Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Amorphous photonic crystal schemochrome material based on black titanium dioxide and silicon dioxide composite and preparation method of amorphous photonic crystal schemochrome material

A technology of black titanium dioxide and photonic crystals, applied in the direction of titanium oxide/hydroxide, silicon dioxide, titanium dioxide, etc., can solve the problems of being unable to reduce environmental pollution and not degrading pollutants by sunlight, so as to avoid oxygen vacancy defects, Simple preparation process and good photocatalytic effect

Inactive Publication Date: 2019-10-08
SHAANXI UNIV OF SCI & TECH
View PDF2 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Structural pigments without angle dependence can replace traditional chemical pigments in use due to their characteristics of never fading and soft colors, but structural color materials still cannot alleviate environmental pollution problems in the application process
[0004] Structural color has been extensively studied and deeply explored by researchers for its functionalization because of its physical coloring characteristics. It has great potential for the industrial production of non-angle-dependent structural colorants with amorphous photonic crystal structures that are not harsh in actual production conditions. possibility, but the introduction of carbon black substances such as acetylene black, carbon nanotubes, and graphene, which are light in weight and not easy to disperse, can only absorb coherent scattered light, and do not have the function of degrading pollutants by sunlight, and so far, no carbon The introduction of black matter can prepare angle-independent structural color materials with photocatalytic effect, which has not been reported by researchers.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Amorphous photonic crystal schemochrome material based on black titanium dioxide and silicon dioxide composite and preparation method of amorphous photonic crystal schemochrome material
  • Amorphous photonic crystal schemochrome material based on black titanium dioxide and silicon dioxide composite and preparation method of amorphous photonic crystal schemochrome material
  • Amorphous photonic crystal schemochrome material based on black titanium dioxide and silicon dioxide composite and preparation method of amorphous photonic crystal schemochrome material

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0035] 2)SiO2 2 Preparation of microspheres

[0036] Drop the ethanol solution of ethyl orthosilicate into the ethanol solution of ammonia water, make the concentration of ammonia water 0.1-0.6mol / L, and the concentration of ethyl orthosilicate 0.4-1.2mol / L, stir the reaction, centrifuge after the reaction is completed, Washed and dried to obtain SiO 2 microsphere powder;

[0037] 3) B-TiO 2 / SiO 2 material preparation

[0038] Weigh SiO according to the mass ratio of 1:(0.1~1) 2 Powder and B-TiO2 Powder, according to the ratio of (1 ~ 2) g: 50ml SiO 2 The powder was dissolved in ethanol, and then the corresponding B-TiO was added 2 The powder is ultrasonically dispersed for a certain period of time after being stirred for 2 hours, and dried at room temperature after sufficient reaction to obtain an amorphous photonic crystal structural color material based on black titanium dioxide and silicon dioxide with a photocatalytic effect.

[0039] In step 1), the grinding tim...

Embodiment 1

[0043] An amorphous photonic crystal structural color material with photocatalytic effect based on the composite of black titanium dioxide and silicon dioxide and a preparation method thereof, comprising the following steps:

[0044] 1) Black TiO2 2 (B-TiO 2 ) Preparation of nanoparticles

[0045] Weigh P25(TiO 2 ) and NaHB 4 , ground with an agate mortar, mixed evenly, heated up to 380°C at a heating rate of 7°C / min, heat-treated at 380°C in vacuum for 3 hours, and cooled naturally. After the reaction was completed, cross-wash with deionized water and ethanol four times, and dry at room temperature to obtain B-TiO 2 Nano powder.

[0046] 2)SiO2 2 Preparation of microspheres

[0047] Drop the ethanol solution of ethyl orthosilicate into the ethanol solution of ammonia water, so that the concentration of ammonia water is 0.1mol / L, and the concentration of ethyl orthosilicate is 0.8mol / L. Stir and react at 36°C for 4 hours. After the reaction is completed, centrifuge, Wa...

Embodiment 2

[0052] 1) Black TiO2 2 (B-TiO 2 ) Preparation of nanoparticles

[0053] Weigh P25(TiO 2 ) and NaHB 4 , ground with an agate mortar, mixed evenly, heated up to 250°C at a heating rate of 7°C / min, heat treated in vacuum at 250°C for 2 hours, and cooled naturally. After the reaction was completed, cross-wash with deionized water and ethanol four times, and dry at room temperature to obtain B-TiO 2 Nano powder.

[0054] 2)SiO2 2 Preparation of microspheres

[0055] Drop the ethanol solution of ethyl orthosilicate into the ethanol solution of ammonia water, so that the concentration of ammonia water is 0.2mol / L, and the concentration of ethyl orthosilicate is 0.4mol / L. Stir and react at 25°C for 6h. After the reaction is completed, centrifuge, Washing and drying to obtain SiO with a diameter of 180nm 2 powder of microspheres;

[0056] 3) B-TiO 2 / SiO 2 material preparation

[0057] Weigh SiO at a mass ratio of 1:0.1 2 Powder and B-TiO 2 Powder, according to the ratio ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Diameteraaaaaaaaaa
Diameteraaaaaaaaaa
Diameteraaaaaaaaaa
Login to View More

Abstract

The invention provides an amorphous photonic crystal schemochrome material based on black titanium dioxide and silicon dioxide composite and a preparation method of the amorphous photonic crystal schemochrome material. The material component comprises SiO2 amorphous photonic crystal and black TiO2, and the mass ratio of the black TiO2 and the SiO2 amorphous photonic crystal is 1 to (0.1-1). The preparation method comprises the steps that (1) black TiO2 nanoparticle powder is prepared, and SiO2 amorphous photonic crystal microsphere powder is prepared; (2) the black TiO2 / SiO2 materials are prepared, specifically, the SiO2 amorphous photonic crystal microsphere powder and the black TiO2 nanoparticle powder are dissolved in ethanol, ultrasonic dispersion is conducted after stirring, and theproduct is dried. According to the preparation method, the schemochrome is combined with the photocatalysis function, the limitation of preparing non-angle independent color material by absorbing coherent scattering light with carbon black as the back bottom is broken, and the obtained material has the function of photocatalytic degradation of pollutants at the same time.

Description

technical field [0001] The invention belongs to the technical field of preparation of structural color materials, and relates to an amorphous photonic crystal structural color material based on the composite of black titanium dioxide and silicon dioxide and a preparation method thereof. Background technique [0002] The dazzling colors used in nature to communicate and camouflage are formed through the complex structural design of the interior. In the past, photonic pigments prepared by photonic crystals and amorphous photonic crystal structures can only replace traditional colors in the application process, and cannot solve the ensuing environmental pollution problems. At the same time, the structural color materials based on photonic crystals are bright and have an iridescent effect, and the non-angle-dependent amorphous photonic crystal structural color materials have been widely studied because of their soft colors and meeting human visual needs. [0003] The amorphous ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C01G23/047C01B33/18B82Y30/00B82Y40/00
CPCB82Y30/00B82Y40/00C01B33/18C01G23/047C01P2002/72C01P2002/84C01P2004/03C01P2004/62C01P2004/64C01P2004/82
Inventor 王芬冯篱秦毅赵婷罗宏杰朱建锋
Owner SHAANXI UNIV OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products