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Amine catalyst for polyurethane foam and preparation method of amine catalyst

A technology of polyurethane foam and amine catalyst, applied in the chemical industry, can solve the problems of high harm to human body, high cost, single function, etc., and achieve the effects of good effect, high tensile strength and breaking strength, and high catalytic activity

Inactive Publication Date: 2019-09-13
南通恒光大聚氨酯材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Polyurethane materials are made of polyisocyanates, polyols and other stabilizers as raw materials, and are prepared by catalytic reactions of catalysts at a certain temperature. A type of catalyst commonly used in the synthesis of polyurethane materials is metal organic compounds. This type of organometallic catalyst was first Organic compounds of lead and mercury, but because lead and mercury are heavy metals, they are harmful to the human body and cause serious environmental pollution, they have been listed as prohibited products, and the existing catalysts have a single purpose and limited application range. Products often need to add a variety of catalysts. When other special auxiliary functions are required, it is often necessary to add some other high-priced auxiliary materials to assist, especially in the production of automobile seat cushions. Because the catalysts and auxiliary materials used are single in function and high in cost, The smell is heavy, so that the free formaldehyde in the polyurethane remains in the polyurethane product, which has a strong smell and is not environmentally friendly

Method used

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  • Amine catalyst for polyurethane foam and preparation method of amine catalyst
  • Amine catalyst for polyurethane foam and preparation method of amine catalyst
  • Amine catalyst for polyurethane foam and preparation method of amine catalyst

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preparation example Construction

[0029] A kind of preparation method for the amine catalyst of polyurethane foam, wherein, described preparation method comprises the steps:

[0030] 1) The raw materials are weighed in parts by mass for subsequent use;

[0031] 2) Mix and stir or grind the weighed raw materials and mix them uniformly to obtain the amine catalyst.

Embodiment 1

[0034] An amine catalyst for polyurethane foam, comprising the following raw materials in percentage by weight: 30% of dipropylene glycol, 32% of ZF10 catalyst, 20% of aldehyde remover, and 18% of auxiliary agent; in parts by weight, the aldehyde remover includes the following parts by weight s material:

[0035]

[0036]

[0037] The surfactant is fatty acid methyl ester polyoxyethylene ether; the reducing agent is stannous chloride; the auxiliary agent includes 32wt% ε-polylysine, 54wt% sodium gluconate and 14wt% trifluoropropyltrimethoxysilane.

[0038] A kind of preparation method for the amine catalyst of polyurethane foam, preparation method comprises the following steps:

[0039] 1) Dipropylene glycol, ZF10 catalyst, 4-nitrophenylbutyrate, polydimethylsiloxane, vermiculite, fatty acid methyl ester polyoxyethylene ether, ammonia monohydrate, stannous chloride, polyethylene wax, ε-polylysine, sodium gluconate and trifluoropropyltrimethoxysilane are weighed in parts...

Embodiment 2

[0042] An amine catalyst for polyurethane foam, comprising the following raw materials in percentage by weight: 35% of dipropylene glycol, 30% of ZF10 catalyst, 18% of aldehyde remover, and 17% of auxiliary agent; in parts by weight, the aldehyde remover includes the following parts by weight s material:

[0043]

[0044] Surfactant is lignosulfonate and stearic acid monoglyceride, mass ratio is 1:2; Reducing agent is sodium borohydride; Auxiliary agent includes 34wt% ε-polylysine, 56wt% sodium gluconate and 10 wt% trifluoropropyltrimethoxysilane.

[0045] A kind of preparation method for the amine catalyst of polyurethane foam, preparation method comprises the following steps:

[0046] 1) Dipropylene glycol, ZF10 catalyst, 4-nitrophenylbutyrate, polydimethylsiloxane, vermiculite, lignosulfonate, monoglyceride stearate, ammonia monohydrate, sodium borohydride, Polyethylene wax, ε-polylysine, sodium gluconate and trifluoropropyltrimethoxysilane are weighed in parts by mass...

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Abstract

The invention discloses an amine catalyst for polyurethane foam. The amine catalyst comprises the following raw materials in percentage by weight: 30-40% of dipropylene glycol, 25-35% of a ZF10 catalyst, 10-20% of an aldehyde remover and 10-18% of an assistant. The amine catalyst for polyurethane foam disclosed by the invention has high catalytic activity and is capable of facilitating rapid completion of a polymerization reaction between isocyanate and polyether polyol under the same reaction condition; and the prepared polyurethane slurry is excellent in physical properties, has higher elongation at break and higher tensile strength and breaking strength at the elongation of 100% and 300%, and is excellent in formaldehyde degradation effect, safe and environment-friendly.

Description

technical field [0001] The invention relates to the field of chemical industry, in particular to an amine catalyst for polyurethane foam and a preparation method thereof. Background technique [0002] Polyurethane is a general term for polymer compounds containing repeated carbamate groups in the main chain. This polymer material can be used to manufacture rubber, rigid and flexible foam plastics, adhesives, coatings, paints and other products. Its excellent wear resistance, impact resistance, UV resistance and high and low temperature resistance are widely used in construction, automobile, light industry, textile, petrochemical, metallurgy, electronics, national defense, medical, machinery and many other fields. [0003] Polyurethane materials are made of polyisocyanates, polyols and other stabilizers as raw materials, and are prepared by catalytic reactions of catalysts at a certain temperature. A type of catalyst commonly used in the synthesis of polyurethane materials is...

Claims

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Application Information

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IPC IPC(8): C08G18/18C08L75/04C08L83/04C08L23/06C08K3/34C08K5/32
CPCC08G18/18C08L75/04C08L83/04C08L23/06C08K3/34C08K5/32C08K5/098Y02P20/52
Inventor 李光
Owner 南通恒光大聚氨酯材料有限公司
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