Light conversion resin composition
A resin composition and light conversion technology, which is applied in the field of image display devices and light conversion resin compositions, can solve the problems of quantum dot extinction, complex structure, and decreased brightness of quantum dots, and achieve excellent reliability, simple structure, long-term The effect of excellent reliability
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manufacture example 1
[0253] Production Example 1: Production of Scattering Particle Dispersion Liquid S1
[0254] Using a bead mill, TiO with a particle size of 100 nm as scattering particles 2 (Huntsman TTO-55 (C)) 70.0 parts by weight, 4.0 parts by weight of DISPERBYK-2001 (manufactured by BYK) as a dispersant, 26 parts by weight of propylene glycol methyl ether acetate as a solvent Mixing / dispersion 12 hours, the scattering particle dispersion S1 was produced.
Synthetic example 1
[0255] Synthesis Example 1: Synthesis of Green Quantum Dots (Q-1)
[0256] Add 0.4 mmol (0.058 g) of indium acetate (0.058 g), 0.6 mmol (0.15 g) of palmitic acid (0.15 g) and 20 mL of 1-octadecene into the reactor, and heat to 120° C. under vacuum. After 1 hour, the atmosphere in the reactor was switched to nitrogen. After heating to 280°C, quickly inject tris(trimethylsilyl)phosphine (TMS 3 P) A mixed solution of 0.2 mmol (58 μL) and 1.0 mL of trioctylphosphine was reacted for 1 minute.
[0257] Next, 2.4 mmol (0.448 g) of zinc acetate, 4.8 mmol of oleic acid, and 20 mL of trioctylamine were added to the reactor, and heated to 120° C. under vacuum. After 1 hour, the atmosphere in the reactor was switched to nitrogen, and the temperature of the reactor was raised to 280°C. 2 mL of the InP core solution synthesized above was added, and next, after adding 4.8 mmol of selenium (Se / TOP) in trioctylphosphine, the final mixture was allowed to react for 2 hours. Adding ethanol ...
Synthetic example 2
[0260] Synthesis Example 2: Synthesis of Red Quantum Dots (Q-2)
[0261] Add 0.2mmol (0.058g) of indium acetate, 0.6mmol (0.15g) of palmitic acid, and 10mL of 1-octadecene into the reactor, and heat to 120°C under vacuum. After 1 hour, the atmosphere in the reactor was switched to nitrogen. After heating to 280°C, quickly inject a mixed solution of 0.1mmol (29uL) of tris(trimethylsilyl)phosphine (TMS3P) and 0.5mL of trioctylphosphine, and react for 20 minutes. Acetone was added to the reaction solution rapidly cooled to room temperature, and the precipitate obtained by centrifugation was dispersed in toluene. The obtained InP semiconductor nanocrystal shows the UV first absorption maximum wavelength of 560-590 nm.
[0262] Add 1.2mmol (0.224g) of zinc acetate, 2.4mmol of oleic acid, and 10mL of trioctylamine into the reactor, and heat to 120°C under vacuum. After 1 hour, the atmosphere in the reactor was switched to nitrogen, and the temperature of the reactor was raised ...
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