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Multilayer composite coating layer suitable for milling and preparation method thereof

A multi-layer composite and milling technology, applied in coating, metal material coating process, ion implantation plating and other directions, can solve the problems of insufficient deposition energy, difficult α structure of coating, large brittleness, etc., to avoid stress The effect of too large, firm bonding, high strength and toughness

Active Publication Date: 2020-01-03
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the nitride coating also has shortcomings: high brittleness, insufficient bonding strength with the substrate, and insufficient thermal stability under high-temperature milling conditions
However, the disadvantage of this method is that the deposition energy is insufficient, which limits its preparation of oxide coatings. The Al deposited by this method 2 o 3 It is difficult for the coating to obtain an α structure with excellent performance, which also greatly restricts the development of multilayer composite coatings.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Put the clean cemented carbide substrate into the vacuum chamber of the plasma-enhanced composite ion coating system, and when the vacuum of the back is evacuated to 0.05Pa, turn on the auxiliary heating device on the furnace wall to heat the substrate, and at the same time turn on the rotating power to make the substrate Rotate continuously, heat until the substrate temperature reaches 380°C; then pass argon gas into the vacuum chamber, adjust the flow rate of argon gas to ensure the pressure is 0.2Pa, and then apply a DC bias voltage of -200V and a pulse bias voltage of -400V to the substrate , using the ionized Ar + Etch the surface of the substrate for 80 minutes; turn off the bias voltage of the substrate in turn, adjust the flow of argon to ensure that the working pressure is 0.15Pa, turn on the main arc power supply of the evaporation plating for evaporation coating, the main arc current on the crucible is 190A, and evaporate the raw material for Co 0.15 Ni 0.1...

Embodiment 2

[0027] Put the clean cemented carbide substrate into the vacuum chamber of the plasma-enhanced composite ion coating system, and when the vacuum of the back is evacuated to 0.05Pa, turn on the auxiliary heating device on the furnace wall to heat the substrate, and at the same time turn on the rotating power to make the substrate Rotate continuously, heat until the substrate temperature reaches 380°C; then pass argon gas into the vacuum chamber, adjust the flow rate of argon gas to ensure the pressure is 0.15Pa, and then apply a DC bias voltage of -200V and a pulse bias voltage of -300V to the substrate , using the ionized Ar + Etch the surface of the substrate for 30 minutes; turn off the bias voltage of the substrate in turn, adjust the flow of argon to ensure that the working pressure is 0.2Pa, turn on the main arc power supply of the evaporation plating for evaporation coating, the main arc current on the crucible is 210A, and evaporate the raw material for Co 0.2 Ni 0.2 ...

Embodiment 3

[0029] Put the clean cemented carbide substrate into the vacuum chamber of the plasma-enhanced composite ion coating system, and when the vacuum of the back is evacuated to 0.04Pa, turn on the auxiliary heating device on the furnace wall to heat the substrate, and at the same time turn on the rotating power to make the substrate Rotate continuously, heat until the substrate temperature reaches 380°C; then pass argon gas into the vacuum chamber, adjust the flow rate of argon gas to ensure the pressure is 0.25Pa, and then apply a DC bias of -100V and a pulse bias of -300V to the substrate , using the ionized Ar + Etch the surface of the substrate for 90 minutes; turn off the bias voltage of the substrate in turn, adjust the flow of argon to ensure that the working pressure is 0.15Pa, turn on the main arc power supply of evaporation plating for evaporation coating, the main arc current on the crucible is 220A, and evaporate the raw material for Co 0.2 Ni 0.2 Cr 0.2 Al 0.2 Y ...

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PUM

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Abstract

The invention discloses a multilayer composite coating layer suitable for milling. The multilayer composite coating layer suitable for milling is a whole consisting of five sublayers of a CoNiCrAlY high-entropy alloy bonding layer, an alpha-Cr2O3 oxide template layer, an alpha-Al2O3 oxide support layer, a TiAlCrON nitric oxide joint layer and a TiAlCrN nitride wear resisting layer; the sequence ofthe five sublayers is from inside to outside; and the total thickness of the coating layer is 1.2-3.5 microns. A preparation method of the coating layer comprises the following steps: after heating and ion etching of a substrate, an arc evaporation plating process is firstly used for depositing the CoNiCrAlY layer on the substrate; and then, a cathode arc ion plating process is used for depositing the alpha-Cr2O3 layer, the alpha-Al2O3 layer, the TiAlCrON layer and the TiAlCrN layer in sequence. The multilayer composite coating layer organically combined by different functional sublayers is high in toughness, excellent in impact resistance and more suitable for milling in an intermittent cutting mode; and the preparation process is simple and convenient for industrial production.

Description

technical field [0001] The invention belongs to the technical field of cutting tool surface coatings, and in particular relates to a multilayer composite coating suitable for milling and a preparation method thereof. Background technique [0002] Milling is an important processing method of cutting. The characteristic of milling is intermittent cutting, and the tool bears impact load during the processing. Milling requires milling cutters and their surface coating materials to have good toughness and impact resistance. Nitride coating is a widely used coating material for cutting tools such as milling cutters and turning tools, such as TiAlN, TiAlCrN, TiAlSiN, etc. The nitride coating has high hardness and good wear resistance. However, the nitride coating also has shortcomings: high brittleness, insufficient bonding strength with the substrate, and insufficient thermal stability under high-temperature milling conditions. Oxide coatings (such as Al 2 o 3 ) Compared with ...

Claims

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Application Information

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IPC IPC(8): C23C14/02C23C14/32C23C14/14C23C14/08C23C14/06
CPCC23C14/0021C23C14/022C23C14/0641C23C14/0676C23C14/081C23C14/083C23C14/14C23C14/325
Inventor 鲜广鲜丽君赵海波
Owner SICHUAN UNIV