause dermatitis. At the same time, it is extremely toxic to aquatic organisms and has long-term adverse effects on the water environment; the price of metallic silver is relatively expensive, which makes the manufacturing cost of the pigment high.

Method used

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  • Aqueous formaldehyde-free painting pigment and preparation method thereof
  • Aqueous formaldehyde-free painting pigment and preparation method thereof

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preparation example Construction

[0031] A preparation method of water-based formaldehyde-free paint, comprising the following steps:

[0032] S1, mixing the toner, vegetable gum and surfactant and then grinding to make a color paste;

[0033] S2, adding inorganic electrolyte and inorganic thickener to the color paste, stirring, and then sterilizing at 120-130°C, and dispersing and activating under the conditions of vacuum pressure 0.7-0.9KPa and rotating speed 400-500r / min after the sterilization is completed; and

[0034] S3, after the dispersion and activation is completed, lower the temperature to below 40°C, add the antibacterial agent, and stir evenly to obtain the finished product.

[0035] Grinding in the present invention is to use a three-roll mill to achieve a specified fineness through the mutual extrusion of the surfaces of three horizontal rollers and friction at different speeds to make a color paste, and the fineness in the present invention is less than 10 μm.

[0036] The method of the prese...

Embodiment 1

[0041] 10 mass parts of toner, 60 mass parts of vegetable gum (gum arabic, peach gum and pectin are the mixture of 1:1.2:1.5 in mass ratio) and 3.5 mass parts of surfactant (hexadecyl trimethyl ammonium chloride) mixed and ground to make a color paste with a fineness of 10 microns;

[0042] Add 0.05 parts by mass of inorganic electrolyte sodium chloride and 1 part by mass of inorganic thickener (bentonite, attapulgite and aluminum silicate at a mass ratio of 1:1.2:2) to the color paste, stir evenly, and then Sterilize at 120°C. After the sterilization is completed, disperse and activate for 25 minutes under the conditions of vacuum pressure 0.7KPa and rotation speed 400r / min;

[0043] After dispersing and activating, lower the temperature to 40°C, add 0.05 parts by mass of antibacterial agent chlorphenesin, and stir evenly to obtain a finished product.

Embodiment 2

[0045] 15 parts by mass of toner, 65 parts by mass of vegetable gum (gum arabic and carrageenan in a mass ratio of 1:1) and 5.5 parts by mass of surfactant (octadecylamine acetate) mixed Grinding to make a color paste with a fineness of 5 microns;

[0046] Add 0.15 parts by mass of inorganic electrolyte potassium chloride and 1 part by mass of inorganic thickener (bentonite, attapulgite and aluminum silicate at a mass ratio of 1:1.5:3) to the color paste, stir evenly, and then Sterilize at 130°C. After the sterilization is completed, disperse and activate for 30 minutes under the conditions of vacuum pressure 0.9KPa and rotation speed 500r / min;

[0047] After dispersing and activating, lower the temperature to 30°C, add 0.1 parts by mass of antibacterial agent paraben, and stir evenly to obtain a finished product.

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Abstract

The invention relates to aqueous formaldehyde-free painting pigment and a preparation method thereof. The pigment includes, by mass, 10-15 parts of toner, 60-65 parts of vegetable gum, 3.5-5.5 parts of a surfactant, 1-5 parts of an inorganic thickening agent, 0.05-0.1 part of an antibacterial agent and 0.05-0.15 part of an inorganic electrolyte. An inorganic thickening agent combination with a special composition is adopted by the pigment. In the technical scheme, the inorganic thickening agent exits in the system in a melted state, does not adsorb air on the surface and provides an environment condition against bacterium breeding, thus effectively avoiding a situation that traditional fillers exist in a particular form in a product system, easily absorb air and cause bacterium breeding. Aproduct can have good antibacterial performance by only adding a small amount of the antibacterial agent. Through addition of the inorganic thickening agent, low color difference and crack resistancewhich are comparable to those of fillers can be achieved, and the product production cost can be reduced.

Description

technical field [0001] The invention relates to the field of pigments, in particular to a water-based formaldehyde-free paint pigment and a preparation method thereof. Background technique [0002] Water-based paints refer to paints that can be dissolved or diluted with water, generally including watercolor paints, gouache paints, acrylic paints, acrylic paints, finger paints, Chinese paints, etc. [0003] In order to make water-based paints have better performance, such as no cracking, low color difference, etc., and lower manufacturing costs, fillers, such as calcium carbonate, talcum powder, etc., are generally added to paints, but the fillers are in the product. It exists in the form of granular particles, has a large specific surface area, absorbs a large amount of air, and easily causes bacterial growth. In order to overcome this shortcoming, a large amount of antibacterial agent is often required to effectively eliminate bacteria. In the prior art, in order to preven...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/06C09D7/44C09D5/14C09D105/00C09D105/06
CPCC09D5/06C09D5/14C09D105/00C09D105/06C09D7/44C08L5/00C08K13/02C08K3/346C08K3/34
Inventor 刘其通何莉娜梁立军
Owner 河北青竹画材科技股份有限公司
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