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A continuous silicon steel long fiber electrical magnetic material and its preparation method

A magnetic material, long fiber technology, applied in the direction of inductor/transformer/magnet manufacturing, fiber processing, circuits, etc., can solve the problem of complex overall process, achieve the effect of large magnetic field strength, reduce size, and save resource consumption

Inactive Publication Date: 2021-11-05
无锡燊旺和电子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent uses the melt spinning method, the combination of the non-sol-gel method and the high-voltage electrospinning method, and the overall process is more complicated.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A continuous silicon steel long-fiber electrical magnetic material is prepared by the following method:

[0034] S1. Mix organic solvent, manganese hydroxide and deionized water, wherein the molar ratio of organic solvent to manganese oxide is 1:10, add deionized water to finally keep the pH value of the solution at 7.2, and stir to obtain a mixed solvent; The organic solvent described in step S1 is: polyvinyl alcohol.

[0035] S2. Add metal iron salt into the mixed solvent, wherein the mass ratio of the metal iron salt to the mixed solvent is 1:10, and stir evenly to obtain a mixed solution; the metal iron salt in step S2 is: iron nitrate.

[0036] S3. The mixed solution is vacuum dehydrated to a gel state at a temperature of 70° C. to obtain an iron gel;

[0037] S4. When the iron gel temperature is 18°C, add silicon tetrachloride dropwise, and stir until the predetermined ratio of silicon and iron elements is reached to obtain a mixed gel; the molar mass of the sili...

Embodiment 2

[0042] A continuous silicon steel long-fiber electrical magnetic material is prepared by the following method:

[0043]S1. Mix organic solvent, manganese hydroxide and deionized water, wherein the molar ratio of organic solvent to manganese oxide is 1:20, add deionized water to finally keep the pH value of the solution at 5.6, and stir to obtain a mixed solvent; The organic solvent described in step S1 is: citric acid.

[0044] S2. Add metal iron salt into the mixed solvent, wherein the mass ratio of the metal iron salt to the mixed solvent is 1:20, and stir evenly to obtain a mixed solution; the metal iron salt in step S2 is: ferric chloride.

[0045] S3. The mixed solution is vacuum dehydrated to a gel state at a temperature of 80° C. to obtain an iron gel;

[0046] S4. When the iron gel temperature is 20°C, add silicon tetrachloride dropwise, and stir until the predetermined ratio of silicon and iron elements is reached to obtain a mixed gel; the molar mass of the silicon ...

Embodiment 3

[0051] A continuous silicon steel long-fiber electrical magnetic material is prepared by the following method:

[0052] S1. Mix organic solvent, manganese hydroxide and deionized water, wherein the molar ratio of organic solvent to manganese oxide is 1:0.5, add deionized water to finally keep the pH value of the solution at 8.5, and stir to obtain a mixed solvent; The organic solvent in step S1 is: polyvinyl alcohol and citric acid mixed in equal proportions.

[0053] S2. Add metal iron salt in mixed solvent, wherein the mass ratio of metal iron salt and mixed solvent is: 1:5, and stir to obtain mixed solution; The metal iron salt described in step S2 is: ferric nitrate, ferric chloride, etc. Proportional mix.

[0054] S3. The mixed solution is vacuum dehydrated to a gel state at a temperature of 60° C. to obtain an iron gel;

[0055] S4. When the iron gel temperature is 15°C, add silicon tetrachloride dropwise, and stir until the predetermined ratio of silicon and iron elem...

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PUM

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Abstract

For solving the deficiencies in the prior art, the invention provides a kind of preparation method of continuous silicon steel long-fiber electrical magnetic material, comprising: S1. get organic solvent, manganese hydroxide and deionized water to mix, wherein the mole of organic solvent and manganese oxide The ratio is 1:0.5-20, and the pH value is maintained at 5.6-8.5; S2. Add metal iron salt to the mixed solvent, wherein the mass ratio of the metal iron salt to the mixed solvent is: 1:5-20; S3. The mixed solution is at 60 At a temperature of ‑80°C, vacuum dehydrate to a gel state to obtain an iron gel; S4. When the temperature of the iron gel is 15‑20°C, add silicon tetrachloride and stir until the predetermined ratio of silicon to iron is reached; S5. The mixed gel is spun by a high-voltage electrospinning method; S6. Continuous silicon steel magnetic long fibers are obtained after heat treatment. The present invention finally spins continuous silicon steel long fibers with an aspect ratio exceeding 4000:1 instead of short fibers.

Description

technical field [0001] The invention belongs to the technical field of magnetic materials, and in particular relates to a continuous silicon steel long fiber electrical magnetic material. Background technique [0002] Soft magnetic materials used under low-frequency magnetic fields are required to have high magnetic permeability and low coercive force. The magnetic permeability is high. When the number of turns of the coil is constant, a small excitation current can generate a high magnetic induction intensity, thereby obtaining a high output voltage. The coercive force of the material is low, the area of ​​the hysteresis loop is small, and the iron loss is also small. Therefore, the iron core made of materials with high magnetic permeability and low coercivity helps to reduce the size of the product and improve the sensitivity. [0003] Low-frequency soft magnetic materials are mainly silicon steel sheets. Adding 0.8 to 4.5% silicon to iron containing a small amount of c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D5/00D01D10/02D01F9/08D06M11/44D06M11/48H01F41/00
CPCD01D5/0015D01D10/02D01F9/08D06M11/44D06M11/48H01F41/00
Inventor 娄建勇
Owner 无锡燊旺和电子科技有限公司