Novel INEOS membrane polar distance electrolytic cell
A membrane electrode spacing and electrolytic cell technology, applied in the electrolysis process, electrolysis components, electrodes, etc., can solve the problems of wasting the effective area of electrolysis, affecting the purity of chlorine gas, and decreasing the current efficiency, and achieves convenient replacement of cathode and anode meshes, reliable and safe operation. , the effect of reducing overvoltage
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Embodiment 1
[0081] Titanium mesh substrate: mesh pitch 3*6mm, thickness 1mm;
[0082] The coating liquid of anodic coating: ruthenium trichloride, iridium tetrachloride, chloroplatinic acid, titanium tetrachloride and hydrochloric acid aqueous solution, form formula raw material by the atomic percentage of Ru43:Ir9:Pt8:Ti40;
[0083] Calculate the mass ratio of each raw material used in the end as follows:
[0084] Ruthenium trichloride: iridium tetrachloride: chloroplatinic acid: titanium tetrachloride=88.3:15.7:16.8:158.7.
[0085] Making anodic coating: spraying, drying, and sintering for 10 cycles, and the amount of spraying in each pass is 55-60ml / m 2 , weighing after each sintering, the weight increases by 3.5-4g / m 2 , after the last sintering, the total weight of spraying on the titanium mesh substrate is 35-40g / m 2 .
[0086] Product test indicators:
[0087] 1. Test result of chlorine analysis potential: 1.09V-1.10V (indicator: current density 4KA / ㎡, saturated brine, tempera...
Embodiment 2
[0092] Titanium mesh substrate: mesh pitch 3.5*6mm, thickness 1mm;
[0093] Coating solution for anode coating: solid ruthenium trichloride, titanium tetrachloride, iridium tetrachloride, zirconium chloride, platinum chloride and ethylene glycol--butyl ether, according to Ru37:Ir15:Pt6:Ti39:Zr3 : the atomic percent constitutes the formula material,
[0094] Calculate the mass ratio of each raw material used in the end as follows:
[0095] Ruthenium trichloride: iridium tetrachloride: chloroplatinic acid: titanium tetrachloride: zirconium chloride=76.0: 26.1: 12.6: 154.8: 7.7.
[0096] Making anodic coating: spraying, drying, and sintering for 10 cycles, and the amount of spraying in each pass is 45-50ml / m 2 , weighing after each sintering, the weight increases by 2.8-3.5g / m 2 , after the last sintering, the total weight of spraying on the titanium mesh substrate is 28-35g / m 2 .
[0097] Product test indicators:
[0098] 1. Test result of chlorine analysis potential: 1.10V-...
Embodiment 3
[0102] Titanium mesh substrate: mesh pitch 4.5*8mm mm, thickness 1mm;
[0103] Coating solution for anode coating: solid ruthenium trichloride, chloroiridic acid, chloroplatinic acid, titanium tetrachloride, palladium chloride and n-butanol, according to the atomic percentage composition formula of Ru40:Ir12:Pt9:Ti35:Pd4 material;
[0104] Calculate the mass ratio of each raw material used in the end as follows:
[0105] Ruthenium trichloride: iridium tetrachloride: chloroplatinic acid: titanium tetrachloride: palladium chloride=82.1: 20.9: 18.9: 138.9: 26.3.
[0106] Making anode coating: spraying, drying, and sintering for 10 cycles, and the amount of spraying in each pass is 40-45ml / m 2 , weighing after each sintering, the weight increases by 3-3.5g / m 2 , after the last sintering, the total spraying weight on the titanium mesh substrate is 30-35g / m 2 .
[0107] Product test indicators:
[0108] 1. Test result of chlorine analysis potential: 1.10V-1.12V (indicator: cur...
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