Preparation method of solid-state lithium ion battery comprising solid electrolyte
A technology of lithium-ion batteries and solid-state electrolytes, which is applied in the manufacture of electrolyte batteries, non-aqueous electrolyte batteries, and solid electrolytes. Improvement and enhancement of room temperature conductivity and reduction of dry environment requirements
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[0036] see figure 1 , the present invention provides a preparation method of a solid-state lithium-ion battery containing a solid-state electrolyte, adopting the synergistic effect of double in-situ reaction, solidifying the liquid electrolyte monomer in-situ in the solid-state battery, and realizing the double-in-situ reaction technology in the solid state The application in the battery specifically includes the following steps:
[0037] The first step, the polymer monomer 1,3-dioxolane and the first lithium salt are dissolved in a volatile small molecule solvent to prepare the first mixed solution (that is, the polymer monomer and the first lithium salt mixed solution);
[0038] In the second step, the polymerization initiator and the second lithium salt are dissolved in a volatile small molecule solvent to prepare a polymerization initiation solution;
[0039] In the third step, tetraethyl orthosilicate and the third lithium salt are dissolved in formic acid to prepare th...
Embodiment 1
[0070] In Example 1, a method for preparing a solid-state lithium-ion battery comprising a solid-state electrolyte provided by the present invention specifically includes the following steps:
[0071] The first step, preparing polymer monomer 1,3-dioxolane and the first lithium salt mixed solution (i.e. the first mixed solution) 100g, wherein, containing 80g polymer monomer 1,3-dioxolane, And 20g lithium salt LiTFSI, stand-by.
[0072] Second step, get 10g tetraethyl orthosilicate and dissolve in 80g formic acid, and mix the 3rd lithium salt LiFSI of 10g, be mixed with the mixed solution of the 3rd lithium salt, tetraethyl orthosilicate and formic acid (being the second Mixed solution), the mass percent content is: tetraethyl orthosilicate is 10%, the third lithium salt is 10%, formic acid is 80%, stand-by.
[0073] The third step, according to the required composite solid electrolyte formula, mix the first mixed solution obtained in the first step and the second mixed soluti...
Embodiment 2
[0078] In Embodiment 2, a method for preparing a solid-state lithium-ion battery comprising a solid-state electrolyte provided by the present invention specifically includes the following steps:
[0079] The first step is to prepare 100 g of polymer monomer 1,3-dioxolane solution for use.
[0080] In the second step, the LiTFSI lithium salt and the polymerization initiator aluminum trifluoromethanesulfonate Al(OTf) 3 Dissolved in formic acid, prepared as a polymerization initiator solution, the mass content of LiTFSI is 0-30%, aluminum trifluoromethanesulfonate Al(OTf) 3 The concentration is 0.01M, ready to use.
[0081] The third step, take 1g of tetraethyl orthosilicate and dissolve it in 99g of formic acid to prepare a mixed solution (i.e. the second mixed solution) of tetraethyl orthosilicate and formic acid, mass percentage: tetraethyl orthosilicate Ethyl ester is 1%, formic acid is 99%, and it is ready for use.
[0082] The fourth step, according to the required compo...
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